Search results for " Magne"

Measuring optical anisotropy in poly(3,4-ethylene dioxythiophene):poly(styrene sulfonate) films with added graphene

2015

Abstract Graphene is a 2D nanomaterial having a great potential for applications in electronics and optoelectronics. Composites of graphene with conducting polymers have shown high performance in practical devices and their solution-processability enables low-cost and high-throughput mass manufacturing using printing techniques. Here we measure the effect of incorporation of graphene into poly(3,4-ethylene dioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) to the optical anisotropy, absorbance and conductivity of the film. Uniaxial anisotropy in PEDOT:PSS films has been thought to be caused by the spin-coating process used in fabrication. We have characterized spray- and spin-coated films …

BODIPY atropisomer interconversion, face discrimination, and superstructure appending

2016

International audience; A strategy was developed to append sterically hindered apical pickets on both faces of the BODIPY platform to prevent stacking and aggregation. Ortho-substitution of both the meso-phenyl ring and the boron-bound catechol affords the right directionality to append pickets, achieve face discrimination, featuring two inter-convertible atropisomers, and is reminiscent of the picket-fence strategy in porphyrins.

Spectroscopic characterization of alkaline earth uranyl carbonates

2005

A series of alkaline uranyl carbonates, M[UO{sub 2}(CO{sub 3}){sub 3}].nH{sub 2}O (M=Mg{sub 2}, Ca{sub 2}, Sr{sub 2}, Ba{sub 2}, Na{sub 2}Ca, and CaMg) was synthesized and characterized by inductively coupled plasma mass spectrometry (ICP-MS) and atomic absorption spectrometry (AAS) after nitric acid digestion, X-ray powder diffraction (XRD), and thermal analysis (TGA/DTA). The molecular structure of these compounds was characterized by extended X-ray absorption fine-structure (EXAFS) spectroscopy and X-ray photoelectron spectroscopy (XPS). Crystalline Ba{sub 2}[UO{sub 2}(CO{sub 3}){sub 3}].6H{sub 2}O was obtained for the first time. The EXAFS analysis showed that this compound consists of …

Acetic acid leaching of neodymium magnets and iron separation by simple oxidative precipitation

2022

Neodymium-iron-boron (NdFeB) has become the most prominent permanent magnet alloy, with a wide variety of applications and an ever-increasing demand. Their recycling is important for securing the supply of critical raw materials used in their manufacturing. The use of organic acids such as acetic acid has been of recent interest for the recycling of waste NdFeB magnets. Despite achieving good leaching efficiencies, the published literature has not properly investigated the effects of key factors influencing the acetic acid leaching process and their respective interactions, which has lead to conflicting findings as to what conditions are optimal. The present work goes to show that no such o…

Exotic Spin-Orbital Physics in Hybrid Oxides

2016

We compare the effective spin-orbital super\-exchange triggered by magnetic $3d$ impurities with $d^3$ and $d^2$ configurations and either no orbital degree of freedom (orbital dilution) or hole replacing a doublon (charge dilution) in a $4d^4$ Mott insulator with $S=1$ spins. Impurities causing orbital dilution act either as spin defects decoupled from the surrounding ions, or generate orbital polarons along $d^3$-$d^4$ hybrid bonds. The exchange on these bonds determines which orbital is occupied by a doublon on the host site. In case of charge dilution by $3d^2$ impurities additional $\propto T_i^+T_j^+$ terms arise which enhance orbital fluctuations. We show that such terms may radicall…

Spin caloric transport from density-functional theory

2019

Spin caloric transport refers to the coupling of heat with spin transport. Its applications primarily concern the generation of spin currents and control of magnetisation by temperature gradients for information technology, known by the synonym spin caloritronics. Within the framework of ab initio theory, new tools are being developed to provide an additional understanding of these phenomena in realistic materials, accounting for the complexity of the electronic structure without adjustable parameters. Here, we review this progress, summarising the principles of the density-functional-based approaches in the field and presenting a number of application highlights. Our discussion includes th…

Theoretical study of systems with interest in molecular magnetism and electronics

2013

The project described in this thesis is motivated by a particular interest in Molecular Magnetism from a theoretical point of view. Molecular Magnetism, is still a thriving research field where some problems remain unexplored: A large amount of molecular systems are still theoretically unmanageable due to their huge computational requirements, while the standard software package cannot profit from the power of multiprocessor supercomputers. The scientific community would require a computational code to calculate the magnetic properties of mixed-valence clusters. A new magnetic POM, which needs only one magnetic ion to behave as SMMs, has appeared. A rationalization of its behaviour and an e…

The close classical T Tauri binary V4046 Sgr: Complex magnetic fields & distributed mass accretion

2011

We report here the first results of a multi-wavelength campaign focussing on magnetospheric accretion processes within the close binary system V4046 Sgr, hosting two partly-convective classical T Tauri stars of masses ~0.9 Msun and age ~12 Myr. In this paper, we present time-resolved spectropolarimetric observations collected in 2009 September with ESPaDOnS at the Canada-France-Hawaii Telescope (CFHT) and covering a full span of 7d or ~2.5 orbital/rotational cycles of V4046 Sgr. Small circularly polarised Zeeman signatures are detected in the photospheric absorption lines but not in the accretion-powered emission lines of V4046 Sgr, thereby demonstrating that both system components host lar…

Il ruolo della corteccia prefrontale dorsolaterale nella memoria di riconoscimento: uso dellla Stimolazione Magnetica Transcranica per il trattamento…

Il ruolo della corteccia prefrontale dorsolaterale (DLPFC) in compiti di memoria è stato largamente documentato. Una questione ancora molto dibattuta è il grado di lateralizzazione anatomica-funzionale dei processi di controllo esecutivo della DLPFC coinvolti nella memoria di riconoscimento. Il lavoro di tesi indaga le connessioni tra DLPFC e ippocampo mediante l’applicazione di tecniche di neuromodulazione dell’eccitabilità della DLPFC che consentano di accrescere l’attività ippocampale durante compiti di memoria di riconoscimento. I primi tre studi valutano gli effetti inibitori ed eccitatori della rTMS applicata alla DLPFC sulla performance in compiti di memoria di riconoscimento, in div…

Photoluminescence and Electron Spin Resonance of Silicon Dioxide Crystal with Rutile Structure (Stishovite)

2018

This work was supported by ERANET MYND. Also, financial support provided by Scientific Research Project for Students and Young Researchers Nr. SJZ/2017/2 realized at the Institute of Solid State Physics, University of Latvia is greatly acknowledged. The authors express our gratitude to R.I. Mashkovtsev for help in ESR signal interpretation. The authors are appreciative to T.I. Dyuzheva, L.M. Lityagina, N.A. Bendeliani for stishovite single crystals and to K. Hubner and H.-J. Fitting for stishovite powder of Barringer Meteor Crater.