Search results for " SCIENZA"

showing 10 items of 1301 documents

The United Nations and the European Union

2019

The European Union (EU) and the United Nations (UN) are expressions of a rules-based global order. The EU has enshrined support to the UN in its security strategies, and its priorities indicate an engagement in a wide range of UN programs and activities to maintain the rules-based order and adapt it to face internal and external challenges. The EU and its member states are the largest contributors to the UN budget. Following the adoption of the Lisbon treaty, the EU has increased its representation at the UN, gaining enhanced observer status in the General Assembly. However, because of the intergovernmental nature of the forum, only its member states have the right to vote. This has led sch…

business.industryGeneral assemblyPolitical sciencemedia_common.cataloged_instanceEU–UN EU cohesion General assembly Security Council Security Council reform EU actorness effective multilateralism EU priorities at the UN EU representation and performance peace and security maintenance European Union politicsSecurity councilInternational tradeEuropean unionbusinessSettore SPS/04 - Scienza Politicamedia_common
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Employing fuzzy logic in the diagnosis of a clinical case

2010

Fuzzy logic is a logical calculus which operates with many truth values (while classical logic works with the two values of true and false). Since fuzzy logic considers the truth of scientific statements like something softened, it is fruitfully applied to the study of biological phenomena, biology is indeed considered the field of complexity, uncertainty and vagueness. In this paper fuzzy logic is successfully applied to the clinical diagnosis of a patient who suffers from different diseases bound by a complex causal chain. In this work it is presented a mathematical foundation of fuzzy logic (with connectives and inference rules) and then the application of fuzzy reasoning to the study of…

business.industryProbabilistic logic networkMany-valued logicMultimodal logicDynamic logic (modal logic)Paraconsistent logicSettore M-FIL/02 - Logica E Filosofia Della ScienzaArtificial intelligenceT-norm fuzzy logicsbusinessFuzzy Logic Probabilistic Logic Clinical diagnosis Biological phenomena TruthHigher-order logicFuzzy logicHealth
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Experimental analysis of "bovedas tabicadas"

2012

A particular type of vaulted structures, known as bóvedas tabicadas (Catalan vaults), made with alternate layers of bricks and mortar and characterized by a very low thickness in comparison to the other two dimensions, are studied. The research has been faced under the historical aspect as well as under the mechanical one, developing experimental and numerical analysis regarding real existing structures. In particular, the experimental analysis, performed by effecting compression and bending tests on samples taken from a real structure, has been devoted to the constitutive material identification and the characterization is made by considering the material as an ideal homogeneous; further e…

bóvedas tabicadas identification experimental and numerical analysis.Settore ICAR/08 - Scienza Delle Costruzioni
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Hyper-reticulated calixarene polymers: a new example of entirely synthetic nanosponge materials

2018

New calixarene-based nanosponges (CaNSs), i.e., hyper-reticulated polymers constituted by calixarene monomer units joined by means of bis(1,2,3-trialzolyl)alkyl linkers, were synthesized, characterized and subjected to preliminary tests to assess their supramolecular absorption abilities towards a set of suitable organic guests, selected as pollutant models. The synthesis was accomplished by means of a CuAAC reaction between a tetrakis(propargyloxy)calix[4]arene and an alkyl diazide. The formation of the polymeric network was assessed by means of FTIR and 13C{1H} CP-MAS solid-state NMR techniques, whereas morphological characterization was provided by SEM microghaphy. The materials were pro…

calixarenesSupramolecular chemistrynanosponges02 engineering and technology010402 general chemistryNanosponge01 natural sciencesFull Research PaperHydrophobic effectlcsh:QD241-441chemistry.chemical_compoundlcsh:Organic chemistrySmart materialCalixarenePolymer chemistryFourier transform infrared spectroscopylcsh:ScienceAlkylSettore CHIM/02 - Chimica Fisicachemistry.chemical_classificationOrganic ChemistrySettore CHIM/06 - Chimica OrganicaSettore CHIM/05 - Scienza E Tecnologia Dei Materiali PolimericiPolymer021001 nanoscience & nanotechnology0104 chemical sciencesChemistryMonomerchemistrySolid-state nuclear magnetic resonancesmart materialsCalixarenesolid-state NMRlcsh:Q0210 nano-technologyBeilstein Journal of Organic Chemistry
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Cambiamenti climatici e diritti umani. Il paradigma della Giustizia climatica e il ruolo delle climate litigations per la protezione dei diritti uman…

2021

In che misura i sempre più diffusi, pervasivi e drammatici impatti dei cambiamenti climatici, che interessano con geometrie variabili tutte le latitudini e longitudini del globo, mettono a rischio la tenuta del sistema dei diritti umani universalmente riconosciuti? La ricerca si pone l'obiettivo di rispondere a tale quesito ragionando su quali sfide essi pongano e su quali siano, nell'attuale panorama, gli strumenti giuridici utili a garantire la piena tutela dei diritti fondamentali nel nuovo contesto clima- alterato. La fondatezza e l’attendibilità delle ricerche scientifiche che avvalorano l’esistenza del cambiamento climatico antropogenico si pongono come presupposto fattuale dell'inter…

cambio climaticolitigio climaticoParis Agreementdiritto climaticodiritti umaniecologia politicaSettore SPS/10 - Sociologia Dell'Ambiente E Del TerritorioSettore IUS/13 - Diritto Internazionalepolitical ecologyclimate lawenvironmental justicemedioambientegiustizia climaticaecologismoderecho internacionaldiritto dell'ambiente:CIENCIA POLÍTICA [UNESCO]ecocidiocontenzioso climaticoUNESCO::CIENCIA POLÍTICASettore IUS/10 - Diritto Amministrativo:CIENCIAS JURÍDICAS Y DERECHO [UNESCO]Accordo di ParigiUNESCO::CIENCIAS JURÍDICAS Y DERECHOclimate justicederecho climaticoUNFCCCjusticia climaticaclimate changegovernancegiustizia ambientalederechos humanosclimate litigationsSettore SPS/04 - Scienza Politicacambiamenti climatici
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Nitrogen-Doped Carbon Nanodots-Ionogels: Preparation, Characterization, and Radical Scavenging Activity

2018

Hybrid diimidazolium-based ionogels were obtained by dispersing nitrogen-doped carbon nanodots (NCNDs) in ionic liquid (IL) solutions and by using dicationic organic salts as gelators. The properties of the NCND-ionogels were studied in terms of thermal stability, mechanical strength, morphology, rheological, and microscopic analyses. Insights into the formation of the hybrid soft material were attained from kinetics of sol-gel phase transition and from estimating the size of the aggregates, obtained from opacity and resonance light-scattering measurements. We demonstrate that, on one hand, NCNDs were able to favor the gel formation both in the presence of gelating and nongelating ILs. On t…

carbon nanostructurePhase transitionMaterials scienceOpacityKineticsGeneral Physics and Astronomychemistry.chemical_element02 engineering and technologycarbon dots; carbon nanostructures; dicationic organic salts; fluorescence; ionogels; radical scavenging; supramolecular gels010402 general chemistry01 natural sciencesdicationic organic saltschemistry.chemical_compoundRheologycarbon dotsGeneral Materials ScienceThermal stabilitycarbon dotradical scavengingGeneral Engineeringsupramolecular gelsSettore CHIM/06 - Chimica Organica021001 nanoscience & nanotechnologycarbon nanostructures0104 chemical sciencesSettore ING-IND/22 - Scienza E Tecnologia Dei MaterialiionogelchemistryChemical engineeringionogelsIonic liquidcarbon nanostructures carbon dots supramolecular gels ionogels dicationic organic salts fluorescence radical scavengingdicationic organic saltfluorescence0210 nano-technologyHybrid materialCarbon
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L'analogia physis-techne in Aristotele (Fisica B, 3-9) e la teoria interventistica della causalità

2015

Ho diviso la lettura dei capitoli 3-9 del libro B della Fisica di Aristotele in due momenti: nei capitoli 3-7 viene data la definizione delle quattro cause e si pone il problema se caso e fortuna sono cause del divenire, nei capitoli 8-9 si risolve tale aporia in senso teleologico e si traggono le conclusioni sulla relazione physis-techne. La concezione interventistica della causalità sostiene che c’è uno stretto legame fra causalità e intervento umano in natura: l’idea di una relazione causale fra due eventi (uno che causa e l’altro che è causato) ha come presupposto il concetto di azione intenzionale e nasce dalla riflessione dell’uomo sul proprio operare finalizzato nella realtà. Sebbene…

cause Aristotle’s physics nature technique interventionist theory aimed operatinCausa fisica di Aristotele natura tecnicaSettore M-FIL/02 - Logica E Filosofia Della Scienza
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Definizione e significati della physis in Aristotele a partire dal confronto con la techne Il logos come apertura della physis alla techne in Fisica …

2015

Oltre all' idea della genesi della dottrina delle cause dal confronto fra techne e physis, l’ipotesi che guida questo studio, a tale idea strettamente connessa, è l’interpretazione della techne aristotelica come sussunzione del divenire naturale, e delle sue catene causali, entro l’operare umano in vista di un fine: la similitudine fra techne e physis viene colta da Aristotele nell’essere entrambe movimenti che producono enti imponendo una forma ad una materia adeguata e secondo un piano finalizzato; in entrambi questi processi la causa formale e la causa finale del movimento giungono, da un certo punto di vista, ad identificarsi.

cause techne physis AristoteleSettore M-FIL/02 - Logica E Filosofia Della Scienza
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Hydrolytic degradation of PLA/Posidonia Oceanica green composites: A simple model based on starting morpho-chemical properties

2021

Abstract In this work, we studied the degradability of PLA-based biocomposites containing Posidonia Oceanica flour at different loading levels and aspect ratios. Hydrolytic tests were carried out in neutral (pH = 7.4) and alkaline (pH = 10) environment. Time-dependent evolution of some key features, including residual mass and solution uptake, was monitored, and correlated with the changes observed in both morphology and chemical structure of the matrix. The results pointed out that biocomposites degraded much faster than neat PLA in both conditions, up to lose 70% of their initial weight after 1000 h immersion. A complex mechanism was unveiled, evidencing the crucial role of the fillers, c…

chemistry.chemical_classificationBio composites Durability Environmental degradation Hydrolytic degradation Natural fibre compositesMorphology (linguistics)Materials sciencebiologyChemical structureGeneral Engineering02 engineering and technologyPolymer010402 general chemistry021001 nanoscience & nanotechnologybiology.organism_classification01 natural sciences0104 chemical sciencesMatrix (chemical analysis)HydrolysisSettore ING-IND/22 - Scienza E Tecnologia Dei MaterialichemistryPosidonia oceanicaCeramics and CompositesDegradation (geology)Chemical stabilityComposite material0210 nano-technology
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Synthesis of cyanoacetic acid by carbon dioxide and electrogenerated acetonitrile anion in undivided cells equipped with sacrificial anodes

2008

The electrochemical synthesis of cyanoacetic acid was performed by cathodic reduction of tetraalkylammonium salts (R4NX) in acetonitrile in undivided cells equipped with sacrificial anodes with concomitant or subsequent addition of carbon dioxide. These syntheses avoid the use of dangerous reagents, yield cyanoacetic acid in moderate faradic yields and confirm that the cathodic reduction of tetraalkylammonium salts in the presence of acetonitrile leads to the formation of the anion CNCH2-.

chemistry.chemical_classificationCHLOROACETONITRILE electrocarboxylationNitrileSupporting electrolyteGalvanic anodecathodic reduction of alkyl ammonium saltsGeneral Chemical EngineeringCarboxylic acidInorganic chemistrycarbon dioxideSettore ING-IND/27 - Chimica Industriale E TecnologicaElectrochemistryAnalytical Chemistrychemistry.chemical_compoundsupporting electrolyteSettore ING-IND/22 - Scienza E Tecnologia Dei Materialialkyl ammonium saltCyanoacetic acidchemistryReagentElectrochemistrycyanoacetic acidAcetonitrilesacrificial anodeJournal of Electroanalytical Chemistry
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