Search results for " Mobility"

Simultaneous endo and exo  Complex Formation of Pyridine[4]arene Dimers with Neutral and Anionic Guests

2017

The formation of complexes between hexafluorophosphate (PF6- ) and tetraisobutyloctahydroxypyridine[4]arene has been thoroughly studied in the gas phase (ESI-QTOF-MS, IM-MS, DFT calculations), in the solid state (X-ray crystallography), and in chloroform solution (1 H, 19 F, and DOSY NMR spectroscopy). In all states of matter, simultaneous endo complexation of solvent molecules and exo complexation of a PF6- anion within a pyridine[4]arene dimer was observed. While similar ternary complexes are often observed in the solid state, this is a unique example of such behavior in the gas phase.

Ion mobility mass spectrometry – an efficient tool for the analysis of conformational switch of macrocyclic receptors upon anion binding

2021

Interactions between anions and synthetic macrocyclic receptors belong to the extensively explored area of research due to the particularly important functions of anions in biological and environmental sciences. Structures of anion-macrocycle complexes are closely related to their function, highlighting the importance of structural analysis of the complexes. Here, we discuss the application of ion mobility mass spectrometry (IM-MS) and theoretical calculations to the structural analysis of tetralactam macrocycles (M) with varying flexibility and structural properties, and their complexes with anions [M + X]−. Collision cross section (CCS) values obtained from both direct drift tube (DT) and…

The effects of a subvention scheme for e-bikes on mode share and active mobility

2022

Hanne Beate Sundfør, Aslak Fyhri, The effects of a subvention scheme for e-bikes on mode share and active mobility, Journal of Transport & Health, Volume 26, 2022, 101403, ISSN 2214-1405, https://doi.org/10.1016/j.jth.2022.101403 (https://www.sciencedirect.com/science/article/pii/S2214140522000755) Introduction Previous studies show substantial mode share effects from e-bikes. E-bike owners cycle more and drive less car than they would without access to an e-bike. Support schemes for e-bikes exist in a number of countries, but knowledge about the effect of subsidies on active transport is limited. The aim of this study is to assess the mode change and active mobility effects of a subvention…

Vertical mobility: a multi-faceted tool for enhancing architectural heritage

2020

Vertical mobility plays a key role in the accessibility of architectural heritage: an ex- traneous requisite, but indispensable for enhancing the built heritage in an inclusive way. In this framework, in the light of their multiple technological features, mechanical devices will be discussed, taking into account the interaction with the users (individuals and community). Urban and architectural design in the historical context is very often confronted with vertical mobility, in the relationships between fragmented spaces and the perceptive processes of the user. The mechanical devices can be read at the same time as technological products and as iconic moments of the narrative sequence of d…

Photoconductivity in the columnar phases of a glassy discotic twin

1995

2012

Abstract. One of the major uncertainties in the understanding of Earth's climate system is the interaction between solar radiation and aerosols in the atmosphere. Aerosols exposed to high humidity will change their chemical, physical, and optical properties due to their increased water content. To model hydrated aerosols, atmospheric chemistry and climate models often use the volume weighted mixing rule to predict the complex refractive index (RI) of aerosols when they interact with high relative humidity, and, in general, assume homogeneous mixing. This study explores the validity of these assumptions. A humidified cavity ring down aerosol spectrometer (CRD-AS) and a tandem hygroscopic DMA…

Nano-hygroscopicity tandem differential mobility analyzer (nano-HTDMA) for investigating hygroscopic properties of sub-10 nm aerosol nanoparticles

2020

Interactions between water and nanoparticles are relevant for atmospheric multiphase processes, physical chemistry, and materials science. Current knowledge of the hygroscopic and related physicochemical properties of nanoparticles, however, is restricted by the limitations of the available measurement techniques. Here, we present the design and performance of a nano-hygroscopicity tandem differential mobility analyzer (nano-HTDMA) apparatus that enables high accuracy and precision in hygroscopic growth measurements of aerosol nanoparticles with diameters less than 10 nm. Detailed methods of calibration and validation are provided. Besides maintaining accurate and stable sheath and a…

Hygroscopic properties and water-soluble volume fraction of atmospheric particles in the diameter range from 50 nm to 3.8 μm during LACE 98

2002

[1] Hygroscopic properties of atmospheric aerosol particles in the Aitken, large, and giant particle range were studied during the Lindenberg Aerosol Characterization Experiment (LACE 98) in a rural area 80 km southeast of Berlin. The hygroscopic behavior of Aitken particles were determined in situ in four size classes (50, 100, 150, 250 nm) with a Hygroscopic Tandem Differential Mobility Analyzer for relative humidities (RH) of 60% and 90%. Measurements at 60% RH served as reference data used by other LACE 98 investigators for mass closure and radiative transfer calculations. In most cases, at 90% RH, the atmospheric particles could be classified into two groups (“more” and “less” hygrosco…

Airborne investigation of the aerosols–cloud interactions in the vicinity and within a marine stratocumulus over the North Sea during EUCAARI (2008)

2013

Abstract Within the European Aerosol Cloud Climate and Air Quality Interactions (EUCAARI) project, the Meteo France research aircraft ATR-42 was operated from Rotterdam (Netherlands) airport during May 2008, to perform scientific flights dedicated to the investigation of aerosol–cloud interactions. The objective of this study is to illustrate the impact of cloud processing on the aerosol particle physical and chemical properties. The presented results are retrieved from measurements during flight operation with two consecutive flights, first from Rotterdam to Newcastle (United Kingdom) and subsequently reverse along the same waypoints back to Rotterdam using data measured with compact Time …

MACC regional multi-model ensemble simulations of birch pollen dispersion in Europe

2015

Abstract. This paper presents the first ensemble modelling experiment in relation to birch pollen in Europe. The seven-model European ensemble of MACC-ENS, tested in trial simulations over the flowering season of 2010, was run through the flowering season of 2013. The simulations have been compared with observations in 11 countries, all members of the European Aeroallergen Network, for both individual models and the ensemble mean and median. It is shown that the models successfully reproduced the timing of the very late season of 2013, generally within a couple of days from the observed start of the season. The end of the season was generally predicted later than observed, by 5 days or more…