Search results for " Materials Science"

showing 10 items of 7414 documents

Oxygen Vacancy Formation and Migration within the Antiphase Boundaries in Lanthanum Scandate-Based Oxides: Computational Study.

2022

The study was performed with the financial support from the Latvian Council of Science under the grant agreement LZP-2020/2-0009. Calculations were performed at the HLRS, University of Stuttgart, within the project 12939 DEFTD. The Institute of Solid State Physics, University of Latvia (Latvia), as the Centre of Excellence has received funding from the European Union’s Horizon 2020 Frame-work Programme H2020-WIDESPREAD-01-2016-2017-Teaming Phase2 under grant agreement No. 739508, project CAMART2.

oxygen transportLa<sub>1−<i>x</i></sub>Sr<i><sub>x</sub></i>ScO<sub>3−<i>δ</i></sub>; lanthanum scandate; perovskite; antiphase boundaries; oxygen vacancy; oxygen transport; DFTGeneral Materials Science:NATURAL SCIENCES::Physics [Research Subject Categories]La1−xSrxScO3−δantiphase boundariesoxygen vacancyDFTperovskitelanthanum scandateMaterials (Basel, Switzerland)
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Paramagnetic Defects and Thermoluminescence in Irradiated Nanostructured Monoclinic Zirconium Dioxide

2022

The work was carried out under the grant of the Ministry of Education and Science of the Republic of Kazakhstan AP09260057, “Luminescence and radiation resistance of synthesized under different conditions micro- and nanostructured compacts and ceramics based on ZrO2”. The research was partly (A.I.P.) performed at the Center of Excellence of the Institute of Solid State Physics, University of Latvia, supported through European Union Horizon 2020 Framework Programme H2020-WIDESPREAD-01-2016-2017-TeamingPhase2, under grant agreement No. 739508, project CAMART2.

paramagnetic defectselectron irradiationion irradiationF+ centerszirconium dioxide:NATURAL SCIENCES::Physics [Research Subject Categories]General Materials Sciencezirconium dioxide; ion irradiation; electron irradiation; paramagnetic defects; <i>F<sup>+</sup></i> centersMaterials
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Hexagonal Microparticles from Hierarchical Self-Organization of Chiral Trigonal Pd3L6 Macrotetracycles

2021

Construction of structurally complex architectures using inherently chiral, asymmetric, or multi-heterotopic ligands is a major challenge in metallosupramolecular chemistry. Moreover, the hierarchical self-organization of such complexes is unique. Here, we introduce a water-soluble, facially amphiphilic, amphoteric, chiral, asymmetric, and hetero-tritopic ligand derived from natural bile acid, ursodeoxycholic acid. We show that via the supramolecular transmetalation reaction, using nitrates of Cu(II) or Fe(III), and subsequently Pd(II), a superchiral Pd3L6 complex can be obtained. Even though several possible constitutional isomers of Pd3L6 could be formed, because of the ligand asymmetry a…

particlesurfactantSupramolecular chemistryGeneral Physics and Astronomychemistry.chemical_elementchirality02 engineering and technology010402 general chemistry01 natural sciences114 Physical sciencessupramolecular chemistryTransmetalationPhysico-chimie généraleChimie des colloïdesAmphiphileStructural isomersupramolekulaarinen kemiaChimiebile acidGeneral Materials ScienceLigandChemistryGeneral Engineeringheterotopic ligandChimie des surfaces et des interfacesGeneral Chemistrykompleksiyhdisteetself-assembly021001 nanoscience & nanotechnologypalladiumself-organization0104 chemical sciences3. Good healthmikrorakenteetCrystallographyChimie organiqueGeneral EnergytransmetalationSelf-assembly0210 nano-technologyChirality (chemistry)Palladium
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Biological Monitoring Using Lichens as a Source of Information About Contamination of Mountain with Heavy Metals

2022

Abstract The aim of this study was passive biomonitoring of the mountains of southern Poland. Lichens Hypogymnia physodes were used for the study. Concentrations of the heavy metals Ni, Cu, Zn, Cd and Pb were determined in these lichens. The concentrations were measured by atomic absorption spectrometry (AAS). The analysis of the concentrations of the determined heavy metals in the lichen thallus allowed to determine the places with the highest and the lowest contamination with a given heavy metal in the study area. It was shown that the area of Great Czantoria and Big Soszow is the most contaminated with heavy metals among the investigated areas. The study shows that the transport of analy…

passive biomonitoringHypogymnia physodes lichensatomic absorption spectrometry (AAS)General Materials Scienceheavy metalsEcological Chemistry and Engineering S
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Computational Fluid Dynamics (CFD) and Finite Element Analysis (FEM) of a Customized Stent-Graft for Endovascular (EVAR) Treatment of Abdominal Aorti…

2023

Background: The treatment of abdominal aortic aneurysm (AAA) is today commonly treated by inserting a stent-graft by the endovascular route, without resorting to open surgery. However, some clinical cases do not allow this less invasive approach, meaning that the stent-graft cannot be inserted and open surgery is used. Methods: In the study, we propose a fluid–structure interaction (FSI) analysis of an aneurysmatic aorta that could not be treated with Endovascular Aneurysm Repair (EVAR). The vessel is reconstructed through segmentation from CT scans and subsequently modeled on CAD software to create the surface and thickness of the vessel itself. Subsequently, we proceeded to carry out Comp…

patient specificFluid Flow and Transfer ProcessesProcess Chemistry and TechnologyGeneral Engineeringstent-graft; patient specific; Computational Fluid Dynamics; finite element analysisGeneral Materials ScienceStent-graftfinite element analysisComputational Fluid DynamicSettore ICAR/08 - Scienza Delle CostruzioniInstrumentationfinite element analysiComputer Science ApplicationsApplied Sciences
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Pickering Emulsion Gels Based on Halloysite Nanotubes and Ionic Biopolymers: Properties and Cleaning Action on Marble Surface

2019

We have fabricated ecocompatible Pickering emulsions based on halloysite nanotubes and ionic biopolymers (chitosan and pectin) from renewable resources. The effect of pectin and chitosan on the Pickering emulsion was investigated by direct visualization of the oil droplets and by the thermodynamic characterization at the interface. Pectin enhances the Pickering emulsion stability, while a phase separation and nonhomogeneous gel was observed in the presence of chitosan. We have demonstrated that the Pickering emulsion in a pectin based gel phase is suitable for wax layer removal from a marble surface. A controlled cleaning is achieved by tuning the contact time between the gel and the marble…

pectinfood.ingredientPectincleaningIonic bondingcultural heritageengineering.materialHalloysiteSettore CHIM/12 - Chimica Dell'Ambiente E Dei Beni CulturaliPickering emulsionChitosanchemistry.chemical_compoundfoodchemistryChemical engineeringPickering emulsionengineeringGeneral Materials SciencechitosanhalloysiteACS Applied Nano Materials
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Asymmetric hysteresis for probing Dzyalohsinskii-Moriya interaction

2016

The interfacial Dzyaloshinskii-Moriya interaction (DMI) is intimately related to the prospect of superior domain-wall dynamics and the formation of magnetic skyrmions. Although some experimental efforts have been recently proposed to quantify these interactions and the underlying physics, it is still far from trivial to address the interfacial DMI. Inspired by the reported tilt of the magnetization of the side edge of a thin film structure, we here present a quasi-static, straightforward measurement tool. By using laterally asymmetric triangular-shaped microstructures, it is demonstrated that interfacial DMI combined with an in-plane magnetic field yields a unique and significant shift in m…

perpendicular magnetic anisotropyNucleationFOS: Physical sciencesBioengineering02 engineering and technology01 natural sciencesMagnetization0103 physical sciencesMesoscale and Nanoscale Physics (cond-mat.mes-hall)General Materials Sciencechiral magnetThin film010306 general physicsPhysicsDzyaloshinskii-Moriya interactionspintronicsCondensed Matter - Materials ScienceCondensed Matter - Mesoscale and Nanoscale PhysicsSpintronicsCondensed matter physicsMechanical EngineeringSkyrmionMaterials Science (cond-mat.mtrl-sci)General Chemistry021001 nanoscience & nanotechnologyCondensed Matter PhysicsMagnetic hysteresisMagnetic fieldHysteresisnanomagnetism0210 nano-technologyasymmetric hysteresis loopNano Letters
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Study of the Effect of Two Phases in Li4SiO4&ndash;Li2SiO3 Ceramics on the Strength and Thermophysical Parameters

2022

This research was funded by the Science Committee of the Ministry of Education and Science of the Republic of Kazakhstan (No. BR11765580). The research of the team from Latvia (A.M., V.P. and A.I.P.) has been carried out within the framework of the EUROfusion Consortium, funded by the European Union via the Euratom Research and Training Programme (Grant Agreement No. 101052200—EUROfusion). Views and opinions expressed are however those of the author(s) only and do not necessarily reflect those of the European Union or the European Commission. Neither the European Union nor the European Commission can be held responsible for them. The research was partly (A.M., V.P. and A.I.P.) performed in …

phase compositionblanketsGeneral Chemical Engineeringlithium orthosilicatelithium-containing ceramicsGeneral Materials Science:NATURAL SCIENCES::Physics [Research Subject Categories]strengthblankets; lithium-containing ceramics; strength; hardness; phase composition; lithium orthosilicatehardnessNanomaterials; Volume 12; Issue 20; Pages: 3682
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On the high-pressure phase stability and elastic properties ofβ-titanium alloys

2017

We have studied the compressibility and stability of different β-titanium alloys at high pressure, including binary Ti–Mo, Ti–24Nb–4Zr–8Sn (Ti2448) and Ti–36Nb–2Ta–0.3O (gum metal). We observed stability of the β phase in these alloys to 40 GPa, well into the ω phase region in the P–T diagram of pure titanium. Gum metal was pressurised above 70 GPa and forms a phase with a crystal structure similar to the η phase of pure Ti. The bulk moduli determined for the different alloys range from 97  ±  3 GPa (Ti2448) to 124  ±  6 GPa (Ti–16.8Mo–0.13O).

phase stabilityMECHANISMMaterials scienceFluids & Plasmas0204 Condensed Matter PhysicsThermodynamicschemistry.chemical_element02 engineering and technologyCrystal structure01 natural sciencestitanium alloysPhase (matter)0103 physical sciencesGeneral Materials Sciencetitanium0912 Materials EngineeringSUPERELASTICITY010302 applied physicsScience & Technology1007 NanotechnologyPhase stabilityPhysicsDiagramMetallurgyGum metal021001 nanoscience & nanotechnologyCondensed Matter PhysicsTI-24NB-4ZR-8SNSTATEMARTENSITIC-TRANSFORMATIONPhysics Condensed Matterdiamond anvil cellchemistryMETALHigh pressurePhysical SciencesCompressibilityTI0210 nano-technologybiomaterialsTitaniumJournal of Physics: Condensed Matter
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Unravelling the Photocatalytic Behavior of All-Inorganic Mixed Halide Perovskites: The Role of Surface Chemical States

2019

Within the most mesmerizing materials in the world of optoelectronics, mixed halide perovskites (MHPs) have been distinguished because of the tunability of their optoelectronic properties, balancing both the light-harvesting efficiency and the charge extraction into highly efficient solar devices. This feature has drawn the attention of analogous hot topics as photocatalysis for carrying out more efficiently the degradation of organic compounds. However, the photo-oxidation ability of perovskite depends not only on its excellent light-harvesting properties but also on the surface chemical environment provided during its synthesis. Accordingly, we studied the role of surface chemical states …

photocatalytic activityMaterials scienceIodideHalide02 engineering and technology010402 general chemistry01 natural sciences7. Clean energyiodide vacanciesSurface chemicalGeneral Materials Sciencehot-injectionPerovskite (structure)chemistry.chemical_classificationanion-exchangedegradation pathwaysIon exchangesurface chemical states021001 nanoscience & nanotechnology0104 chemical sciencesNanocrystalChemical engineeringchemistryPhotocatalysisDegradation (geology)0210 nano-technologysuperoxide ions
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