Search results for " Optics"

showing 10 items of 5880 documents

Shaping of a ground state rotational wavepacket by frequency-chirped pulses

2001

0953-4075; A coherent rotational superposition state is produced in the ground vibronic level of N2 through the interaction of the molecule with the electric field vector of a nonresonant laser pulse. This rotational wavepacket is shaped with a linear frequency chirp of the laser field. The structural shape of the rotational coherences shows a strong dependence with the frequency-chirp amplitude. A comparison with a theoretical model allows the interpretation of the observed effects in terms of dephasing of the wavepacket induced by the laser phase distortion. Application of the presented results to the phase characterization of short XUV pulses is suggested.

CONTROLDephasingPhase (waves)Physics::Opticslaw.inventionCOHERENTSuperposition principleINDUCED POLARIZATION SPECTROSCOPYlawPhysics::Atomic and Molecular ClustersChirpPhysics::Atomic PhysicsFIELDFEMTOSECOND LASER-PULSESINTERFERENCEPhysicsPhase distortionPHOTODISSOCIATIONCondensed Matter PhysicsLaserEVOLUTIONN-2Atomic and Molecular Physics and OpticsAmplitudeAtomic physicsGround stateJournal of Physics B: Atomic, Molecular and Optical Physics
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Controlling molecular alignment rephasing through interference of Raman-induced rotational coherence

2000

0021-9606; Quantum control over molecular alignment rephasing is experimentally investigated in gaseous CO2. The control process is achieved by illuminating the medium with a pair of pump-pulses separated in time by approximately an integer value of T0=1/8B(0), where B(0) is the rotational constant. Through a Raman-type process, each pulse alone produces rotational coherence leading to a periodic orientational anisotropy. It is the combination of the two pulses that yields to quantum interference, resulting in a modification of this anisotropy probed by a third delayed pulse. The effect is accurately analyzed for different time delays between the two pulses. A theoretical analysis supplies …

CONTROLGeneral Physics and AstronomyRotational transitionTRANSITIONS01 natural sciencesMolecular physicssymbols.namesakeOpticsINDUCED POLARIZATION SPECTROSCOPYTIME-RESOLVED DYNAMICSMULTIPHOTON IONIZATIONSYSTEMSElectric field0103 physical sciencesPhysical and Theoretical ChemistryMolecular alignmentFIELD010306 general physicsAnisotropyPhysicsQuantum optics010304 chemical physicsbusiness.industryWAVE-PACKETSPHOTODISSOCIATIONINDUCED CONTINUUM STRUCTUREsymbolsLASERRotational spectroscopyRaman spectroscopybusinessCoherence (physics)
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Advances in High-Energy-Resolution CdZnTe Linear Array Pixel Detectors with Fast and Low Noise Readout Electronics

2023

Radiation detectors based on Cadmium Zinc Telluride (CZT) compounds are becoming popular solutions thanks to their high detection efficiency, room temperature operation, and to their reliability in compact detection systems for medical, astrophysical, or industrial applications. However, despite a huge effort to improve the technological process, CZT detectors’ full potential has not been completely exploited when both high spatial and energy resolution are required by the application, especially at low energies (<10 keV), limiting their application in energy-resolved photon counting (ERPC) systems. This gap can also be attributed to the lack of dedicated front-end electronics whic…

CZTSettore FIS/01 - Fisica SperimentaleX-ray spectroscopyCdZnTeGamma-ray spectroscopyElectrical and Electronic EngineeringBiochemistryInstrumentationSettore FIS/07 - Fisica Applicata(Beni Culturali Ambientali Biol.e Medicin)nuclear microelectronicsAtomic and Molecular Physics and Opticssemiconductor radiation detectorsAnalytical ChemistrySensors
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Quantitative Raman spectroscopy as a tool to study the kinetics and formation mechanism of carbonates

2013

We have carried out a systematic study of abiotic precipitation at different temperatures of several Mg and Ca carbonates (calcite, nesquehonite, hydrocalcite) present in carbonaceous chondrites. This study highlights the capability of Raman spectroscopy as a primary tool for performing full mineralogical analysis. The precipitation reaction and the structure of the resulting carbonates were monitored and identified with Raman spectroscopy. Raman spectroscopy enabled us to confirm that the precipitation reaction is very fast (minutes) when Ca(II) is present in the solution, whereas for Mg(II) such reactions developed at rather slow rates (weeks). We also observed that both the composition a…

CalciteReaction mechanismChemistryPrecipitation (chemistry)KineticsAnalytical chemistrySpectrum Analysis RamanAtomic and Molecular Physics and OpticsCalcium CarbonateAnalytical ChemistryKineticssymbols.namesakechemistry.chemical_compoundX-Ray DiffractionChondriteX-ray crystallographysymbolsChemical PrecipitationMagnesiumRaman spectroscopyInstrumentationSpectroscopySpectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
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Canonical versus microcanonical analysis of first-order phase transitions

1998

Abstract I discuss the relation between canonical and microcanonical analyses of first-order phase transitions. In particular it is shown that the microcanonical Maxwell construction is equivalent to the equal-peak-height criterion often employed in canonical simulations. As a consequence the microcanonical finite-size estimators for the transition point, latent heat and interface tension are identical to standard estimators in the canonical ensemble. Special emphasis is placed on various ways for estimating interface tensions. The theoretical considerations are illustrated with numerical data for the two-dimensional 10-state Potts model.

Canonical ensembleNuclear and High Energy PhysicsPhase transitionMicrocanonical ensembleTransition pointCritical phenomenaMaxwell constructionEstimatorStatistical physicsAtomic and Molecular Physics and OpticsPotts modelMathematicsNuclear Physics B - Proceedings Supplements
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Temperature concepts for small, isolated systems: 1/t decay and radiative cooling

2003

We report on progress in our investigations of cluster cooling. The analysis of measurements is based on introduction of the microcanonical temperature and a statistical description of the decay of an ensemble with a broad distribution in temperature. The resulting time dependence of the decay rate is a power law close to t �1 , replaced by nearly exponential decay after a characteristic time for quenching by radiative cooling. We focus on results obtained for fullerenes, both anions and cations and recently also neutral C60.

Canonical ensemblePhysicsQuenchingMicrocanonical ensembleRadiative coolingExcited statePhysics::Atomic and Molecular ClustersOptical physicsAtomic physicsExponential decayPower lawAtomic and Molecular Physics and Optics
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A global Canopy Water Content product from AVHRR/Metop

2020

Abstract Spatially and temporally explicit canopy water content (CWC) data are important for monitoring vegetation status, and constitute essential information for studying ecosystem-climate interactions. Despite many efforts there is currently no operational CWC product available to users. In the context of the Satellite Application Facility for Land Surface Analysis (LSA-SAF), we have developed an algorithm to produce a global dataset of CWC based on data from the Advanced Very High Resolution Radiometer (AVHRR) sensor on board Meteorological–Operational (MetOp) satellites forming the EUMETSAT Polar System (EPS). CWC reflects the water conditions at the leaf level and information related …

Canopy010504 meteorology & atmospheric sciencesMean squared errorAdvanced very-high-resolution radiometerCanopy Water Content (CWC)0211 other engineering and technologiesGaussian Process Regression (GPR)FOS: Physical sciencesContext (language use)02 engineering and technologyAVHRR/MetOp01 natural sciencesComputers in Earth SciencesEngineering (miscellaneous)Water content021101 geological & geomatics engineering0105 earth and related environmental sciencesRemote sensingVegetation15. Life on landAtomic and Molecular Physics and OpticsComputer Science ApplicationsPhysics - Atmospheric and Oceanic PhysicsMODIS13. Climate actionEUMETSAT Polar System (EPS)Atmospheric and Oceanic Physics (physics.ao-ph)Spatial ecologyEnvironmental scienceSatelliteSentinel-2
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Effects of temperature and pressure on microcantilever resonance response.

2003

Abstract The variation in resonance response of microcantilevers was investigated as a function of pressure (10 −2 –10 6  Pa) and temperature (290–390 K) in atmospheres of helium (He) and dry nitrogen (N 2 ). Our results for a silicon cantilever under vacuum show that the frequency varies in direct proportion to the temperature. The linear response is explained by the decrease in Young's modulus with increasing the temperature. However, when the cantilever is bimaterial, the response is nonlinear due to differential thermal expansion. Resonance response as a function of pressure shows three different regions, which correspond to molecular flow regime, transition regime, and viscous regime. …

CantileverChemistryMean free pathThermodynamicschemistry.chemical_elementYoung's modulusMolecular physicsAtomic and Molecular Physics and OpticsThermal expansionElectronic Optical and Magnetic Materialssymbols.namesakeFree molecular flowDeflection (engineering)symbolsKnudsen numberInstrumentationHeliumUltramicroscopy
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Monitoring the chemical changes in Pd induced by hydrogen absorption using microcantilevers.

2003

Abstract The reactivity of the palladium shaped as a microcantilever is investigated as a function of the hydrogen stoichiometry. A small cell holding the microcantilever is designed to monitor the deflection and the flexural resonance response from high vacuum to a hydrogen gas pressure of several bars. The measurements show that the Young's modulus is accurate if the cantilever is thick enough to be described by a continuum mechanics approach. The orientation distribution function of the palladium grains determined by X-ray diffraction enables to correlate Young's modulus measured using microcantilevers with the elastic constant tensor issued from the literature. The surface stress induce…

CantileverHydrogenHydrideSurface stressUltra-high vacuumAnalytical chemistrychemistry.chemical_elementYoung's modulusAtomic and Molecular Physics and OpticsElectronic Optical and Magnetic Materialssymbols.namesakechemistrysymbolsInstrumentationStoichiometryPalladiumUltramicroscopy
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Measurement of Mechanical Properties of Cantilever Shaped Materials

2008

Microcantilevers were first introduced as imaging probes in Atomic Force Microscopy (AFM) due to their extremely high sensitivity in measuring surface forces. The versatility of these probes, however, allows the sensing and measurement of a host of mechanical properties of various materials. Sensor parameters such as resonance frequency, quality factor, amplitude of vibration and bending due to a differential stress can all be simultaneously determined for a cantilever. When measuring the mechanical properties of materials, identifying and discerning the most influential parameters responsible for the observed changes in the cantilever response are important. We will, therefore, discuss the…

CantileverMechanical engineeringReviewBendinglcsh:Chemical technologyBiochemistrymaterialsAnalytical ChemistryStress (mechanics)stresspressuresensorResidual stressgaslcsh:TP1-1185Electrical and Electronic EngineeringComposite materialInstrumentationContinuum mechanicsChemistrySurface forcetemperatureMicrocantileverAtomic and Molecular Physics and OpticsVibrationageingMaterial propertiesenvironmentmechanicsSensors
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