Search results for " Quaternary"
showing 8 items of 148 documents
Molecular Structure of the Arthropod Hemocyanins
1992
Hemocyanin is an extracellular, blue protein that occurs in high concentrations in the blood of many arthropods, including spiders, scorpions, horseshoe crabs, crustaceans, and at least two centipedes. Serving as an ### oxygen carrier, it is functionally equivalent to hemoglobin, but performs reversible oxygen binding between two copper ions. Hemocyanin is composed of a number of subunits that assemble in an extremely large macro-molecular entity. These particles, which are similar in size to viruses or ribosomes, exhibit a complex allosteric behavior during oxygen binding. There is growing evidence that this functional plasticity has evolved upon, and answers to, ecophysiological constrain…
Polymer-coated reversed-phase packings with controlled hydrophobic properties
1992
Abstract We have designed and synthesized novel reversed-phase packings of non-porous and porous polymethacrylate-coated silicas. By varying the hydrophobicity of the polymer coating, selective unfolding of polypeptides may be achieved, thus enabling manipulation of the chromatographic profile. This study characterizes these packings through their employment for separations of model synthetic peptides of defined secondary, tertiary and quaternary structure. Thus, the packings were applied to the reversed-phase separation α-helical amphipathic and non-amphipathic peptides of the same amino acid composition but different sequences. In addition, selective unfolding of model to-stranded α-helic…
On the stability of the 24-meric hemocyanin from Eurypelma californicum.
1998
The stability of the 24-meric hemocyanin from Eurypelma californicum towards various denaturants (GdnHCl, urea, urea derivatives and salts of the Hofmeister series) indicates that the quaternary structure is stabilized by hydrophilic and polar forces. Thus, the interaction between the seven different subunit types of this cheliceratan hemocyanin is comparable with that of the closely related crustacean hemocyanins. In contrast, no significant influence of divalent ions such as Ca2+ and Mg2+ on the stability is observed at pH 8.0 and pH 8.5 but not at pH 7.0. Studies, both in the presence of urea and GdnHCl indicate that the denaturation process consists of a dissociation of the oligomeric s…
Mediterranean coccolith ecobiostratigraphy since the penultimate Glacial (the last 145,000years) and ecobioevent traceability
2015
The Mediterranean Sea is a miniature ocean ideal to test the response of marine ecosystems to amplified orbital and suborbital climate changes. Here we present coccolith data from a Sardinia Channel gravity core (Arcose C_33) analysed over the last 145,000 years, with a mean resolution of about 900 years. The study highlights that regional phytoplankton assemblages underwent significant modifications between the penultimate glacial and the last interglacial, as well as between the last glacial and the Holocene. The N ratio palaeoproductivity index suggests reduced productivity levels and the development of a deep nutricline during the last interglacial and the Holocene. Within the last glac…
Native and subunit molecular mass and quarternary structure of the hemoglobin from the primitive branchiopod crustacean Triops cancriformis
2006
Many branchiopod crustaceans are endowed with extracellular, high-molecular-weight hemoglobins whose exact structural characteristics have remained a matter of conjecture. By using a broad spectrum of techniques, we provide precise and coherent information on the hemoglobin of one of the phylogenetically ‘oldest’ extant branchiopods, the tadpole shrimp Triops cancriformis. The hemoglobin dissociated under reducing conditions into two subunits, designated TcHbA and TcHbB, with masses of 35 775 ± 4 and 36 055 ± 4 Da, respectively, determined by ESI-MS. Nonreducing conditions showed only two disulfide-bridged dimers, a homodimer of TcHbA, designated D1 (71 548 ± 5 Da), and the heterodimer D2 (…
Vertical movements in NE Sicily and its offshore: Outcome of tectonic uplift during the last 125 ky
2013
New data in the coastal area between Acquedolci and Patti (northeastern Sicily, Italy) have been collected to calculate vertical tectonic rates in a key sector between the Kabilian-Calabrian and the Sicilian-Maghrebian chain. The comparison among marine geology data (multibeam and seismic reflection profiles) on the continental shelf-slope system and the radiocarbon ages on geomorphological markers collected during a coastal survey, provided new stratigraphic, geomorphological and biological data, contributing to the knowledge of the geological evolution of this sector for the last 125 ky.This coastal area is framed between two main structural features active during the Pleistocene in north…
INDUSTRY - A PILLAR OF STRENGTH ECONOMIC AND SOCIAL DEVELOPMENT. ROMANIAN SEQUENCES
2012
In the last 300 years, industry was the key driver of economic development and social, political, military, cultural and spiritual, which are inconceivable without the contribution of this important sector of the economy of any country. At least in these 300 years since the first industrial revolution, industrialization took place in every country in the world along with free trade, protectionism alternation - free schimbism contributing to balancing economic and social development. Nothing is more important than industry between the four basic economic sectors (agriculture, industry, trade and transport). Recrudescence services of any kind, but also the unprecedented quaternary sector (lei…
Late Quaternary marine ostracods of the Basque Basin (S Bay of Biscay): taxonomy and distribution
2018
Late Quaternary taxonomy and ecologic and age distributions of ostracods from the Basque Basin (S Bay of Biscay) are described. More than forty-four thousands ostracod specimens have been obtained from one hundred surface samples and core samples from six cores located in shelf and upper bathyal depths and other infrabathyal core as comparative deep reference. A total of 155 species have been taxonomically described, belonging to 67 genera. Most characteristic species (123) have been SEM figured, and ecologic-geographic distributions and ages have been provided for all species. The resulting database will be a useful help for palaeoceanographic and palaeoclimatologic studies of the region.