Search results for " Mobility"

New conducting radical salts based upon Keggin-type polyoxometalates and perylene

2004

Three new radical salts, Per6[PMo12O40]·CH2Cl2 (1), Per6[PMo12O40]·CH3CN (2), and Per9(NBu4)4[SiW12O40]2 (3) (Per = perylene), have been synthesised and their electrical and magnetic properties characterised. These three salts are diamagnetic and they behave as semiconductors with room temperature conductivities of 69, 3.6 and 0.85 S cm−1. While salt 2 presents hole-type conduction and 3 exhibits electron-dominated electrical transport properties, salt 1 shows at 150 K an abrupt change in the thermal dependence of the electrical conductivity and the Seebeck coefficient suggesting a phase transition.

2004

β-oxidation of long and very long chain fatty acyl-CoA derivatives occurs in peroxisomes, which are ubiquitous subcellular organelles of eukaryotic cells. This pathway releases acetyl-CoA as precursor for several key molecules such as cholesterol. Numerous enzymes participating to cholesterol and fatty acids biosynthesis pathways are co-localized in peroxisomes and some of their encoding genes are known as targets of the NFY transcriptional regulator. However, until now no interaction between NFY transcription factor and genes encoding peroxisomal β-oxidation has been reported. This work studied the interactions between NFY factor with the rat gene promoters of two enzymes of the fatty acid…

Increased conformational rigidity of humic substances by oxidative biomimetic catalysis

2005

A synthetic water-soluble meso-tetra(2,6-dichloro-3-sulfonatophenyl)porphyrinate of iron(III) chloride, Fe(TDCPPS)Cl, was employed as a biomimetic catalyst in the oxidative coupling of terrestrial humic materials. High-performance size-exclusion chromatography (HPSEC), solid-state nuclear magnetic resonance (CPMAS-(13)C NMR), electron paramagnetic resonance (EPR), and diffuse reflectance infrared spectroscopy (DRIFT) were used to follow conformational and structural changes brought about in different humic materials by the oxidative coupling. Increase in apparent weight-average molecular weight (Mw(a)) occurred invariably for all humic substances with the oxidative polymerization catalyzed …

El lujo cambiante. El vestido y la difusión de las modas en la Corona de Aragón (siglos XIII-XV)

2015

La apariencia física de las persona era ya en la Baja Edad Media el primer indicativo de su condición social, pero en un período mucho más urbanizado e interconectado que los anteriores, el refinamiento de la indumentaria se convirtió en un hecho con unas connotaciones económicas, políticas y culturales de gran calado. El mismo incremento de la movilidad social llevó además a que no bastara con invertir grandes sumas en la propia imagen, sino que fuera necesario estar atento a los cambios de eso que llamamos “moda”, cuyos orígenes se suelen situar en estos momentos en los que las clases dominantes tradicionales buscaban nuevos elementos de diferenciación frente a los advenedizos. Todo ello …

ISSP position stand : Transnationalism, mobility, and acculturation in and through sport

2017

The historically unprecedented pace of internationalising sport industry and transnational movement of athletic talent in the last 20 years has heightened the need for developing new competencies in research and daily practice of sport psychology professionals. While academic literature in cultural sport psychology and praxis has been increasing, sport professionals and local organisations seem to give scant time and resources to stay abreast of complex social changes in transnational industry and to the development of cultural competencies. Stemming from the continuing need for qualified athletic personnel to support transitioning athletes and to achieve intercultural effectiveness in dail…

Unravelling the rationalities of childhood cycling promotion

2022

Decrease of children’s independent mobility (CIM) has worried academics, policymakers, educators and other professionals for decades. Research and policy often emphasise that promoting children’s physically active and independent transport modes as cycling is important to achieve better public health, solve environmental challenges and increase related economic benefits. Yet, cycling promotion is not a neutral process and all promotion efforts are derived from latent notions of ‘cyclists’ and ‘cycling’. This paper discusses different rationalities of childhood cycling promotion and the representations of ‘children’ as independent ‘cyclists’ they entail. We argue that in order to efficiently…

Towards sustainable mobility : Transformative scenarios for 2034

2022

Highlights • Increasing the share of walking and cycling is one of the building blocks of sustainable mobility transformation. • We organised an online Delphi survey for 30 walking and cycling experts during the first wave of COVID-19 pandemic. • Disaggregative Delphi analysis is elaborated based on the systemic restructuring of qualitative data. • Transport experts’ views of the future are described in the form of five walking and cycling scenarios up to 2034. • The results can be used for strategic transport planning and policy, and for identifying instruments for walking and cycling promotion in urban areas. Increasing the share of walking and cycling is one of the building blocks of sus…

Modelling daily mobility according to actors strategies

2015

International audience

Public Choices and Decision-making Processes: A Case Study on Sustainable Mobility

2017

The definition of a decision process, which implies the capacity to implement and realize an action involving all the actors interested, is crucial not only for taking adequate political decisions but even mainly for getting a democratic control of the decisions themselves. From a strategic planning point of view, decision process on public issues should be essentially considered as a process of participation, which involves political decision-makers as well as all the administrative organizations which have to realize the decisions taken and citizens and more generally all the stakeholders who will be impacted in a positive or negative way by such decisions. If this is the case, important …

Evaluating the impact of external job mobility on three health outcomes: a longitudinal study of the IDEWE cohort of Belgian workers

2022

There is large debate in the literature about the relationship between job mobility and health. This thesis contributes to this topic by estimating the impact of work mobility on either cardiovascular, musculoskeletal or neuropsychological diseases in a longitudinal study on a sample of Belgian workers followed-up for seven-years. The occurrence of such diseases was assessed through medication use as proxy. In the first part of this thesis, the focus was on CVD and MSD diseases. To this aim, a logistic regression model for autocorrelated data with repeated measures was applied (while controlling for the time-variant and time-invariant confounders). This longitudinal model was adequate to ta…