Search results for " Mechanics of Materials"

Cohesive delamination and frictional contact on joining surface via XFEM

2018

In the present paper, the complex mechanical behaviour of the surfaces joining two different bodies is analysed by a cohesive-frictional interface constitutive model. The kinematical behaviour is characterized by the presence of discontinuous displacement fields, that take place at the internal connecting surfaces, both in the fully cohesive phase and in the delamination one. Generally, in order to catch discontinuous displacement fields, internal connecting surfaces (adhesive layers) are modelled by means of interface elements, which connect, node by node, the meshes of the joined bodies, requiring the mesh to be conforming to the geometry of the single bodies and to the relevant connectin…

Ultra-broad spectral photo-response in FePS3 air-stable devices

2021

Van der Waals materials with narrow energy gaps and efficient response over a broadband optical spectral range are key to widen the energy window of nanoscale optoelectronic devices. Here, we characterize FePS as an appealing narrow-gap p-type semiconductor with an efficient broadband photo-response, a high refractive index, and a remarkable resilience against air and light exposure. To enable fast prototyping, we provide a straightforward guideline to determine the thickness of few-layered FePS nanosheets extracted from the optical transmission characteristics of several flakes. The analysis of the electrical photo-response of FePS devices as a function of the excitation energy confirms a …

Iron and lithium-iron alkyl phosphates as nanostructured material for rechargeable batteries

2018

Abstract Inorganic/organic hybrid materials composed by iron atoms bonded to an alkyl phosphate can be easily synthesized by mixing at 110 °C iron chlorides with tri-alkyl phosphates. Since structural information on these products are lacking and taking into account that lithium/iron organic hybrid materials are important in lithium ion battery technology we report here the physico-chemical characterization of different hybrid lithium/iron butylphosphates. These materials are characterized by the presence of elongated hexagonal crystals stable up to 315 °C. The insertion of lithium does not affect the local structure. Thanks to such structures the material can be electrochemically-cycled an…

A numerical and experimental study through laser thermography for defect detection on metal additive manufactured parts

2017

Additive manufacturing has been recently employed in industrial sectors with the fundamental requirement for zero defect parts. Technological developments in additive manufacturing notwithstanding, there continues to be a scarcity of non-destructive inspection techniques to be exploited during the manufacturing process itself, thus limiting industrial advancements and extensive applications. Therefore, being able to integrate the defect inspection phase within the additive manufacturing process would open the way to enabling corrective actions on the component in itinere, that is, before reaching the final product. For this reason, new methods of in-process monitoring are gaining more and m…

Stress field model for strengthening of shear-flexure critical RC beams

2017

A model for the design of shear-flexure critical reinforced concrete elements strengthened with fiber-reinforced polymer (FRP) sheets and plates is presented. The model is based on the stress field approach and the equilibrium method and accounts for the different failure modes of FRP, focusing on the debonding of the FRP from the concrete surface. The efficiency of the model in the strength assessment of beams reinforced with FRP by the prediction of the shear-flexure capacity is checked by corroborating the results of several experimental tests found in the literature. Moreover, the presented model's capacity to reproduce experimental behavior is compared with the formulations suggested b…

Nanostructured Materials: Formation, Characterization, and Properties—Latest Advances in 1D, 2D, and 3D Nanostructures

2014

Use of pure vanadium and niobium/copper inserts for laser welding of titanium to stainless steel

2020

Abstract Niobium and vanadium have high metallurgical compatibility with titanium and therefore can be used as inserts to avoid the accumulation of brittle intermetallic phases such as Fe2Ti during the fusion welding of titanium alloys with steels. In the present study, the continuous double pass welding of 1 mm thick Ti-6Al-4V alloy and 316 L stainless steel plates through several mm wide pure vanadium or niobium insert was studied. In case of a vanadium insert, a beam offset on the vanadium was found to produce cold crack formation in vanadium/316 L melted zones containing more than 40 wt.% V despite the absence of σ phase. Whereas a centered beam position and offset on the steel side pro…

Tunable Eu2+ emission in KxNa1 − xLuS2 phosphors for white LED application

2016

Set of Eu2+-doped KxNa1 − xLuS2 phosphors (x = 0–1) in the form of transparent crystalline hexagonal platelets was successfully synthesized by chemical reaction under the flow of hydrogen sulfide. Their physical properties were investigated by means of X-ray diffraction, X-ray fluorescence, time-resolved luminescence spectroscopy and electron paramagnetic resonance. Special attention was given to photoluminescence emission spectra under the 395 nm and 455 nm excitation aiming to obtain white emission with tunable color temperature. EPR method was employed to understand the Eu2+ incorporation and distribution in the KxNa1 − xLuS2 hosts. CIE xy-coordinates were calculated to compare effects o…

Structure-properties relationships in melt reprocessed PLA/hydrotalcites nanocomposites

2017

In this work the effect of multiple reprocessing was studied on molecular structure, morphology and properties of poly(lactic acid)/hydrotalcites (PLA/HT) nanocomposites compared to neat PLA. In addition, the influence of two different kinds of HT – organically modified (OM-HT) and unmodified (U-HT) – was evaluated. Thermo-mechanical degradation was induced by means of five subsequent extrusion cycles. The performance of the recycled materials was investigated by mechanical and rheological tests, differential scanning calorimetry (DSC), intrinsic viscosity measurements and SEM observation. The results indicated that the best morphology was achieved in the systems incorporating OM-HT. On inc…

Processing – morphology – property relationships of polyamide 6/polyethylene blend–clay nanocomposites

2013

In this work, we studied the effect of the method of preparation and of reprocessing on the morphology and, con- sequently, on the physical properties of polyamide 6 (PA6)/ high density polyethylene (HDPE)-clay nanocomposite blends in the presence of different compatibilizers. In particular, the nanocomposites were obtained by melt mixing using a co- rotating twin screw extruder (E1). The blends thus obtained were re-extruded (E2) under the same operating conditions. Moreover, blends with the same final composition were produced using a masterbatch of the compatibilizer with the clay prepared in a separated stage in a batch mixer (MB). All the materials were characterized by scanning electr…