Search results for " PRIN"

showing 10 items of 1809 documents

Polysaccharide hydrogels for regenerative medicine applications

2022

injectionpolysaccharidetissue engineering3D printinghydrogelscaffold
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Molecular Confinement in Femtoliter scale aqueous Compartments

2017

Molecular confinement is known to lead to acceleration of molecular dynamics along with surface interaction. Nature employs confinement in molecularly crowded, heterogeneous and, specialized femtoliter (fL) compartments inside living cells for spontaneously achieving higher reaction efficiency and spatial-programming of composite, multi-step biochemical processes. We here show the facile production of aqueous fL droplets for studying molecular confinement on a biochip. We prepare fL aqueous droplets in oil drops on solid substrates by a “field-free”- no external electric fields and electrolytes - piezoelectric inkjet printing in which a novel actuating waveform is employed by picoliter size…

inkjet printing molecular confinement molecular rotors molecular machines
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Enhanced Thin-Film Transistor Performance by Combining 13,6-N-Sulfinylacetamidopentacene with Printed PEDOT:PSS Electrodes

2011

Bottom-contact/bottom-gate organic thin-film transistors (OTFTs) are fabricated using a soluble pentacene precursor (13,6-N-sulfinylacetamidopentacene; SAP) and inkjet printed PEDOT:PSS electrodes on bare SiO2 dielectrics. Saturation mobility, Ion/Ioff ratio, and threshold voltage parameters, respectively, of 0.27 cm2 V−1 s−1, 105, and −4.25 V were measured under ambient conditions after the thermal conversion of SAP to pentacene in 100 μm long channel OTFT devices. The results obtained by the above solution approach are comparable to that of vapor-phase grown pentacene-based OTFTs with photolithographic gold contacts and organic buffer layers and/or inorganic injection layers. The present …

inkjet printingMaterials scienceOrganic thin film transistorbusiness.industryGeneral Chemical EngineeringTransistorGeneral ChemistryDielectriclaw.inventionThreshold voltagePentacenechemistry.chemical_compoundPEDOT:PSSchemistryThin-film transistorlawElectrodesoluble pentaceneMaterials ChemistryOptoelectronicsbusinessSaturation (magnetic)Settore CHIM/02 - Chimica Fisica
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Water Fluxes in Polymeric Membranes for Desalination via Membrane Distillation

2010

Membrane distillation is an emerging technique for seawater desalination. Hydrophobic polymeric membranes are used to separate the solute‐free water vapour from the hot solution. Vapour fluxes of commercial polymeric membranes were measured in various conditions, i.e. natural and forced convection and vacuum. Vapour fluxes were also predicted with models and compared with experimentals. Higher fluxes were recorded in vacuum conditions.

inorganic chemicalsPhysics::Biological PhysicsSettore ING-IND/24 - Principi Di Ingegneria ChimicaChemistryDiffusiontechnology industry and agriculturemembrane distillationPortable water purificationMembrane distillationDesalinationQuantitative Biology::Cell BehaviorForced convectionPhysics::Fluid DynamicsQuantitative Biology::Subcellular ProcessesdesalinationMembraneChemical engineeringEnvironmental chemistrypolymeric membranebiological scienceshealth occupationsbacteriaPolymeric membranePhysics::Atmospheric and Oceanic PhysicsWater vapor
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Nano-sized I12L6 Molecular Capsules Based on the [N⋅⋅⋅I+⋅⋅⋅N] Halogen Bond

2017

Summary Self-assembly of pre-organized subunits with a concave overall shape is an effective strategy for the synthesis of supramolecular capsules. We report the synthesis of a cavitand-based hexameric capsule held together solely by 12 robust [N⋅⋅⋅I + ⋅⋅⋅N] halogen bonds and its characterization in solution and in the gas phase via 1 H NMR spectroscopy, diffusion-ordered nuclear magnetic resonance spectroscopy (DOSY), and electrospray ionization mass spectrometry. The [N⋅⋅⋅I + ⋅⋅⋅N] halogen-bonded hexameric capsule was efficiently synthesized from the isolobal metallosupramolecular Ag + capsule by application of the [N⋅⋅⋅Ag + ⋅⋅⋅N] → [N⋅⋅⋅I + ⋅⋅⋅N] cation-exchange reaction.

inorganic chemicalsStereochemistrycapsuleGeneral Chemical EngineeringElectrospray ionizationSupramolecular chemistrysupramolecular capsule010402 general chemistry01 natural sciencesBiochemistrysupramolecular chemistryresorcinarene cavitandMaterials ChemistryEnvironmental ChemistryHalonium ionhalonium-ion-based nanotechnologyta116silver-to-iodine cation exchangeHalogen bond010405 organic chemistryChemistryBiochemistry (medical)CavitandIsolobal principleself-assemblyGeneral ChemistryNuclear magnetic resonance spectroscopy0104 chemical sciencesCrystallographyhalonium ionProton NMRhalogen bondChem
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Motivos por los que los emigrantes españoles se inscriben en el registro consular

2018

La inscripción en el registro consular no es obligatoria para los emigrantes españoles. Conlleva, no obstante, una serie de ventajas que propician, antes o después, su realización. En este artículo se identifican y analizan los principales motivos que animan a ello a los emigrantes españoles. Se toman como base fundamental los datos e informaciones obtenidos a través de una encuesta cuantitativa y entrevistas semiestructuradas realizadas a más de cuatro mil españoles residentes en el extranjero. Se concluye que los principales motivos para llevar a cabo esta inscripción son los relacionados con el ejercicio de derechos y deberes ciudadanos (especialmente el de sufragio en elecciones español…

inscripciones en el Registro Civilsu realización. En este artículo se identifican y analizan los principales motivos que animan a ello a los emigrantes españoles. Se toman como base fundamental los datos e informaciones obtenidos a través de una encuesta cuantitativa y entrevistas semiestructuradas realizadas a más de cuatro mil españoles residentes en el extranjero. Se concluye que los principales motivos para llevar a cabo esta inscripción son los relacionados con el ejercicio de derechos y deberes ciudadanos (especialmente el de sufragio en elecciones españolas) y el uso de los servicios consulares más conspicuos (renovación de documentos de identidadetc.). Estos últimos juegan un papel decisivo para que acaben inscribiéndose los más reacios en principio a hacerlo. Otros motivos relevantes son los relacionados con la asistencia y protección (especialmente en países con mayores niveles de riesgo e inseguridad):SOCIOLOGÍA [UNESCO]motivosJuan Manuel La inscripción en el registro consular no es obligatoria para los emigrantes españoles. Conlleva1137-7038 8537 Arxius de sociologia 514142 2018 39 6874485 Motivos por los que los emigrantes españoles se inscriben en el registro consular Romero Valienteasí como con las ventajas fiscales y de cara al retorno a España. Emigración españolaUNESCO::SOCIOLOGÍAinscripción consularSpanish emigrationconsular registrationno obstanteuna serie de ventajas que propicianantes o despuésreasons. 37 54
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Varas dalīšanas principa realizācija tiesu varas neatkarības garantijās (1918-1940)

2017

Mūsdienās joprojām sasāpējies jautājums ir tiesu varas neatkarība. Tas izsauc plašas diskusijas ne tikai juristu un tiesību zinātnieku vidū, bet rada bažas arī pārējā sabiedrībā. Līdz ar to rodas nepieciešamība izvērtēt tiesu varas neatkarības garantijas. Izpratne par valsts varu, varas dalīšanas teoriju un tiesu varas neatkarības garantijām nav iedomājama bez vēsturiskās izpētes. Tēma ir aktuāla un tik pat kā nav pētīta šādā šķērsgriezumā. Autore darbā izvirza mērķi - analizēt varas dalīšanas principa realizāciju tiesu varas neatkarības garantijās (1918 - 1940). Izpētīt ne tikai pašu varas dalīšanas principu tiesu varas neatkarības aspektā, bet arī Latvijas tiesu varas veidošanos un to vēs…

institucionālā un personiskā neatkarībatiesu reformatiesnešu neatkarībavaras dalīšanas principstiesu varas neatkarības garantijasJuridiskā zinātne
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La resistenza di interfaccia calcestruzzo poroso-terreni a grana fina per il consolidamento di pendii mediante trincee drenanti profonde

2022

Le trincee drenanti profonde rappresentano uno dei metodi più efficaci per la mitigazione del rischio da frana, in pendii con falda idrica. Esse sono realizzate mediante pannelli o pali secanti. Il riempimento è costituito di calcestruzzo poroso o materiale granulare. Se le trincee sono adeguatamente “innestate” nel terreno stabile e il materiale di riempimento ha sufficiente resistenza e rigidezza come il calcestruzzo poroso, si ha ulteriore in-cremento di resistenza a taglio per effetto shear keys, oltre a quello derivante dalla riduzione delle pressioni in-terstiziali. L’incremento di resistenza è dovuto sia alla resistenza all’interfaccia calcestruzzo–terreni sia a quella intrinseca del…

interface shear strengthPervious concreteSettore ICAR/07 - Geotecnicashear keys effect. Pervious concrete for deep trench drains used to stabilise slopes must simultaneously satisfy many requirements namely adequate hydraulic conductiv-ity adequate shear strength a few days after pour-ing capacity to act as a protective filter for soils in which the drain is installed good resistance to clog-ging and adequate residual hydraulic conductivity. The pervious concrete with appropriated mix-design can effectively satisfy all the abovementioned requirements. If the trenches depth is such that they intersect the sliding surface and if the trenches are adequate-ly "socket" in the layers of stable soil there is a fur-ther increase in shear strength due to the shear keys effect. This latter is in addition to the increase in shear strength resulting from the reduction of inter-stitial pressures that remains the principal scope of the draining trenches. Obviously the increase of shear strength due to the shear keys effect occurs if the trenches are filled with material that have enough strength and stiffness such as the porous concrete. In this case the beneficial effects of the draining trenches on stability are also due to the resistance at the concrete interface of the trench - soils and to the intrinsic resistance of the concrete at the area of the trench intersected by the sliding surface taken into consideration.The increase in resistance due to the shear keys effect can be very significant in relation to the thickness and interspace of the trenches. Results reported in the paper demonstrated that the interface fine grained soil-pervious concrete is higher than the residual shear strength of the soil.
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Il diritto non scritto nel sistema della Convenzione europea dei diritti umani

2016

Il lavoro si occupa dei rapporti tra diritto internazionale generale e sistema della Cedu, affrontando in particolare il problema di capire se la Corte edu abbia fatto ricorso al modello tradizionalmente usato nella giurisprudenza internazionale per stabilire condizioni e modalità di funzionamento delle norme generali nel sistema o se abbia elaborato una concezione un modello autonomo. This paper discusses the relationship between customary international law and the ECHR. The focus is the question whether this problem has been handled by the European Court of Human Rights through the model of relationship between customary law and treaty law which is commonly used by international judges an…

international law - customary law - ECHR - relationship between customary law and treaties - interpretation in conformity with customary law - integral application of customary law - autonomous interpretation method - balancing conflicting values.diritto internazionale - diritto consuetudinario - Cedu - rapporti tra norme - presunzione di conformità al diritto consuetudinario - principio di integriale applicaizone del diritto consuetudinario - interpretazione autonoma - bilanciamento.Settore IUS/13 - Diritto Internazionale
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Purposes and Principles of the United Nations Organization.

2023

Purposes and Principles of the United Nations Organization. 1. Introduction. 2. The Purposes of the United Nations. 3. The Principles of the United Nations.

international subjectivityUNESCO::CIENCIAS JURÍDICAS Y DERECHO::Derecho internacionalunited nations organizationpurposes and principlesUNOinternational law
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