Search results for " Materia"
showing 10 items of 18071 documents
Un peculiare itinerario geo-turistico nella Sicilia occidentale: dall’oceano anossico Mesozoico al Moscato di Pantelleria.
2008
Effect of the extensional flow on the properties of oriented nanocomposite films for twist wrapping
2011
In this study, we examined the mechanical behavior of nanocomposite films based on polyethylene (PE) and pristine PE films. The films were prepared by film blowing and were then cold-drawn at low temperature. The experimental results show that cold drawing significantly enhanced the orientation; with increasing draw ratio (DR), the elastic modulus and tensile strength of the PE films strongly increased, particularly in the presence of the organoclay. To obtain polymeric films suitable for twist wrapping, the films must be sufficiently stiff so that no shrinkage or elastic recovery occur during or after twisting. The elongation at break and the yield strain sharply decreased with orientation…
Patterning of supported gold monolayers via chemical lift-off lithography
2017
The supported monolayer of Au that accompanies alkanethiolate molecules removed by polymer stamps during chemical lift-off lithography is a scarcely studied hybrid material. We show that these Au–alkanethiolate layers on poly(dimethylsiloxane) (PDMS) are transparent, functional, hybrid interfaces that can be patterned over nanometer, micrometer, and millimeter length scales. Unlike other ultrathin Au films and nanoparticles, lifted-off Au–alkanethiolate thin films lack a measurable optical signature. We therefore devised fabrication, characterization, and simulation strategies by which to interrogate the nanoscale structure, chemical functionality, stoichiometry, and spectral signature of t…
Prompt Determination of the Mechanical Properties of Industrial Polypropylene Sandwich Pipes
2021
A simple and prompt method to determine the mechanical properties of industrial multilayer extrusion polypropylene pipes for a gravity sewer network is suggested. The engineering formulas included for calculating the permissible thickness and relative position of a foam core in the pipes are based on a linear-elastic approximation and the rule of mixtures. The applicability of the approximation was justified experimentally during investigation of the effective tensile characteristics of single- and multilayer pipes and each layer specimen by using traditional tests and finite-element calculations. The results obtained were used to formulate engineering recommendations for calculations of th…
ULTRASONIC WAVES IN HETEROGENEOUS MATERIALS - MECHANICAL CHARACTERIZATION OF HETEROGENEOUS MATERIALS BY MEANS OF ULTRASONIC TESTS AND NUMERICAL MODEL…
2014
This Ph.D thesis treats the propagation of ultrasonic waves in heterogeneous materials. It is widely known how waves propagate in homogeneous materials like metallic ones. But very few aspects are known about the propagation in the heterogeneous materials because of the complex behavior regarding these materials. The heterogeneity can be related with the intrinsic properties, elastic and chemical, of each phase of the material, or with the periodic or random arrangement of inclusions of constant or different shapes. Concrete is a common case. In this work the first chapter gives a description of the main characteristics of heterogeneous materials.. In the second one, the methods of inspecti…
Synthesis of nanostructured protein–mineral-microcapsules by sonication
2022
We propose a simple and eco-friendly method for the formation of composite protein–mineral-microcapsules induced by ultrasound treatment. Protein- and nanoparticle-stabilized oil-in-water (O/W) emulsions loaded with different oils are prepared using high-intensity ultrasound. The formation of thin composite mineral proteinaceous shells is realized with various types of nanoparticles, which are pre-modified with Bovine Serum Albumin (BSA) and subsequently characterized by EDX, TGA, zeta potential measurements and Raman spectroscopy. Cryo-SEM and EDX mapping visualizations show the homogeneous distribution of the densely packed nanoparticles in the capsule shell. In contrast to the results re…
Observation of the Early Structural Changes Leading to the Formation of Protein Superstructures.
2014
Formation of superstructures in protein aggregation processes has been indicated as a general pathway for several proteins, possibly playing a role in human pathologies. There is a severe lack of knowledge on the origin of such species in terms of both mechanisms of formation and structural features. We use equine lysozyme as a model protein, and by combining spectroscopic techniques and microscopy with X-ray fiber diffraction and ab initio modeling of Small Angle X-ray Scattering data, we isolate the partially unfolded state from which one of these superstructures (i.e., particulate) originates. We reveal the low-resolution structure of the unfolded state and its mechanism of formation, hi…
Influence of uniaxial pressure on dielectric properties of (1- x )Na 0.5 Bi 0.5 TiO 3– x SrTiO 3 for x = 0.01, 0.04, and 0.1 ceramics
2017
The publication costs of this article were covered by the Estonian Academy of Sciences and the University of Tartu.
A new forum for upconversion research: The UPCON conference
2019
International audience; The Conference and Spring School on Properties, Design and Applications of Upconversion Nanomaterials (UPCON) provides a new forum for all experts and newcomers in the field of upconversion research. On the occasion of the second UPCON 2018 in Valencia (Spain), we are pleased to present a collection of 12 reviews and research articles that reflect recent advances in upconversion materials, their unique luminescent properties and many applications spanning from nanoscale thermometry to biomedicine.
Dual Enzyme-Triggered Controlled Release on Capped Nanometric Silica Mesoporous Supports
2012
The development of nanoscopic hybrid materials equipped with “molecular gates” showing the ability of releasing target entrapped guests upon the application of an external trigger has attracted great attention and has been extensively explored during recent years.1 These nanodevices are composed of two subunits, namely, a suitable support and certain capping entities grafted on the surface of the scaffolding.2 The support is used as a suitable reservoir in which certain chemicals can be stored whereas the molecules grafted in the outer surface act as a “gate” and can control the release of the entrapped molecules at will. Both components are carefully selected and arranged in order to achie…