Search results for " Reflection"
showing 10 items of 345 documents
Photonic transfer through subwavelength optical waveguides
1998
Optical tunneling effect through dielectric junctions with subwavelength transverse sizes has been demonstrated some years ago. In this letter, we demonstrate how similar effects can be exploited to perform photonic transfer through a subwavelength optical wave guide (SOW) by structuring its optical index along the direction of propagation. The optical transmittance of the SOW is computed self-consistently in direct space through the numerical solution of a Dyson equation. We apply this scheme to investigate the optical properties of different SOW architectures. Even under total internal reflection, in which the light is coupled to the SOW by an evanescent mode, an efficient optical transfe…
Discovery-learning in grammar education:a study on anaphoric pronouns
2022
En les darreres dècades, en el context educatiu portuguès, com en altres països, la gramàtica ha estat un tema central de debat en l’educació L1. L’any 2001, amb la publicació del Currículum Nacional d’Educació Bàsica, la gramàtica, que es va anomenar «coneixement explícit de la llengua», es va considerar un dels components bàsics del currículum de L1 portuguès. Des d’aquesta perspectiva, inspirada en les propostes del moviment anglosaxó de consciència lingüística, l’objectiu principal de l’educació gramatical és desenvolupar els coneixements implícits que els infants ja tenen i utilitzen en un coneixement cada cop més reflexiu i explícit. En aquesta concepció, en què se suposa que «la majo…
Optical modeling of nickel-base alloys oxidized in pressurized water reactor
2012
International audience; The knowledge of the aging process involved in the primary water of pressurized water reactor entails investigating a mixed growth mechanism in the corrosion of nickel-base alloys. A mixed growth induces an anionic inner oxide and a cationic diffusion parallel to a dissolution-precipitation process forms the outer zone. The in situ monitoring of the oxidation kinetics requires the modeling of the oxide layer stratification with the full knowledge of the optical constants related to each component. Here, we report the dielectric constants of the alloys 600 and 690 measured by spectroscopic ellipsometry and fitted to a Drude-Lorentz model. A robust optical stratificati…
Modelling of piping collapses and gully headcut landforms: Evaluating topographic variables from different types of DEM
2021
Abstract The geomorphic studies are extremely dependent on the quality and spatial resolution of digital elevation model (DEM) data. The unique terrain characteristics of a particular landscape are derived from DEM, which are responsible for initiation and development of ephemeral gullies. As the topographic features of an area significantly influences on the erosive power of the water flow, it is an important task the extraction of terrain features from DEM to properly research gully erosion. Alongside, topography is highly correlated with other geo-environmental factors i.e. geology, climate, soil types, vegetation density and floristic composition, runoff generation, which ultimately inf…
Conclusione generale
2009
Le ipotesi relative alla congruenza delle attività formative progettate con gli obiettivi che ci si prefiggeva di raggiungere sono state verificate in un campione di livello medio-alto per la competenza metacognitiva.
Influence of Polyvinyl Alcohol (PVA) on PVA-Poly-N-hydroxyethyl-aspartamide (PVA-PHEA) Microcrystalline Solid Dispersion Films
2020
AbstractThis study was conducted to formulate buccal films consisting of polyvinyl alcohol (PVA) and poly-N-hydroxyethyl-aspartamide (PHEA), to improve the dissolution of the drug through the oral mucosa. Ibuprofen sodium salt was used as a model drug, and the buccal film was expected to enhance its dissolution rate. Two different concentrations of PVA (5% w/v and 7.5% w/v) were used. Solvent casting was used to prepare films, where a solution consisting of drug and polymer was cast and allowed to dry. Attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIR), differential scanning calorimetry (DSC), and scanning electron microscopy (SEM) were used to investigate the pr…
Application of solid-state electrochemistry techniques to polyfunctional organic–inorganic hybrid materials: The Maya Blue problem
2013
Abstract The time evolution of indigo plus palygorskite powdered mixtures during isothermal heating at different temperatures between 120 and 180 °C to form Maya Blue-type materials has been monitored by means of infrared spectrometry, diffuse reflectance spectrometry in the visible region and solid state electrochemical techniques. The kinetics of the formation process of such materials can be described in terms of two consecutive reactions, the first one consisting of the loss of zeolitic water of the palygorskite coupled with clay-indigo attachment and partial indigo to denydroindigo oxidation. The palygorskite dehydration acts as a rate-determining step fitting to a 3D Avrami-Erofe’ev k…
Comparison of two vibrational procedures for the direct determination of mancozeb in agrochemicals.
2007
The direct determination of mancozeb in agrochemicals has been made by diamond attenuated total reflectance (ATR) Fourier transform infrared spectroscopy in the middle range (DATR-MIR) and diffuse reflectance infrared Fourier transform spectroscopy in the near range (DR-NIR) methods using in both cases a previous identification of the samples using a dendrographic classification and an appropriate partial least squares (PLS) calibration established from a set of nine external standards and optimized for each type of sample. It was analyzed a heterogeneous population of 11 samples obtained from the Spanish market, containing different co-formulated products, such as fosetyl-Al, copper oxychl…
3D reconstruction of external and internal surfaces of transparent objects from polarization state of highlights
2014
A vision-based method is proposed to measure the 3D shape of external and internal surfaces (not accessible) of smooth transparent objects. Looking at the reflections of point sources on a specular surface with a polarimetric camera, we combine the measurements of two techniques: shape from distortion and shape from polarization. It permits us to recover the position and orientation of the specular surface for each detected point. The internal surface of transparent objects exhibiting as well a specular component, the same technique is used on the highlights coming from the back surface, taking into account the refraction by using polarimetric ray tracing.
Nutritional parameters of commercially available milk samples by FTIR and chemometric techniques
2004
Abstract A chemometric study on the prediction of the main nutritional aspects of milk has been carried out by using fourier transform infrared spectroscopy (FTIR) attenuated total reflectance (ATR) measurements of commercially available milk samples of different types. Whole, semi and skimmed milks, enriched or not with calcium, vitamins or modified by alteration of lipid or sugar composition were considered. After evaluating different strategies for data acquisition and ATR cleaning between samples, hierarchical cluster analysis (HCA) was carried out for classification of samples in order to choose the calibration set. The prediction capabilities of partial least squares (PLS) data treatm…