Search results for " Resonance"
showing 10 items of 5579 documents
Four-Component Relativistic DFT Calculations of C-13 Chemical Shifts of Halogenated Natural Substances
2015
We have calculated the (13) C NMR chemical shifts of a large ensemble of halogenated organic molecules (81 molecules for a total of 250 experimental (13) C NMR data at four different levels of theory), ranging from small rigid organic compounds, used to benchmark the performance of various levels of theory, to natural substances of marine origin with conformational degrees of freedom. Carbon atoms bonded to heavy halogen atoms, particularly bromine and iodine, are known to be rather challenging when it comes to the prediction of their chemical shifts by quantum methods, due to relativistic effects. In this paper, we have applied the state-of-the-art four-component relativistic density funct…
Noise effect in a FitzHugh-Nagumo circuit driven by a bichromatic signal
2013
We analyze the response of a nonlinear circuit exactly ruled by the FitzHugh-Nagumo equations. This circuit is submitted to a bichromatic signal including a high frequency and a low frequency. In absence of noise, we show that for an appropriate amplitude of the high frequency driving, the response of the circuit estimated at the low frequency can be optimized via the phenomenon of vibrational resonance. Next, we show that under certain conditions, noise can contribute to the effect of vibrational resonance. Colored noise is also considered. Our experimental results are confirmed by a numerical analysis.
Transcranial Magnetic Stimulation and Neuroimaging Coregistration
2013
The development of neuroimaging techniques is one of the most impressive advancements in neuroscience. The main reason for the widespread use of these instruments lies in their capacity to provide an accurate description of neural activity during a cognitive process or during rest. This important advancement is related to the possibility to selectively detect changes of neuronal activity in space and time by means of different biological markers. Specifically, functional magnetic resonance imaging (fMRI), positron emission tomography (PET), single-photon emission computed tomography (SPECT), and nearinfrared spectroscopy (NIRS) use metabolic markers of ongoing neuronal activity to provide a…
Acidity and basicity of primaryN-phenylnitramines: catalytic effect of protons on the nitramine rearrangement
2002
Para-substituted N-phenylnitramines were prepared either by oxidation of diazonium salts or by nitration under alkaline or acidic conditions. Isotopic [15N-NO2] labelling indicated that the bands characteristic of the N-nitro group appear in the 1318–1323 and 1585–1607 cm−1 regions. In the nitrogen NMR spectra, the nitramino group gives two resonances at −193 ± 3 (NH) and −32 ± 3 ppm (NO2). The chemical shifts in proton and carbon NMR spectra are predictable, based on increments and the additivity rule. The spectral data indicate the lack of conjugation between the nitramino group and another substituent bound to the ring. It seems to contradict the well-known fact that substituents strongl…
Noise effect in a sine-Gordon Lattice
2013
International audience; This paper is devoted to the influence of internal noise in a sine-Gordon chain exhibiting the well known nonlinear supratransmission phenomenon. It is shown that spatiotemporal noise can trigger breather modes with a given probability in a range of parameters where they do not occur without noise. A frequency analysis is carried out to quantify the degree of coherence of the emitted breather. It is shown that there exists an appropriate amount of noise which ensures the existence of breather modes with the best coherence.
Johnson-Nyquist Noise Effects in Neutron Electric-Dipole-Moment Experiments
2021
Magnetic Johnson-Nyquist noise (JNN) originating from metal electrodes, used to create a static electric field in neutron electric-dipole-moment (nEDM) experiments, may limit the sensitivity of measurements. We present here the first dedicated study on JNN applied to a large-scale long-measurement-time experiment with the implementation of a co-magnetometry. In this study, we derive surface- and volume-averaged root-mean-square normal noise amplitudes at a certain frequency bandwidth for a cylindrical geometry. In addition, we model the source of noise as a finite number of current dipoles and demonstrate a method to simulate temporal and three-dimensional spatial dependencies of JNN. The c…
Ghost stochastic resonance in FitzHugh–Nagumo circuit
2014
International audience; The response of a neural circuit submitted to a bi-chromatic stimulus and corrupted by noise is investigated. In the presence of noise, when the spike firing of the circuit is analysed, a frequency not present at the circuit input appears. For a given range of noise intensities, it is shown that this ghost frequency is almost exclusively present in the interspike interval distribution. This phenomenon is for the first time shown experimentally in a FitzHugh-Nagumo circuit.
Etude spectroscopique de fibres durcies pour un environnement radiatif sévère
2013
Les nouveaux environnements radiatifs, comme LMJ, ITER, ILE/ELI, HiPER, réacteurs nucléaires des générations III+ et IV, nécessitent le développement de nouveaux composants pour le transport et le traitement des signaux. A cause de l’impossibilité d’utiliser les composants électroniques, la recherche est orientée vers les composants à fibres optiques comme vecteur d’information et aussi comme élément de diagnostic. Ils présentent de nombreux avantages, comme leur relative immunité électromagnétique, faible pois, large bande passante, mais les rayonnements gamma et les neutrons dégradent leur transmission. La dégradation dépend principalement de la composition de la fibre. Ainsi, il a été mo…
O2-Loading Treatment of Ge-Doped Silica Fibers: A Radiation Hardening Process
2016
International audience; The effects of a high-pressure O2-loading treatment on the radiation response of Ge-doped optical fibers (OFs) were investigated. We found that the incorporation of high concentration of interstitial molecular oxygen remarkably enhances the resistance to ionizing radiation of Ge-doped OFs in the UV-Visible domain and, at the same time, improves the transmission of UV light in the unirradiated OF sample. By comparison with previously reported results, the O2-loading treatment turned out to increase the radiation resistance of Ge-doped OFs more efficiently than F or Ce codoping. The understanding of such amelioration relies in basic radiation-induced mechanisms that we…
Optical properties and photosensitivity of vacuum synthesized Ge-doped sol-gel amorphous SiO/sub 2/
2005
We report optical and electron paramagnetic resonance investigations of gamma ray irradiation effects in sol-gel Ge-doped amorphous SiO/sub 2/. The studied materials have Ge-doping levels up to 10/sup 4/ molar part per million and were densified by two routes differing for the atmosphere: O/sub 2/+N/sub 2/ or vacuum. The obtained results evidence that irradiation affects matrix sites inducing paramagnetic defects. Furthermore, the comparison between the two densification procedures shows that vacuum atmosphere induces higher radiation sensitivity.