Search results for " Ion exchange"
showing 10 items of 65 documents
Towards 1 kW power production in a reverse electrodialysis pilot plant with saline waters and concentrated brines
2017
Abstract Reverse electrodialysis (RED) is a promising technology to extract energy from salinity gradients, especially in the areas where concentrated brine and saline waters are available as feed streams. A first pilot-scale plant was recently built in Trapani (Italy), and tested with real brackish water and brine from saltworks. The present work focuses on the scale-up of the pilot plant, reaching more than 400 m 2 of total membrane area installed and representing the largest operating RED plant so far reported in the literature. With a nominal power capacity of 1 kW, the pilot plant reached almost 700 W of power capacity using artificial brine and brackish water, while a 50% decrease in …
Electrodialysis for water desalination: A critical assessment of recent developments on process fundamentals, models and applications
2018
Abstract The need for unconventional sources of fresh water is pushing a fast development of desalination technologies, which proved to be able to face and solve the problem of water scarcity in many dry areas of the planet. Membrane desalination technologies are nowadays leading the market and, among these, electrodialysis (ED) plays an important role, especially for brackish water desalination, thanks to its robustness, extreme flexibility and broad range of applications. In fact, many ED-related processes have been presented, based on the use of Ion Exchange Membranes (IEMs), which are significantly boosting the development of ED-related technologies. This paper presents the fundamentals…
Application of conductometric and pH metric measurements in determining the kinetics and equilibrium parameters of the heterophasic ion exchange: Met…
2019
The application possibilities of conductometric and pH metric measurements in the description of the process of heterophasic ion exchange have been analysed, between metal cation (Zn, Cu) - proton, which occurs according to the formula, M+ + HR ⇄ H+ + MR, where R is an anion permanently bound in the sorbent. Kinetic models of the pseudo-first and pseudo-second order reactions, as well as the Langmuir isotherm model which describes the process equilibrium, have been used in mathematical presentations. It was confirmed that conductometric and pH metric measurements are equally effective in the assessment of such processes' parameters, in comparison with the expensive method of determining met…
Structural Characterisation of Complex Layered Double Hydroxides and TGA-GC-MS Study on Thermal Response and Carbonate Contamination in Nitrate- and …
2015
Layered double hydroxides (LDHs) are versatile materials used for intercalating bioactive molecules in the fields of pharmaceuticals, nutraceuticals and cosmetics, with the purpose of protecting them from degradation, enhancing their water solubility to increase bioavailability and improving their pharmacokinetic properties and formulation stability. Moreover, LDHs are used in various technological applications to improve stability and processability. The crystal chemistry of hydrotalcite-like compounds was investigated by X-ray powder diffraction (XRPD), automated electron diffraction tomography (ADT) and thermogravimetric analysis (TGA)-GC-MS to shed light on the mechanisms involved in io…
Coxsackievirus B3 VLPs purified by ion exchange chromatography elicit strong immune responses in mice
2014
Coxsackievirus B3 (CVB3) is an important cause of acute and chronic viral myocarditis, and dilated cardiomyopathy (DCM). Although vaccination against CVB3 could significantly reduce the incidence of serious or fatal viral myocarditis and various other diseases associated with CVB3 infection, there is currently no vaccine or therapeutic reagent in clinical use. In this study, we contributed towards the development of a CVB3 vaccine by establishing an efficient and scalable ion exchange chromatography-based purification method for CVB3 virus and baculovirus-insect cell-expressed CVB3 virus-like particles (VLPs). This purification system is especially relevant for vaccine development and produ…
Membrane Deformation and Its Effects on Flow and Mass Transfer in the Electromembrane Processes
2019
In the membrane processes, a trans-membrane pressure (TMP) may arise due to design features or operating conditions. In most applications, stacks for electrodialysis (ED) or reverse electrodialysis (RED) operate at low TMP (<
Toward the Identification of Two Glycoproteins Involved in the Stomatal Deregulation of Downy Mildew–Infected Grapevine Leaves
2015
SPE Pôle IPM UB; International audience; Stomata remain abnormally opened and unresponsive to abscisic acid in grapevine leaves infected by downy mildew. This deregulation occurs from 3 days post inoculation and increases concomitantly with leaf colonization by the pathogen. Using epidermal peels, we demonstrated that the active compound involved in this deregulation is located in the apoplast. Biochemical assays showed that the active compound present in the apoplastic fluids isolated from Plasmopara viticola infected grapevine leaves (IAF) is a CysCys bridge-independent, thermostable and glycosylated protein. Fractionation guided assays based on chromatography / stomatal response and prot…
Transmission Electron Microscopy of GroEL, GroES, and the Symmetrical GroEL/ES Complex
1994
Two new 2-D crystal forms of the Escherichia coli chaperone GroEL (cpn60) 2 x 7-mer have been produced using the negative staining-carbon film (NS-CF) technique. These 2-D crystals, which contain the cylindrical GroEL in side-on and end-on orientations, both possess p21 symmetry, with two molecules in the respective unit cells. The crystallographically averaged images correlate well with those obtained by other authors from single particle analysis of GroEL and our own previous crystallographic analysis. 2-D crystallization of the smaller chaperone GroES (cpn10) 7-mer has also been achieved using the NS-CF technique. Crystallographically averaged images of GroES single particle images indic…
The determination of the DNA base composition in 19 species of adriatic sponges with high-pressure liquid cation-exchange chromatography.
1976
Abstract The (adenine + thymine)/(guanine + cytosine) base ratios of 19 species of adriatic sponges have been determined by high-pressure liquid cation-exchange chromatography. The base ratios vary from 1.49 (Mycale massa) to 0.63 (Hippospongia communis) according to an (A+T) content of 59.7 and 38.6 mol%, respectively. The DNAs of sponges of the order Keratosa showed marked differences in their (A +T) contents (39.5 to 58.8 mol%) whereas those of Tetractinellida and Halichondrina were nearly identical (39.3 to 40.8 and 49.5 to 49.8 mol%, respectively). The 5-methylcytosine (5MC) content was determined in 8 sponge DNAs by a semiquantitative method. The values differed from 0.8 to 2.2 mol% o…
The second component of human complement: Detection of two hemolytic forms in plasma by pH Variation
1988
The second component of human complement (C2) in pseudoglobulin prepared from normal plasma eluted as a single peak at high conductivity (30 mS) and pH 4.5 from the cationic exchangers S-Sepharose or Mono S in the Fast Protein Liquid Chromatography (FPLC) System. The C2 was stable at pH 4.5 and 0 degrees C if enzyme inhibitors were used and the pH was raised to 6.0 after elution from the columns. After rechromatography on Mono S in the FPLC System at the median isoelectric point of 5.5 or pH 6.0, the C2 eluted as two distinct hemolytic forms: the first peaked at 16 mS, the second at 30 mS. The two forms of C2 did not correlate with the allotypic variant of C2 in individual, normal human pla…