Search results for " Mixed"

Structural and Transport Properties of Bola C-16 Micelles in Water and in Aqueous Electrolyte Solutions

2003

Aqueous solutions containing a bolaform surfactant [R,ω-(4,7,10,13-pentaoxa-16-azacyclooctadecane)- hexadecane], with and without electrolytes have been investigated as a function of surfactant concentration and ionic strength. Small angle neutron scattering (SANS), NMR self-diffusion, and other physical-chemical methods were used. From the analysis of SANS data it was inferred that in water the surfactant forms slightly charged ellipsoidal micelles, because of the partial hydrolysis of amino groups. The aggregates grow with the increase of concentration, becoming more elongated. Due to the selective complexing ability of aza crown ether units, significant differences were observed upon add…

Iodine speciation in rain, snow and aerosols

2008

Iodine oxides, such as iodate, should be the only thermodynamically stable sink species for iodine in the troposphere. However, field observations have increasingly found very little iodate and significant amounts of iodide and soluble organically bound iodine (SOI) in precipitation and aerosols. The aim of this study was to investigate iodine speciation, including the organic fraction, in rain, snow, and aerosols in an attempt to further clarify aqueous phase iodine chemistry. Diurnal aerosol samples were taken with a 5 stage cascade impactor and a virtual impactor (PM<sub>2.5</sub>) from the Mace Head research station, Ireland, during summer 2006. Rain was collected from Austr…

A PARTITION TYPE METHOD FOR CLUSTERING MIXED DATA

1990

In this paper, we propose a method for clustering mixed data. The method is a nonhierarchical one, and deals simultaneously with variables of three main kinds: numerical, ordinal, and nominal. It is based on the minimization of a particular criterion f(G。) over all the partitions G。of n entities in m distinct clusters. The criterion is founded on a peculiar kind of internal standardized mean diversity of the entities, according to the three types of variables. The algorithm to get the best partition is also presented: it starts from a non-random choice of the first partition; the results are compared with those obtained by a random assignment to a first partition. In order to show the usefu…

Uso della moneta presso gli Indigeni della Sicilia centro-meridionale

2011

The study of the coins found in the indigenous settlements of Caltanissetta province and the analysis of the related contexts of provenance, have highlighted that in these centers, still in the 4th century BC, the coin was considered a worthless piece of metal and that other bronze objects were used as medium of exchange. It is remarkable the discovery in this territory of three “mixed” hoards, including not only coins, but also of bronze scraps and small fragmentary objects. In this regard, the presence in this area of the so-called "monetary barbarizations" is interesting. They are rare specimens whose stylistic aspect, typological association, technical and, sometimes, even weight elemen…

Food for flight: pre-migratory dynamics of the Lesser Kestrel Falco naumanni.

2014

Capsule The post-reproductive stage of Lesser Kestrel is crucial for migratory fuelling and survival. Aims To describe the summer pre-migratory ecology of the Lesser Kestrel in Sicily and review existing data in Southern Europe. Methods We identified the main summer roosts and then made roost counts every ten days from 2010 to 2012. We used case-sensitive modelling procedures to detect biases in counts (generalized linear mixed models), assess the annual population trends from 2005 to 2012 (TRends and Indices for Monitoring); and to model habitat preferences (generalized linear model). We sampled pellets to describe the birds’ diet during the peak month prior to migration. Results We discov…

Behaviour of the erythrocyte deformability and nitric oxide metabolites in unprofessional athletes

2009

Enhancement of Hydrolysis through the Formation of Mixed Heterometal Species: Al3+/CH3Sn3+ Mixtures

2013

ABSTRACT: The hydrolysis of mixed-metal cations (Al3+/CH3Sn3+) was studied in aqueous solutions of NaNO3, at I = 1.00 ± 0.05 mol·dm−3 and T = 298.15 K, by potentiometric technique. Several hydrolytic mixed species are formed in this mixed system, namely, Alp(CH3Sn)q(OH)r with (p, q, r) = (1, 1, 4), (1, 1, 5), (1, 1, 6), (2, 1, 4), (1, 2, 5), (1, 4, 11), (1, 3, 8), and (7, 6, 32). The stability of these species, expressed by the equilibrium: pAl3+ + qCH3Sn3+ + rOH− = Alp(CH3Sn)q(OH)r 3(p+q)−r, βpqr OH, can be modeled by the empirical relationship: log βpqr OH = −3.34 + 2.67p + 9.23(q + r). By using the equilibrium constant Xpqr relative to the formation reaction: pAl(p+q)(OH)r + q(CH3Sn)(p+q…

Item Response Trees: a recommended method for analyzing categorical data in behavioral studies

2015

Behavioral data are notable for presenting challenges to their statistical analysis, often due to the difficulties in measuring behavior on a quantitative scale. Instead, a range of qualitative alternative responses is recorded. These can often be understood as the outcome of a sequence of binary decisions. For example, faced by a predator, an individual may decide to flee or stay. If it stays, it may decide to freeze or display a threat and if it displays a threat, it may choose from several alternative forms of display. Here we argue that instead of being analyzed using traditional nonparametric statistics or a series of separate analyses split by response categories, this kind of data ca…

Comparison between the MHFEM formulation and a 2nd spatial order FV formulation of the linear ground problem

2008

Comparison of different 2nd order formulations for the solution of the 2D groundwater flow problem over irregular triangular meshes

2009

Mixed and Mixed Hybrid Finite Elements (MHFE) methods have been widely used in the last decade for simulation of groundwater flow problem, petroleum reservoir problems, potential flow problems, etc. The main advantage of these methods is that, unlike the classical Galerkin approach, they guarantee local and global mass balance, as well the flux continuity between inter-element sides. The simple shape of the control volume, where the mass conservation is satisfied, makes also easier to couple this technique with a Finite Volume technique in the time splitting approach for the solution of advection-dispersion problems. In the present paper, a new MHFE formulation is proposed for the solution …