Search results for " Spectra"
showing 10 items of 709 documents
Capacity Analysis in Downlink WCDMA Systems Using Soft Handover Techniques With SIR-Based Power Control and Site Selection Diversity Transmission
2006
This work analyzes the downlink performance of a WCDMA system with site selection diversity transmission power control (SSDT) during soft handover mode. Signal to interference ratio (SIR) power control techniques are modeled and used in the simulations of this analysis. The study is focused on finding the optimum soft handover margin in terms of maximum system capacity under energy-per-bit to noise spectral density ratio (Eb/N0) quality requirements. The results of this analysis show an increase in user capacity of about 15 -20 % for optimum soft handover margins of 5 – 5.5 dB. Nevertheless, the resources required (number of scrambling codes) by base station increase faster than the number …
Combination of modal responses consistent with seismic input representation
2004
The well-known modal superposition method for the evaluation of seismic response by the complete quadratic modal combination rule (CQC) is revisited. The most widely used version of the CQC rule utilizes correlation coefficients derived for white-noise excitation and neglects the influence of peak factor variation on the response. Here a simplified procedure for evaluation of correlation coefficients and peak factors consistent with the power spectral density of seismic excitation is proposed. The procedure is based on an approximate analytic expression for direct evaluation of the power spectral density of the excitation consistent with any prefixed response spectrum, and the evaluation of…
Oxidation of diclofenac in the presence of iron(II) octacarboxyphthalocyanine
2021
Abstract This paper presents the results of the research on the influence of catalytic activity of iron(II) octacarboxyphthalocyanines (FePcOC) on the transformation of diclofenac (DCF) which is the most popular anti-inflammatory analgesic. Diclofenac poses a serious threat to the natural environment. The paper demonstrates that diclofenac, in the presence a monomeric form of iron octacarboxyphthalocyanine and hydroxyl radicals (HO•) (from H2O2), undergoes a transformation into diclofenac-2,5-iminoquinone (DCF-2,5-IQ), causing distinct changes in the UV–Vis absorption spectrum. In the presence of iron octacarboxyphthalocyanine and H2O2, the previously colourless diclofenac solution becomes …
The distribution of Rare Earth Elements discriminates the growth substrate of Vitis vinifera L.
2021
Sustainable agricultural, food-related strategies and geographic traceability require understanding of the plant physiological response to stress potentially generated by contaminated soils. Here, we have investigated the effect of contaminated substrate on growth of Vitis vinifera L. plants analysing the distribution of full Rare Earth Elements (REE) spectra in different parts of the plant. Experiments were carried out using pristine plants growing in a handmade substrate (blank experiment) and in REE artificially-enriched soil (spiked experiment). Our results show that both plant mass and REE amount in leaves are not influenced by the substrate enrichment while roots are by one-order of m…
Towards an accurate molecular orbital theory for excited states : Ethene, butadiene, and hexatriene
1993
A newly proposed quantum chemical approach for ab initio calculations of electronic spectra of molecular systems is applied to the molecules ethene, trans‐1,3‐butadiene, and trans‐trans‐1,3,5‐hexatriene. The method has the aim of being accurate to better than 0.5 eV for excitation energies and is expected to provide structural and physical data for the excited states with good reliability. The approach is based on the complete active space (CAS) SCF method, which gives a proper description of the major features in the electronic structure of the excited state, independent of its complexity, accounts for all near degeneracy effects, and includes full orbital relaxation. Remaining dynamic ele…
Light-component spectrum of the primary cosmic rays in the multi-TeV region measured by the ARGO-YBJ experiment
2012
The ARGO-YBJ experiment detects extensive air showers in a wide energy range by means of a full-coverage detector which is in stable data taking in its full configuration since November 2007 at the YBJ International Cosmic Ray Observatory (4300 m a.s.l., Tibet, People's Republic of China). In this paper the measurement of the light-component spectrum of primary cosmic rays in the energy region $(5\textdiv{}200)\text{ }\text{ }\mathrm{TeV}$ is reported. The method exploited to analyze the experimental data is based on a Bayesian procedure. The measured intensities of the light component are consistent with the recent CREAM results and higher than that obtained adding the proton and helium sp…
Extrapolation of water and formaldehyde harmonic and anharmonic frequencies to the B3LYP/CBS limit using polarization consistent basis sets
2010
The harmonic and anharmonic frequencies of fundamental vibrations in formaldehyde and water were successfully estimated using the B3LYP Kohn-Sham limit. The results obtained with polarization- and correlation-consistent basis sets were fitted with a two-parameter formula. Anharmonic corrections were obtained by a second order perturbation treatment (PT2). We compared the performance of the PT2 scheme on the two title molecules using SCF, MP2 and DFT (BLYP, B3LYP, PBE and B3PW91 functionals) methods combined with polarization consistent pc-n (n = 0, 1, 2, 3, 4) basis sets, Dunning’s basis sets (aug)-cc-pVXZ where X = D, T, Q, 5, 6 and Pople’s basis sets up to 6-311++G(3df,2pd). The influence…
On the interpretability and computational reliability of frequency-domain Granger causality
2017
This Correspondence article is a comment which directly relates to the paper “A study of problems encountered in Granger causality analysis from a neuroscience perspective” (Stokes and Purdon, 2017). We agree that interpretation issues of Granger causality (GC) in neuroscience exist, partially due to the historically unfortunate use of the name “causality”, as described in previous literature. On the other hand, we think that Stokes and Purdon use a formulation of GC which is outdated (albeit still used) and do not fully account for the potential of the different frequency-domain versions of GC; in doing so, their paper dismisses GC measures based on a suboptimal use of them. Furthermore, s…
Fractional Spectral Moments for Digital Simulation of Multivariate Wind Velocity Fields
2012
In this paper, a method for the digital simulation of wind velocity fields by Fractional Spectral Moment function is proposed. It is shown that by constructing a digital filter whose coefficients are the fractional spectral moments, it is possible to simulate samples of the target process as superposition of Riesz fractional derivatives of a Gaussian white noise processes. The key of this simulation technique is the generalized Taylor expansion proposed by the authors. The method is extended to multivariate processes and practical issues on the implementation of the method are reported.
Features of the Energy Spectrum of Cosmic Rays above 2.5×10$^{18}$ eV Using the Pierre Auger Observatory
2020
We report a measurement of the energy spectrum of cosmic rays above $2.5{\times} 10^{18}$ eV based on $215,030$ events. New results are presented: at about $1.3{\times} 10^{19}$ eV, the spectral index changes from $2.51 \pm 0.03 \textrm{ (stat.)} \pm 0.05 \textrm{ (sys.)}$ to $3.05 \pm 0.05 \textrm{ (stat.)}\pm 0.10\textrm{ (sys.)}$, evolving to $5.1\pm0.3\textrm{ (stat.)} \pm 0.1\textrm{ (sys.)}$ beyond $5{\times} 10^{19}$ eV, while no significant dependence of spectral features on the declination is seen in the accessible range. These features of the spectrum can be reproduced in models with energy-dependent mass composition. The energy density in cosmic rays above $5{\times} 10^{18}$ eV …