Search results for " NANOTUBES"
showing 10 items of 289 documents
Radical scavenging activity of ultrasound-treated Carbon Nanotubes
2016
Carbon nanotubes (CNTs) having controlled radical activity have been achieved tuning the content of their lattice defects induced by an ultra-sound (us) treatment.
Unravelling Radicals Reactivity Towards Carbon Nanotubes Manipulation/Functionalization
2016
Carbon Nanotubes (CNTs) chemistry is under constant evolution, as a consequence of the deep interest of the scientific community in finding new applications for these versatile materials. New and old synthetic protocols are used for improving the control of the functionalization degree of the final materials and for offering to scientists the possibility to fine-tune their final properties. In this Review, we focus the attention on radical reactions, a class of protocols characterized by small number of steps, different degrees of functionalization and enhanced solubility of the final modified CNTs, in the desired environment. The most well-known protocols are analysed providing some releva…
Carbocatalytic Oxidative Dehydrogenative Couplings of (Hetero)Aryls by Oxidized Multi‐Walled Carbon Nanotubes in Liquid Phase
2019
HNO3-oxidized carbon nanotubes catalyze oxidative dehydrogenative (ODH) carbon-carbon bond formation between electron-rich (hetero)aryls with O-2 as a terminal oxidant. The recyclable carbocatalytic method provides a convenient and an operationally easy synthetic protocol for accessing various benzofused homodimers, biaryls, triphenylenes, and related benzofused heteroaryls that are highly useful frameworks for material chemistry applications. Carbonyls/quinones are the catalytically active site of the carbocatalyst as indicated by model compounds and titration experiments. Further investigations of the reaction mechanism with a combination of experimental and DFT methods support the compet…
Modelling of protonation constants of halloysite clay nanotubes in various aqueous media, at different ionic strengths
2015
In the last decade nanoparticles have assumed more and more importance because of their particular properties mainly due to the nanometer-scale dimensions that confer them a large surface/volume ratio. Among nanomaterials one of the most studied is the halloysite that, as well as the other natural clay minerals is safe for human and environmental friendly. Halloysite is abundant and cheap and is present in large deposits worldwide like those in New Zealand, France, Belgium and China [1,2]. It is similar to kaolin but has a hollow tubular structure that can be attributable to particular crystallization conditions. Typically, halloysite nanotubes (HNTs) are formed by 15 – 20 aluminosilicate l…
Chemical Modification of Carbon Nanotubes with Sulfonylamides
LIQUIDI IONICI E FULLERENI: PIATTAFORME PER NUOVI MATERIALI
The synthesis of innovative catalysts based on different carbon nanoforms (CNFs), namely fullerene C60 and carbon nanotubes (CNTs), and their application in Suzuki and Heck C-C coupling reactions, constitutes the common thread of the first part (Chapter 1 and 2) of this thesis. C60 and CNTs were functionalized with ionic liquids (ILs) and poly-amidoamine (PAMAM) dendrimers, respectively, and used as supports for palladium nanoparticles (PdNPs). Moreover, additional supported catalytic systems based on one of the synthesized C60-IL hybrids were prepared and successfully employed in the title coupling reactions. The final part (Chapter 3) of the thesis deals on the microwave-mediated synthesi…
Electrical Properties of Single and Multiwall Carbon Nanotubes Under Mechanical Deformations
2004
Electronic and Transport Properties of Single and Multiwall Carbon Nanotubes under Mechanical Deformations
2009
Electrical conductance in carbon nanotubes under mechanical deformation
2013
Electromechanical behavior of carbon nanotubes under traction, bending, torsion and misalignment of the two ends
2011
Carbon nanotubes (CNTs) can be metallic or semiconductors depending simply on geometric characteristics [e.g., 1]. This peculiar electronic behavior, combined with high mechanical strength, make them potential building blocks of a new nano-electronic technology. Most discussions of the electronic structure of CNTs assume perfect cylindrical symmetry, but this is somewhat of an oversimplification. High resolution images of CNTs often disclose structural deformations such as bent, twisted, or collapsed tubes. These deformations may develop during growth, deposition, and processing, or upon interaction with other CNTs, and with surfaces and surface features such as electrodes. Deformations bre…