Search results for " STORAGE"

INVESTIGATIONS OF THE INFLUENCE OF DIFFERENT ADDITIVES TO THE LANTHANUM RICH MISCHMETAL

2007

Hydrogen Sorption Properties of Metal Hydride and Glass Phase

2009

This work is devoted to the development of a new composite material for hydrogen storage and to investigation of physical and chemical characteristics of material. The new composite material is formed by combination of AB5 type lanthanum nickel alloy with a glass based on silica. Thermogravimetric and XRD measurements prove that the new material absorbs more hydrogen than both constituents separately. That is explained by hydrogen sorption in the composite material due to the hydrogen spillover phenomena, where the hydrogen molecules dissociated on the surface of catalyst in atoms and spills over to the inert surface. That causes the increase of catalytic activity of an alloy and the presen…

ChemInform Abstract: Electrochemical Behavior of Metal Hydrides

2010

Metal hydride electrodes are of particular interest owing to their potential and practical application in batteries. A large number of hydrogen storage materials has been characterized so far. This paper deals with the effect of the chemical nature and stoichiometry of specific alloy families (AB5, A2B, AB/AB2 and AB2) on the hydride stability, hydrogen storage capacity and kinetics of hydrogen sorption-desorption in the solid phase/gas and solid phase/electrolyte solution systems. Special attention has been paid towards the electrochemical properties of metal hydrides in terms of their performance in Ni-MH rechargeable alkaline cells.

Optimal hydrogen storage in sodium substituted lithium fullerides

2017

Through the substitution of Li with Na in Li6C60, we synthesized a series of mixed alkali cluster intercalated fullerides, NaxLi6−xC60. These compounds share lattices of Na6C60 and Li6C60 with a cubic parameter linearly dependent on x. H2 absorption and desorption were studied by means of charge/discharge kinetic measurements and coupled calorimetric–manometric evaluation. By varying the stoichiometry, we found the best compromise among the absorption rate, temperature and amount of hydrogen for x = 0.5 and 1. Small concentrations of Na substituted to Li significantly lower the absorption temperature of Li6C60, improving the hydrogenation capacity, the kinetics, and the dehydrogenation enth…

From determination of the fugacity coefficients to estimation of hydrogen storage capacity: A convenient theoretical method

2015

Abstract The equation of state (EOS) from virial expansion (VE) is used in this work to pave the way for determining the fugacity coefficients of the hydrogen fluid at arbitrary temperature and pressure. The fugacity coefficients from our VE method have more physical meanings than the empirical values. In this way, the hydrogen storage capacity of a novel material model can be estimated by using few density functional theory (DFT) calculations with the aid of a continuum model. The efficient continuum model can provide a more accurate estimation of the hydrogen storage capacity than the pure DFT calculations. Furthermore, the expensive grand canonical ensemble (μNT) simulations combining wi…

Experimental investigation on lithium borohydride hydrolysis

2010

Abstract Lithium borohydride, one of the highest energy density chemical energy carriers, is considered as an attractive potential hydrogen storage material due to its high gravimetric hydrogen density (19.6%). Belonging to borohydride compounds, it presents a real issue to overcome aims fixed by the U.S. Department of Energy in the field of energy, and so crystallizes currently attention and effort to use this material for large scale civil and military applications. However, due to its important hygroscopicity, lithium borohydride is a hazardous material which requires specific handling conditions for industrial aspects. In order to understand much more the reaction mechanism involved bet…

Annual runoff assessment in arid and semiarid Mediterranean watersheds under the Budyko's framework

2017

The solution of many practical water problems is strictly connected to the availability of reliable and widespread information about runoff. The estimation of mean annual runoff and its interannual variability for any basin over a wide region, even if ungauged, would be fundamental for both water resources assessment and planning and for water quality analysis. Starting from these premises, the main aim of this work is to show a new approach, based on the Budyko's framework, for mapping the mean annual surface runoff and deriving the probability distribution of the annual runoff in arid and semiarid watersheds. As a case study, the entire island of Sicily, Italy, is here proposed. First, ti…

Climatic changes in yield index and soil water deficit trends in China

2000

Long-term trends of the combined effects of evapotranspiration and precipitation effect surface hydrology and soil water and consequently natural and agricultural ecosystems. This paper analyses yield index and soil water deficit time series derived from water balance calculations for multiple cropping systems with FAO methodology. The analysis shows that yield index values have increased and soil water deficits have consequently decreased over much of China during 1954‐1993. The likely parameters contributing to this trend are precipitation changes north of 35 N and maximum evapotranspiration as well as available soil water trends south of this line. Increasing the assumed maximum soil wat…

Combining a data-driven approach with seasonal forecasts data to predicting reservoir water volume in the Mediterranean area.

2021

<p>Artificial reservoirs are one of the main water supply resources in the Mediterranean areas; their management can be strongly affected by the problems of drought and water scarcity. The reservoir water level is the result of the hydrological processes occurring in the upstream catchment, which, in turn, depend on meteorological variables, such as rainfall and temperature. It follows that a reliable forecast model of the meteorological forcing, along with a reliable water balance model, could enhance the correct management of a reservoir. With regard to the rainfall/temperature forecast model, the use of forecast climate data in the mid-term may provide further support for t…

Neutron-Induced Effects on a Self-Refresh DRAM

2022

International audience; The field of radiation effects in electronics research includes unknowns for every new device, node size, and technical development. In this study, static and dynamic test methods were used to define the response of a self-refresh DRAM under neutron irradiation. The neutron-induced effects were investigated and characterised by event cross sections, soft-error rate, and bitmaps evaluations, leading to an identification of permanent and temporary stuck cells, single-bit upsets, and block errors. Block errors were identified in different patterns with dependency in the addressing order, leading to up to two thousand faulty words per event, representing a real threat fr…