Search results for " Plastics"
showing 10 items of 2628 documents
Use of Biochar as Filler for Biocomposite Blown Films: Structure-Processing-Properties Relationships
2021
In this work, biocomposite blown films based on poly(butylene adipate-co-terephthalate) (PBAT) as biopolymeric matrix and biochar (BC) as filler were successfully fabricated. The materials were subjected to a film-blowing process after being compounded in a twin-screw extruder. The preliminary investigations conducted on melt-mixed PBAT/BC composites allowed PBAT/BC 5% and PBAT/BC 10% to be identified as the most appropriate formulations to be processed via film blowing. The blown films exhibited mechanical performances adequate for possible application as film for packaging, agricultural, and compost bags. The addition of BC led to an improvement of the elastic modulus, still maintaining h…
Study and evaluation of dispersion of polyhedral oligomeric silsesquioxane and silica filler in polypropylene composites
2018
Various methods were used for evaluation of homogeneity of polypropylene (PP) matrix composites with octakis([n‐octyl]dimethylsiloxy)octasilsesquioxane, octakis([n‐octadecyl]dimethylsiloxy)octasilsesquioxane, and silica (SiO2) fillers. The filler dispersion was determined on the basis of the results from the wide‐angle X‐ray scattering (WAXS) analysis, from the tests of selected mechanical properties, from scanning electron microscopy (SEM) with energy dispersive X‐ray spectroscopy and from the decomposable entropic descriptor method. The use of different methods allowed to evaluate homogeneity of PP composites on various levels and with different precisions. The dispersion degree was found…
Using organoclay to promote morphology refinement and co-continuity in high-density polyethylene/polyamide 6 blends – Effect of filler content and po…
2010
We investigate the gradual changes of the microstructure of two blends of high-density polyethylene (HOPE) and polyamide 6 (PA6) at opposite composition filled with increasing amounts of an organo-modified clay. The filler locates preferentially inside the polyamide phase, bringing about radical alterations in the micron-scale arrangement of the polymer phases. When the host polyamide represents the major constituent, a sudden reduction of the average sizes of the polyethylene droplets was observed upon addition of even low amounts of organoclay. A morphology refinement was also noticed at low filler contents when the particles distributes inside the minor phase. In this case, however, keep…
Orientation and Crystallinity Measurements in Film Casting Products
2003
Film casting experiments were carried out with iPP under processing conditions causing the crystallization process to occur under orienting flow. Draw ratio and cooling rates were changed by varying mass flow rates and die thickness. The effect of processing conditions on film crystallinity was investigated by combining WAXS and FT-IR transmission methods, while orientation of both phases was measured by IR dichroism (according to Fraser's method) and successfully compared to birefringence measurements on final films. Crystallinity appears to be almost insensitive to draw ratio and cooling rate. Moreover the crystallinity profile turned out to be also constant along the transverse film dire…
Density Fluctuation in Amorphous Polymers by Small Angle X-Ray Scattering
1984
Density fluctuations in an infinite volume can be obtained by extrapolating the scattering intensity to the zero scattering angle, while those in a finite volume having a radius of several tens of Angstrom can be obtained from intensities at non-zero scattering angles. Small angle X-ray scattering intensities for condensed phases were approximated by I(s)=I(0)exp(As2). This s dependence of the intensity arises from the repulsive interaction between two particles. Since the density fluctuations in the above two types of volume (infinite and finite) were nearly the same in magnitude and temperature dependence for an amorphous polymer (PMMA), it was concluded that no density fluctuations due t…
In situ monitoring of moisture uptake of flax fiber reinforced composites under humid/dry conditions
2021
The use of green materials such as natural fiber-reinforced composites represents an increasingly stringent prerogative in the future planning of industrial and non-industrial production. The optimization of these materials is the main aim of the current research, focused on the evaluation of the behavior of flax fiber reinforced composites exposed to isothermal adsorption and desorption cycles, at varying the partial pressure of water vapor (P/P0). For this purpose, the moisture uptake and the morphology changes of the composite material and their constituents were in situ monitored through a measurement protocol, by using a dynamic vapor sorption (DVS) analysis, coupled with an environmen…
Basic Modeling of the Visco Elastic Behavior of Flax Fiber Composites
2017
International audience; L’effet de massification automobile qui accompagne les besoins croissants de mobilité terrestre et l’offre de nouvelles infrastructures routières qui soutient de nouvelles demandes rendent les modèles de mobilité actuels de plus en plus difficilement acceptables. En effet, les personnes souffrent de l’inconfort des villes engorgées (nuisances), de l’insécurité lors de transports du fait de défaillances techniques ou humaines, de la très grande difficulté d’optimiser ses itinéraires en fonction des horaires ou circonstances exceptionnelles (accident par exemple). Par ailleurs, la mobilité se heurte toujours aux contraintes liées aux rigidités des infrastructures compo…
Effect of high methoxyl pectin on pea protein in aqueous solution and at oil/water interface
2010
International audience; The effect of the addition of high methoxyl pectin on the stability of pea protein isolate emulsions was investigated. Except for low pectin concentrations at acidic pHs where bridging flocculation occurred the addition of pectin improved emulsion stability to pH changes and depletion flocculation induced by maltodextrin addition. The mechanism of pectin induced stability was probed by measuring protein-pectin complex formation in solution, zeta potential of the emulsions droplets and the change in surface viscoelasticity on pectin addition. The phase diagrams of pectin-pea protein isolate in solution and pectin-pea protein-stabilized emulsions were established based…
Catalytic oxidation and reduction of polycyclic aromatic hydrocarbons (PAHs) present as mixtures in hydrothermal media
2012
Author's version of an article in the journal: Polycyclic Aromatic Compounds. Also available from the publisher at: http://dx.doi.org/10.1080/10406638.2012.663451 The reactivity of fluorene, anthracene, and fluoranthene under oxidation and reduction conditions were investigated in this study. This project looks at catalytic and green approaches of converting PAHs to less toxic and/or less stable derivatives that are amenable to further degradation. Hydrothermal reactions have been performed at 300°C with pure H2O and Nafion-SiO2 catalyst for oxidation, and pure H2O, HCOOH, Pd-C, and Nafion-SiO2 catalysts for reductive hydrogenation. Time series has been performed for both the oxidation and …
Dual Enzyme-Responsive Capsules of Hyaluronic Acid-block-Poly(Lactic Acid) for Sensing Bacterial Enzymes.
2015
The synthesis of novel amphiphilic hyaluronic acid (HYA) and poly(lactic acid) (PLA) block copolymers is reported as the key element of a strategy to detect the presence of pathogenic bacterial enzymes. In addition to the formation of defined HYA-block-PLA assemblies, the encapsulation of fluorescent reporter dyes and the selective enzymatic degradation of the capsules by hyaluronidase and proteinase K are studied. The synthesis of the dual enzyme-responsive HYA-b-PLA is carried out by copper-catalyzed Huisgen 1,3-dipolar cycloaddition. The resulting copolymers are assembled in water to form vesicular structures, which are characterized by scanning electron microscopy, transmission electron…