Search results for " Pollution"

Evaluation of working air quality by using semipermeable membrane devices

2008

Abstract It has been evaluated the use of semipermeable membrane devices (SPMDs) as passive samplers of organophosphorus pesticides from air, in order to determine the contamination of working environments. Additionally, the use of SPMDs as portable samplers has been also considered. The analytical methodology for the determination of diazinon, chlorpyrifos-methyl, pirimiphos-methyl, chlorpyrifos and fenthion in SPMDs exposed to contaminated air was based on microwave-assisted extraction and gas chromatography with mass spectrometry determination. Limit of detection (LOD) values from 2 to 4 ng SPMD−1 and repeatability from 2 to 7% were obtained by using the aforementioned methodology. Theor…

Determination of volatile organic compounds in contaminated air using semipermeable membrane devices

2009

Abstract Semipermeable membrane devices (SPMDs) were evaluated as passive samplers for the determination of 26 volatile organic compounds (VOCs) in contaminated air of occupational environments. A direct methodology based on the use of head-space-gas chromatography–mass spectrometry (HS-GC–MS) was developed for VOCs determinations in SPMDs, without any sample pre-treatment and avoiding the use of solvents. A desorption temperature of 150 °C for 10 min was sufficient for a sensitive VOCs determination providing limits of detection in the range of 15 ng SPMD−1 for 21 of 26 studied compounds. Linear and equilibrium uptake models were established for each VOC from compound isotherms. Highly vol…

TOXICITY INDUCED BY GADOLINIUM IONS ON DEVELOPING SEA URCHIN EMBRYOS

2016

Pharmaceuticals are a class of emerging environmental contaminants. Gadolinium (Gd) is a metal of the lanthanide series of the elements whose chelates are commonly employed as contrast agents for magnetic resonance imaging, and subsequently released into the aquatic environment. We investigated the effects of exposure to sublethal Gd concentrations on the development of four phylogenetically and geographically distant species: two Mediterranean species, Paracentrotus lividus and Arbacia lixula, and two species living in the East coast of Australia, Heliocidaris tuberculata and Centrostephanus rodgersii. Measures of the Gd and Ca content inside embryos by ICPMS showed a time- and dose-depend…

Innovative and Applied Research in Biology: Proceedings

2022

The collection contains SCIENTIFIC articles on the topics of the LU 80 conference reports. The main focus is on innovative and applied research in biology and interdisciplinary fields.

Pesticides in the Ebro River basin: Occurrence and risk assessment

2016

In this study, 50 pesticides were analyzed in the Ebro River basin in 2010 and 2011 to assess their impact in water, sediment and biota. A special emphasis was placed on the potential effects of both, individual pesticides and their mixtures, in three trophic levels (algae, daphnia and fish) using Risk Quotients (RQs) and Toxic Units (TUs) for water and sediments. Chlorpyrifos, diazinon and carbendazim were the most frequent in water (95, 95 and 70% of the samples, respectively). Imazalil (409.73 ng/L) and diuron (150 ng/L) were at the highest concentrations. Sediment and biota were less contaminated. Chlorpyrifos, diazinon and diclofenthion were the most frequent in sediments (82, 45 and 2…

Simultaneous clean up of fish fat containing low levels of residues and separation of PCB from chlorinated pesticides by thin-layer chromatography

1974

Il diritto come relazione comunicativa

2012

Da un punto di vista sociologico, il diritto può essere inteso come sistema informativo ed in particolare la norma non è altro che un atto di comunicazione, cioè un messaggio, avente particolari caratteristiche di descrittività e, in senso lato, di prescrittività. Un messaggio, cioè, che appare indirizzato a orientare azioni e aspettative d’azione. In questo senso, dunque, la norma conferisce senso e significato all’azione, in senso weberiano.

Results of a literature review on methods for estimating buildings energy demand at district level

2019

Abstract In the framework of distributed energy planning, evaluating reliable energy profiles of different sectors has a prominent role. At the same time, it is a quite challenging task, since the availability of actual energy profiles of buildings at the district level is not widespread. A survey of over 70 studies in scientific literature has been accomplished and a set of criteria has been defined for classifying the selected contributions based on the energy demand data features, source and/or estimation methods, highlighting the ones adopting hourly energy profiles. As final results, tables summarizing the main methods characteristics and a selection of studies providing directly useab…

Emergence of Aspergillus fumigatus azole resistance in azole-naïve patients with chronic obstructive pulmonary disease and their homes.

2017

Azole-resistant Aspergillus fumigatus (ARAF) has been reported in patients with chronic obstructive pulmonary disease (COPD) but has not been specifically assessed so far. Here, we evaluated ARAF prevalence in azole-naïve COPD patients and their homes, and assessed whether CYP51A mutations were similar in clinical and environmental reservoirs. Sixty respiratory samples from 41 COPD patients with acute exacerbation and environmental samples from 36 of these patient's homes were prospectively collected. A. fumigatus was detected in respiratory samples from 11 of 41 patients (27%) and in 15 of 36 domiciles (42%). Cyp51A sequencing and selection on itraconazole medium of clinical (n = 68) and e…

Multi-residue determination of 47 organic compounds in water, soil, sediment and fish—Turia River as case study

2017

A sensitive and reliable method based on solid-liquid extraction (SLE) using McIlvaine-Na2EDTA buffer (pH = 4.5)-methanol and solid-phase extraction (SPE) clean up prior to ultra-high-performance liquid chromatography coupled to tandem mass spectrometry (UHPLC–MS/MS) was applied to determine 47 organic contaminants in fish, soil and sediments. The SPE procedure to clean-up the extracts was also used as extraction method to determine these compounds in water. Recoveries ranged from 38 to 104% for all matrices with RSDs 50% for 36 compounds in front of 9, matrix effect < 20% for 31 compounds against 21, and LOQs <25 ng g−1 for 38 compounds against 22) indicates that the proposed method is mor…