Search results for " Montmorillonite"
showing 10 items of 21 documents
Kinetic and equilibrium studies for the adsorption of acid nucleic bases onto K10 montmorillonite
2011
Abstract The kinetic of the adsorption of two nucleic acid bases, namely adenine (A) and cytosine (C), on K10 montmorillonite (MMT) clay has been investigated over a wide range of nitrogenous bases concentrations, by using the spectrophotometric method. The measurements have been performed at T = 25.0 °C and pH = 4.0 where adenine and cytosine exist both in their protonated and neutral forms. Preliminary to the kinetic data treatment, the adsorption isotherms have been gathered and, then, analyzed by using the Freundlich and the Dubinin–Radushkevich model. The obtained results allow to draw the conclusion that physisorption of adenine and cytosine on MMT occurs and the process is mainly gov…
Photo-stabilization of biopolymers-based nanocomposites with UV-modified layered silicates
2020
Abstract Eco-friendly in-situ stabilised biopolymer nanocomposites based on polyamide 11 (PA11) and polylactic acid (PLA) were prepared by melt mixing in the presence of a modified organo-montmorillonite clay containing a chemically-bound hindered amine UV-stabilising function, [(UV)OM-MMt]. Characterisation of the newly synthesised organo-modifier containing the reactive hindered amine (HAS) UV-stabilising function [(UV)OM] has confirmed a successful synthesis. The (UV)OM was then introduced into NaMMt through ion exchange reaction to prepare the UV stabiliser-bound organo-modified-MMt, [(UV)OM-MMt]. The in-situ stabilised PA11- and PLA- nanocomposites (PA11-(UV)OM-MMt and PLA-(UV)OM-MMt) …
Thermomechanical Characterization of Polylactic Acid and Composites
2018
This paper presents the experimental tests for the thermomechanical characterization of biopolymer polylactic acid, and its composites with beech flour or with nanoreiforcement of modified montmorillonite, in order to evaluate any applicability in the automotive sector. Tests of torque and traction are executed for the mechanical characterization and the results comparison; dynamical tests are executed for the thermomechanical characterization, determining the elastic modulus and loss factor versus the actual temperature.
Caratterizzazione termomeccanica dell’acido polilattico e due suoi compositi
2018
Questa memoria presenta i test sperimentali per la caratterizzazione termomeccanica del biopolimero acido polilattico e dei suoi compositi con farina di faggio o con nanorinforzo di montmorillonite modifcata, per uno studio di applicabilità nel settore automobilistico. Per la caratterizzazione meccanica e il confronto dei risultati vengono eseguiti prove di coppia e di trazione; i test dinamici vengono eseguiti per la caratterizzazione termomeccanica, determinando il modulo elastico e il fattore di perdita rispetto alla temperatura effettiva. This paper presents the experimental tests for the thermomechanical characterization of biopolymer polylactic acid, and its composites with beech flour…
POLYCHLORINATED BIPHENYLS ADSORPTION ONTO ALGINATE BEADS AND HYBRID ALGINATE MONTMORILLONITE BEADS: ISOTHERMAL AND KINETIC STUDIES
2013
Olive mill wastewaters decontamination based on organo-nano-clay composites
2019
Abstract Green composites for environmental applications were successfully prepared by intercalation of the biosurfactant Quillaja saponin onto montmorillonite mineral clay on varying pH and surfactant/clay ratio. Equilibrium adsorption isotherms were constructed and the system was characterized by performing TGA and XRD analyses. The efficiency of the surfactant-modified clay in the removal of the organic content present in olive mill wastewaters (OMW) was evaluated by means of spectrophotometric measurements. The interest for this cogent issue comes from the consideration that, despite their high pollutant content, OMW can be considered as a potential resource of several organic compounds…
New tailor-made bio-organoclays for the remediation of olive mill waste water
2013
A systematic study aimed at obtaining new organoclays for the treatment of Olive Mill Waste water (OMW) has been performed. Several organoclays have been prepared by loading different amounts of the biocompatible surfactant Tween20 onto the K10 montmorillonite (MMT). Complementary kinetic and equilibrium studies on the adsorption of the Tween20 onto the MMT have been carried out and the characterization of the new tailor-made bio-materials has been performed by means of the XRD and FT-IR measurements. Finally the prepared bio-organoclays have been successfully applied for the OMW remediation and they proved to be highly effective in decreasing the organic content (OC) to an extent that depe…