Search results for " Relation"

2020

The course of organic chemical reactions is efficiently modelled through the concepts of “electrophiles” and “nucleophiles” (meaning electron-seeking and nucleus-seeking reactive species). On the one hand, an advanced approach of the correlation of the nucleophilicity parameters N and electrophilicity E has been delivered from the linear free energy relationship log k (20 °C) = s(N + E). On the other hand, the general influence of the solvent mixtures, which are very often employed in preparative synthetic chemistry, has been poorly explored theoretically and experimentally, to date. Herein, we combined experimental and theoretical studies of the solvent influence on pyrrolidine nucleophili…

Thorough evaluation of OECD principles in modelling of 1-[(2-hydroxyethoxy)methyl]-6-(phenylthio)thymine derivatives using QSARINS.

2020

The human immunodeficiency virus is a lethal pathology considered as a worldwide problem. The search for new strategies for the treatment of this disease continues to be a great challenge in the scientific community. In this study, a series of 107 derivatives of 1-[(2-hydroxyethoxy)methyl]-6-(phenylthio)thymine, previously evaluated experimentally against HIV-I reverse transcriptase, was used to model antiretroviral activity. A model of linear regression, implemented in the QSARINS software, was developed with a genetic algorithm for variable selection. The fit of its parameters was good and exhaustive validation, according to the OECD regulatory principles, was performed. Also, the applica…

Dimensionless Stage-Discharge Relationship for a Non-Linear Water Reservoir: Theory and Experiments

2020

In the field of hydrology, stage&ndash

On numerical broadening of particle size spectra: a condensational growth study using PyMPDATA 1.0

2021

Abstract. The work discusses the diffusional growth in particulate systems such as atmospheric clouds. It focuses on the Eulerian modeling approach in which the evolution of the probability density function describing the particle size spectrum is carried out using a fixed-bin discretization. The numerical diffusion problem inherent to the employment of the fixed-bin discretization is scrutinized. The work focuses on the applications of MPDATA family of numerical schemes. Several MPDATA variants are explored including: infinite-gauge, non-oscillatory, third-order-terms and recursive antidiffusive correction (double pass donor cell, DPDC) options. Methodology for handling coordinate transfor…

Comparison and Evaluation of the TES and ANEM Algorithms for Land Surface Temperature and Emissivity Separation over the Area of Valencia, Spain

2017

Land Surface temperature (LST) is a key magnitude for numerous studies, especially for climatology and assessment of energy fluxes between surface and atmosphere. Retrieval of accurate LST requires a good characterization of surface emissivity. Both quantities are coupled in a single radiance measurement; for this reason, for N spectral bands available in a remote sensor, there will always be N + 1 unknowns. To solve the indeterminacy, temperature-emissivity separation methods have been proposed, among which the Temperature Emissivity Separation (TES) algorithm is one of the most widely used. The Adjusted Normalized Emissivity Method (ANEM) was proposed as a modification of the Normalized E…

Climate change policies and agendas: facing implementation challenges and guiding responses

2020

Climate policies are essential to mitigate climate change and to develop successful adaptation processes. However, there is a paucity of international studies that analyse the status of climate change policies. This paper reports on research undertaken in a sample of 13 highly diverse countries, in regards to their geography, socioeconomic development, vulnerability elements, adaptation, and climate-risks. The results draw attention to the global spread and standardisation of climate change policies, namely through the adoption of comprehensive National Adaptation Plans/Strategies (NAPs/NASs) that include mitigation measures and evaluation mechanisms. Although NAPs tend to take into account…

Radiance-based NIRv as a proxy for GPP of corn and soybean

2020

Abstract Substantial uncertainty exists in daily and sub-daily gross primary production (GPP) estimation, which dampens accurate monitoring of the global carbon cycle. Here we find that near-infrared radiance of vegetation (NIRv,Rad), defined as the product of observed NIR radiance and normalized difference vegetation index, can accurately estimate corn and soybean GPP at daily and half-hourly time scales, benchmarked with multi-year tower-based GPP at three sites with different environmental and irrigation conditions. Overall, NIRv,Rad explains 84% and 78% variations of half-hourly GPP for corn and soybean, respectively, outperforming NIR reflectance of vegetation (NIRv,Ref), enhanced vege…

Testing the use of an image-based technique to measure gully erosion at Sparacia experimental area

2016

The first part of this investigation was aimed at testing the use of a three-dimensional (3D) Digital Terrain Model (DTM) and a quasi-tridimensional (2.5D) Digital Elevation Model (DEM) obtained by a large series of oblique images of eroded channels taken from consumer un-calibrated and non-metric cameras. For two closed earth channels having a different sinuosity the ground measurement of some cross-sections by a profilometer (P) was carried out. The real volume of each channel was also measured by waterproofing it by a plastic film and filling it with a known volume of water. The comparison among the three methods (3D, 2.5D and P) pointed out that a limited underestimation of the total vo…

Driving through floodwater: Exploring driver decisions through the lived experience

2019

Abstract More than half of unintentional flood-related drowning deaths in Australia are due to driving through floodwater, despite on-going public campaigns. Currently, there is a knowledge gap in understanding why individuals choose to drive through floodwater and the decisions that may lead to such actions. We propose that a more complete understanding of individuals’ decisions to drive through floodwater needs to be considered in the context of the lived experience. Australian drivers (N = 20) who had intentionally driven through floodwater participated in semi-structured interviews. Data were analysed using a thematic analysis based in an interpretivist approach. Past experience, indivi…

Patterns Comparison Between Gome-2 Sun-Induced Fluorescence and Msg Gross Primary Production

2018

A comparison between maximum monthly MSG gross primary production (GPP) estimates with the sun-induced chlorophyll fluorescence (SIF) product from the Global Ozone Monitoring Experiment-2 (GOME-2) over Europe and Africa is presented as an indirect validation of MSG GPP estimates. The maximum daily GPP value for each month is derived from daily MSG GPP, which takes full advantage of the SEVIRI/MSG products from the European Organization for the Exploitation of Meteorological Satellites (EUMETSAT) delivered by the Satellite Application Facility for Land Surface Analysis (LSA SAF). A linear relationship found between both products over savanna, grasslands and forests at high latitudes evidence…