Search results for " Metals"
showing 10 items of 462 documents
On Mathematical Modelling of Metals Distribution in Peat Layers
2014
In this paper we consider averaging and finite difference methods for solving the 3-D boundary-value problem in multilayered domain. We consider the metals Fe and Ca concentration in the layered peat blocks. Using experimental data the mathematical model for calculation of concentration of metals in different points in peat layers is developed. A specific feature of these problems is that it is necessary to solve the 3-D boundary-value problems for elliptic type partial differential equations (PDEs) of second order with piece-wise diffusion coefficients in the layered domain. We develop here a finite-difference method for solving of a problem of one, two and three peat blocks with periodica…
Heavy metal sorption in biosorbents – Using spent grain from the brewing industry
2019
The sorption properties of brewer's spent grain (BSG) were assessed in terms of its usefulness in removing heavy metals from solutions. The specific objectives of the investigation involved studying sorption equilibrium and kinetics, assessing the influence of other cations on sorption efficiency, and examining the possibility of bed regeneration. The studies were carried out in a static system, with a constant ratio of solution volume to biosorbent mass, and using a flow through system. The affinity of metal cations to BSG functional groups was established and increased in the series: Mn2þzZn2þ < Ni2þ < Cd2þ < Cu2þ < Pb2þ. The BSG's sorption capacities (mmol g�1), determined using the Lang…
Presence of pharmaceuticals and heavy metals in the waters of a Mediterranean coastal wetland: Potential interactions and the influence of the enviro…
2015
The occurrence of 17 relevant pharmaceuticals and 7 heavy metals in the waters of the Pego-Oliva Marsh Natural Park (Valencia Community, Spain) were monitored. Thirty four zones (including the lagoon and the most important irrigation channels), covering the main land uses and water sources, were selected for sampling. Thirty three of them were contaminated with at least one pharmaceutical. Ibuprofen and codeine were the pharmaceuticals more frequently detected, in concentrations between 4.8 and 1.2 ng/L and a maximum of 59 ng/L and 63 ng/L, respectively.Regarding metals, Zn showed values under the detection limit in all the samples, while Cd, Co, Cr, Cu, Ni and Pb were detected at concentra…
Trace element accumulation and elutriate toxicity in surface sediment in northernTunisia (Tunis Gulf, southern Mediterranean)
2017
International audience; Metal concentrations in sediments were investigated in the Gulf of Tunis, Tunisia, in relation to anthropic activities along the Mejerda River and Ghar El Melh Lagoon, with effluents discharged into the gulf. Distribution of grain size showed that the silty fraction is dominant with 53%, while sand and clay averages are 34 and 12% respectively. Zn concentration increased in the vicinity of the Mejerda River while Pb was at its highest levels at the outlet of Ghar El Mehl Lagoon. Sediment elutriate toxicity, as measured by oyster embryo bioassays, ranged from 10 to 45% abnormalities after 24 h, but no relation was found between metal concentration and sediment toxicit…
Gull-derived trace elements trigger small-scale contamination in a remote Mediterranean nature reserve
2013
The role of a yellow-legged gull (Larus michahellis) small colony in conveying trace elements (As, Cd, Cr, Cu, Ni, Pb, THg, V, Zn) was assessed in a Mediterranean nature reserve (Marinello ponds) at various spatial and temporal scales. Trace element concentrations in guano were high and seasonally variable. In contrast, contamination in the ponds was not influenced by season but showed strong spatial variability among ponds, according to the different guano input. Biogenic enrichment factor B confirmed the role of gulls in the release of trace elements through guano subsidies. In addition, comparing trace element pond concentrations to the US NOAA’s SQGs, As, Cu and Ni showed contamination …
Discrimination of Lithogenic and Anthropogenic Metals in Calcareous Agricultural Soils: A Case Study of the Lower Vinalopó Region (SE Spain)
2008
Analysis of heavy metal concentrations in soils and their sources is required to identify agricultural areas affected by contamination on a regional level, according to the European Thematic Strategy for Soil Protection. Pseudo-total and EDTA-extractable concentrations of nine elements (Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb and Zn) in eighteen agricultural soils with vegetable crops in the Lower Vinalopo region (southeast Spain) were determined. The main aim was to assess the present state of the agricultural soils in relation to contamination processes by heavy metals for a representative area of the Mediterranean region under semiarid conditions. The pseudo-total concentrations for heavy metals …
GENE STRUCTURE, DIFFERENTIAL EXPRESSION AND PHYLOGENETIC ANALYSIS OF THE METALLOTHIONEIN GENE FAMILY OF THE SEA URCHIN PARACENTROTUS LIVIDUS
2017
Metallothioneins (MT) are small and cysteine-rich proteins that bind metal ions such as zinc, copper, cadmium, and nickel1. Several functions were proposed for these peptides, ranging from toxic metal protection to physiological metal homeostasis, free radical scavenging, oxidative stress protection, antiapoptotic defense, control of the redox status of the cell and also roles during development. Previously, we reported the identification of five different MT homologues (PlMT4-8) from the Mediterranean sea urchin species P. lividus2. In order to shed some light on MT gene structure and evolution, we cloned seven P. lividus MT genes, comparing them to Echinodermata and Chordata genes3. Moreo…
Shining castles and humans of metal/floral appearance ? metaphorical language in the Palaiologan romances Kallimachos and Velthandros
2019
About eight centuries after Heliodorus, the Greek novel resurfaced in the twelfth century, in Komnenian Byzantium, and again two centuries later under the Palaiologan dynasty. This latter literary revival was due to the political stability of the imperial Byzantine government, which promoted cultural production, rhetorical education, and patronage networks. Kallimachos and Velthandros, two Palaiologan romances presented as court literature, combine ancient and medieval tropes with rhetorical artistry to blur the boundaries between the artificial and the natural. Castles and objects made of precious metals thus resemble living, natural spaces, and human characters are portrayed in metallurgi…
Impact of hydrothermal alteration processes on element mobility and potential environmental implications at the Sousaki solfataric field (Corinthia -…
2020
Abstract Samples of efflorescences and encrustations of hydrothermal origin were collected at Sousaki (Greece) and analysed for their mineralogical (XRD) and chemical composition. Solutions obtained both from mineralization with HNO3 and from leaching with deionised water were analysed for major (ICP-OES), minor and trace metals (ICP-MS) and sulfate contents (IC). Results evidence the dependence of the chemical and mineralogical composition on micro-environmental conditions i.e. humidity, oxygen-rich or -poor environment, exposed or sheltered from meteoric agents. In fact, the presence of highly soluble sulfate minerals with elevated contents of many metals (e.g. Mg, Al, Fe, Mn, Cr, Ni, etc…
Synthesis of Tetrasubstituted 4,4'-Biimidazoles
2012
Highly substituted 4,4'-biimidazoles were synthesized, in good to excellent yields, through a multicomponent imidazole ring synthesis by using imidazol-4-yl-ethane-1,2-diones as starting materials. The obtained compounds were preliminarily tested as chromogenic and fluorescent sensors for heavy metals.