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showing 10 items of 4510 documents
Characterization of the porous structure of Chilean volcanic soils by nitrogen adsorption and mercury porosimetry
2004
Pore volume, specific surface area (SSA), and total intragranular porosity (TIP) of Chilean soils derived from volcanic materials were studied. Soil samples involving the 0-15 and 15-30 cm depth of virgin and cultivated Collipulli (Ultisol) and Diguillin (Andisol) soils at two particle size fractions (<1 mm and <2 µm) were considered. From mercury porosimetry and N2 adsorption, mainly mesopores (pore diameter, dpore, about 10 nm) were determined for <1 mm Collipulli samples. Diguillin <1 mm soil shows macroporosity with dpore from 70 nm to 7000 nm. The clay fraction of Collipulli has macropores (dpore from 2000 nm to 40000 nm) and mesopores (dpore from 3 nm to 23 nm), while for Diguillin cl…
Microscopic Revelation of Charge-Trapping Sites in Polymeric Carbon Nitrides for Enhanced Photocatalytic Activity by Correlating with Chemical and El…
2019
The influences of chemical and electronic structures on the photophysical properties of polymeric carbon nitrides (PCNs) photocatalysts, which govern the microscopic mechanisms of the superior photocatalytic activity under visible-light irradiation, have been resolved in this work. Time-resolved photoluminescence and in situ electron paramagnetic resonance measurements indicate that the photoexcited electrons in the fractured PCNs swiftly transfer to the C2p-localized states where the trapped photoelectrons exhibit longer lifetime compared to those in the ordinary PCNs. Moreover, the structure deviation at the carbon (Cb) atoms around the bridging sites of heptazine ring units, where trappe…
Modelling load-transmission mechanisms in axially loaded RC columns retrofitted with steel jackets
2018
The use of steel jacketing technique is a common practice for retrofitting existing reinforced concrete (RC) columns, as it allows increasing load-carrying capacity and ductility of the member. When the external jacket has no-end connections – i.e. the jacket is indirectly loaded- the load sustained by the column is transferred from the inner RC core to the external jacket through shear stresses along the contact surface. The assessment of this mechanism is quite complex, due to the marked non-linear behaviour of constituent materials and to the calibration of a proper shear stress-relative slip constitutive law of the concrete-to-steel interface. In this paper, a step-by-step analytical ap…
Intelligent Constructing Exact Tolerance Limits for Prediction of Future Outcomes Under Parametric Uncertainty
2021
The problem of constructing one-sided exact statistical tolerance limits on the kth order statistic in a future sample of m observations from a distribution of log-location-scale family on the basis of an observed sample from the same distribution is considered. The new technique proposed here emphasizes pivotal quantities relevant for obtaining tolerance factors and is applicable whenever the statistical problem is invariant under a group of transformations that acts transitively on the parameter space. The exact tolerance limits on order statistics associated with sampling from underlying distributions can be found easily and quickly making tables, simulation, Monte Carlo estimated percen…
A New Intelligent Technique of Constructing Optimal Airline Seat Protection Levels for Multiple Nested Fare Classes of Single-Leg Flights
2019
A new, rigorous formulation of the optimization problem of airline seat protection levels for multiple nested fare classes is presented. A number of results useful for practical application are obtained. A numerical example is given.
The application of electroanalytical methods to determine affinity series of metal cations for functional biosorbent groups
2018
Abstract The affinity of the selected heavy metal cations: Mn 2 + , Ni 2 + , Cu 2 + , Zn 2 + , Cd 2 + , Pb 2 + and Na + , K + , Mg 2 + , Ca 2 + was determined for the functional groups located on the surface of leached barley middlings, so called Brewer's spent grain (BSG) – a by-product of the brewing industry. A simple method for determining the affinity series, with the use of a conductivity meter and a pH-meter, was described. It was demonstrated that the affinity of cations for the functional groups located on the surface of the BSG increases in the series: Na + + 2 + 2 + ≈ Zn 2 + 2 + ≈ Ca 2 + 2 + 2 + 2 + , and the series was determined by comparing concentrations expressed in gram e…
Economic globalisation, the perceived room to manoeuvre of national governments, and electoral participation: Evidence from the 2001 British General …
2016
Recent macro-level research argues that economic globalisation negatively affects electoral turnout by constraining the leeway of national governments and thereby rendering elections less meaningful to voters. This article analyses the link between perceptions of the national government's room to manoeuvre and turnout on the individual level. Drawing on the 2001 British General Election, it is shown that citizens who believe that economic globalisation leaves the national government with less influence on the economy are less likely to report to have voted. Further findings also support the proposed theoretical model according to which room to manoeuvre perceptions affect turnout via views …
Political interest furthers partisanship in England, Scotland, and Wales
2016
ABSTRACTAccording to much of the literature, partisanship in Britain exercises little independent influence on the vote but merely reflects voters’ prospective and retrospective evaluations of the parties’ performance with regard to their management of the economy, national security, and public services. In this view, partisanship comes close to Fiorina’s model of a “running tally” of political experiences. Similarly, Dalton’s notion of “cognitive mobilization” suggests that seeking out political information should undermine both the need for and the likelihood of party identification. Applying Mixed Markov Latent Class Analysis to the British Election Study Panel 1997–2000, we challenge th…
Experimental study of a naturally weathered stiff clay
2016
Studying the shear strength of a naturally weathered clay is important to understand rain-induced slope failures in weathered soils. However, experimental studies on naturally weathered soils are limited. The paper focuses on the laboratory experimental investigation carried out to analyse the shear strength of a naturally weathered stiff clay that can be found in unsaturated conditions in situ. This has an important practical relevance in the evaluation of the stability conditions of natural slopes at clay outcrops. Different experimental techniques of suction measurement were used to obtain the soil-water retention curve of the clay over a wide range of suctions. Scanning electronic micr…