Search results for " Nanoparticle"
showing 10 items of 936 documents
Photochemical preparation of polyaminocyclodextrin-capped silver nanocomposites: mechanistic insights
2016
Photoreduction of silver salts in the presence of three polyaminocyclodextrin derivatives (AmCD, Figure 1) constitutes a simple and straightforward route to obtain stable Ag nanoparticles. These systems have been suitably characterized (UV-vis, FT-IR, TEM, Figure 2) and tested for their antimicrobial activity.1 We observed that Ag photoreduction is effectively induced by irradiation with green light (513 nm); however, best performances are achieved with the use of a light source having at the same time a significant emission in the near-infrared (NIR) region. On the grounds of analytical and kinetic evidences, we hypothesized a multi-step mechanism for nanoparticle formation. In particular,…
Switching the Magnetic Vortex Core in a Single Nanoparticle.
2016
Imaging and manipulating the spin structure of nano- and mesoscale magnetic systems is a challenging topic in magnetism, yielding a wide range of spin phenomena such as skyrmions, hedgehog-like spin structures, or vortices. A key example has been provided by the vortex spin texture, which can be addressed in four independent states of magnetization, enabling the development of multibit magnetic storage media. Most of the works devoted to the study of the magnetization reversal mechanisms of the magnetic vortices have been focused on micrometer-size magnetic platelets. Here we report the experimental observation of the vortex state formation and annihilation in individual 25 nm molecular-bas…
Surface contribution to the anisotropy of magnetic nanoparticles.
2002
We calculate the contribution of the Neel surface anisotropy to the effective anisotropy of magnetic nanoparticles of spherical shape cut out of a simple cubic lattice. The effective anisotropy arises because deviations of atomic magnetizations from collinearity and thus the energy depends on the orientation of the global magnetization. The result is second order in the Neel surface anisotropy, scales with the particle volume and has cubic symmetry with preferred directions [+-1,+-1,+-1].
Neutron Scattering in Nanomagnetism
2015
Abstract Polarized neutron reflectometry (PNR) has played an essential role for the exploration of nanomagnetic and spintronic materials, including exchange coupled magnetic superlattices, exchange bias systems between ferromagnetic and antiferromagnetic films, spin valves, exchange springs between soft and hard magnetic films, superconducting proximity effects, periodic lateral magnetic patterns, and magnetic nanoparticles. The main virtues of PNR are depth-resolved vector magnetometry in the film plane, high sensitivity to magnetic interfaces, and statistical analysis of magnetic domain fluctuations. Recently the capabilities of PNR have been carried over from steady state to dynamic inve…
Particle Plasmons as Dipole Antennas: State Representation of Relative Observables
2018
The strong interactions between light and plasmons (in metal nanoparticles) allow to observe chemical and physical processes on and around the particle on nanometer length scales as well as they al...
Rotating-field-driven ensembles of magnetic particles.
2019
Vortex patterns in ensembles of magnetic particles driven by a rotating field are studied. The driving arises due to the lubrication forces between the rotating particles acting in the direction perpendicular to the radius vector between the particles. Since the lubrication forces cannot be equilibrated by the radial forces due to the dipolar attraction and steric repulsion, the ensemble is in a nonequilibrium state. Different regimes are found for the dynamics of the driven ensembles---solid-body rotation at low frequency of the rotating field and stick-slip motion of the external layers of the aggregate with respect to the internal structure as the frequency is increased. The relation obt…
A magnetic source imaging camera
2016
We describe a magnetic source imaging camera (MSIC) allowing a direct dynamic visualization of the two-dimensional spatial distribution of the individual components Bx(x,y), By(x,y) and Bz(x,y) of a magnetic field. The field patterns allow—in principle— a reconstruction of the distribution of sources that produce the field B→ by inverse problem analysis. We compare experimentally recorded point-spread functions, i.e., field patterns produced by point-like magnetic dipoles of different orientations with anticipated field patterns. Currently, the MSIC can resolve fields of ≈10 pT (1 s measurement time) range in a field of view up to ∼20 × 20 mm2. The device has a large range of possible appli…
A microscopic approach to Casimir and Casimir-Polder forces between metallic bodies
2014
We consider the Casimir-Polder interaction energy between a metallic nanoparticle and a metallic plate, as well as the Casimir interaction energy between two macroscopic metal plates, in terms of the many-body dispersion interactions between their constituents. Expressions for two- and three-body dispersion interactions between the microscopic parts of a real metal are first obtained, both in the retarded and non-retarded limits. These expressions are then used to evaluate, a compare each other, the overall two- and three-body contributions to the macroscopic Casimir-Polder and Casimir force, by summing up the contributions from the microscopic constituents of the bodies (metal nanoparticle…
Dynamics of anisotropic superparamagnetic particles in a precessing magnetic field.
2013
A bifurcation diagram for anisotropic magnetic particles in a precessing magnetic field is analyzed. It is found that a synchronous regime in the case of a prolate particle exists for all precession angles of the magnetic field if the frequency of field rotation is below some critical value. An oblate particle has a synchronous regime in a limited range of precession angle. To understand the flow of suspensions of these particles in precessing fields, it is essential to take into account the differing dynamics of prolate and oblate particles.
Dynamics of an active magnetic particle in a rotating magnetic field.
2006
The motion of an active (self-propelling) particle with a permanent magnetic moment under the action of a rotating magnetic field is considered. We show that below a critical frequency of the external field the trajectory of a particle is a circle. For frequencies slightly above the critical point the particle moves on an approximately circular trajectory and from time to time jumps to another region of space. Symmetry of the particle trajectory depends on the commensurability of the field period and the period of the orientational motion of the particle. We also show how our results can be used to study the properties of naturally occurring active magnetic particles, so-called magnetotacti…