Search results for " Spectra"
showing 10 items of 709 documents
Quantification of minerals from ATR-FTIR spectra with spectral interferences using the MRC method.
2017
A method for quantifying the individual components of mineral samples based on attenuated total reflectance - Fourier transform infrared spectroscopy (ATR-FTIR) is described, extending the constant ratio (CR) method to analytes absorbing in a common range of wavenumbers. Absorbance values in the spectral region where the analytes absorb relative to the absorbance of an internal standard absorbing at a wavenumber where the analytes do not absorb, permits the quantification of N analytes using measurements at N fixed wavenumbers. The method was tested for mixtures of albite, orthoclase, kaolin and quartz.
A study of dimethyltin(IV)-L-cysteinate in aqueous solution
1988
The in vivo activity of some R2Sn-L-cysteinate complexes (R = Me, Et, n-Bu) against murine P-388 leukaemia has been tested. Only the Et2Sn(IV) complex showed a marginal positive effect. Trigonal bipyramidal tin environments with two carbon (R) atoms and the sulfur atom in the equatorial plane and oxygen (carboxylate) and nitrogen (NH2) in apical positions have been proposed for the solid compexes (R = Me, Et, n-Bu, Ph) on the basis of experimental Mossbauer parameters and infrared (IR) data. Aqueous solutions of the Me2SnL-cysteinate have been studied by IR, 1H NMR and 119Sn Mossbauer spectroscopy (in frozen solution) at different pH values to identify the Me2Sn(IV) species present. At pH >…
Sensitivity of noble gas NMR parameters to the heterocyclic ring proximity. Density functional theory studies of Ne–furan and Ar–furan complexes
2014
Theoretical modeling of noble gas interaction with furan as a simple heterocyclic ring was performed. The structures of neon–furan and argon–furan complexes were calculated at the MP2, M06-2X, CAM-B3LYP, APFD, and VSXC levels of theory using 6-311++G** basis set. The predicted 21Ne and 39Ar NMR chemical shifts for the Ne–furan and Ar–furan complexes calculated with pcS-3 and aug-pcS-3 basis sets were sensitive to the presence of the aromatic furan ring. Our results indicate a higher sensitivity of the neon and argon NMR probes than the previously reported 3He NMR spectroscopic parameters in studies of small heterocyclic rings containing the oxygen atom.
Gravitational Waves and Gamma-Rays from a Binary Neutron Star Merger: GW170817 and GRB 170817A
2017
On 2017 August 17, the gravitational-wave event GW170817 was observed by the Advanced LIGO and Virgo detectors, and the gamma-ray burst (GRB) GRB 170817A was observed independently by the Fermi Gamma-ray Burst Monitor, and the Anticoincidence Shield for the Spectrometer for the International Gamma-Ray Astrophysics Laboratory. The probability of the near-simultaneous temporal and spatial observation of GRB 170817A and GW170817 occurring by chance is $5.0\times 10^{-8}$. We therefore confirm binary neutron star mergers as a progenitor of short GRBs. The association of GW170817 and GRB 170817A provides new insight into fundamental physics and the origin of short gamma-ray bursts. We use the ob…
In-medium jet shape from energy collimation in parton showers: Comparison with CMS PbPb data at 2.76 TeV
2014
Abstract: We present the medium-modified energy collimation in the leading-logarithmic approximation (LLA) and next-to-leading-logarithmic approximation (NLLA) of QCD. As a consequence of more accurate kinematic considerations in the argument of the Dokshitzer-Gribov-Lipatov-Altarelli-Parisi (DGLAP) fragmentation functions (FFs) we find a new NLLA correction O ð α s Þ which accounts for the scaling violation of DGLAP FFs at small x . The jet shape is derived from the energy collimation within the same approximations and we also compare our calculations for the energy collimation with the event generators PYTHIA 6 and Y A JEM for the first time in this paper. The modification of jets by the …
On vibrating thin membranes with mass concentrated near the boundary: an asymptotic analysis
2018
We consider the spectral problem \begin{equation*} \left\{\begin{array}{ll} -\Delta u_{\varepsilon}=\lambda(\varepsilon)\rho_{\varepsilon}u_{\varepsilon} & {\rm in}\ \Omega\\ \frac{\partial u_{\varepsilon}}{\partial\nu}=0 & {\rm on}\ \partial\Omega \end{array}\right. \end{equation*} in a smooth bounded domain $\Omega$ of $\mathbb R^2$. The factor $\rho_{\varepsilon}$ which appears in the first equation plays the role of a mass density and it is equal to a constant of order $\varepsilon^{-1}$ in an $\varepsilon$-neighborhood of the boundary and to a constant of order $\varepsilon$ in the rest of $\Omega$. We study the asymptotic behavior of the eigenvalues $\lambda(\varepsilon)$ and the eige…
Charged-particle multiplicities in pp interactions measured with the ATLAS detector at the LHC
2011
Measurements are presented from proton–proton collisions at centre-of-mass energies of \sqrt{s} = 0.9 , 2.36 and 7 TeV recorded with the ATLAS detector at the LHC. Events were collected using a single-arm minimum-bias trigger. The charged-particle multiplicity, its dependence on transverse momentum and pseudorapidity and the relationship between the mean transverse momentum and charged-particle multiplicity are measured. Measurements in different regions of phase space are shown, providing diffraction-reduced measurements as well as more inclusive ones. The observed distributions are corrected to well-defined phase-space regions, using model-independent corrections. The results are compared…
Relationship between the effective cloud optical depth and different atmospheric transmission factors
2015
This study examines the sensitivity of cloud optical depth (COD) for overcast conditions to radiation transmission using data collected in Valencia, Spain. These relationships are provided as simple empirical functions, therefore avoiding the need to apply complex model minimisation schemes to obtain COD. Comparisons are presented between COD obtained by a minimization method and several radiation transmission factors comprising a clearness index (kt), a modified version (kt'), a cloud modification factor (CMF) and its modified version (CMF'). Additionally, a statistical model of COD proposed by J.C. Barnard and C.N. Long (2004) is tested with our data. Statistical relationships between COD…
The erythemal clearness index for Valencia, Spain
2009
The values of three clearness indices have been measured for the city of Valencia: kt, the clearness index for the whole solar spectrum, ktUV the clearness index for the ultraviolet range, and the erythemal clearness index for the erythemal radiation ktUVER, corresponding to the solar radiation weighted by the erythemal action spectrum on human skin, normalized with respect to the solar constant corresponding to that spectrum. The measurements of ktUV reached values that were approximately 54% of that corresponding to kt, while those of ktUVER were much smaller. Some statistics of the erythemal clearness index have been calculated both for monthly as well as hourly means. The shape of the d…
Apparent absorption of solar spectral irradiance in heterogeneous ice clouds
2010
[1] Coordinated flight legs of two aircraft above and below extended ice clouds played an important role in the Tropical Composition, Cloud and Climate Coupling Experiment (Costa Rica, 2007). The Solar Spectral Flux Radiometer measured up- and downward irradiance on the high-altitude (ER-2) and the low-altitude (DC-8) aircraft, which allowed deriving apparent absorption on a point-by-point basis along the flight track. Apparent absorption is the vertical divergence of irradiance, calculated from the difference of net flux at the top and bottom of a cloud. While this is the only practical method of deriving absorption from aircraft radiation measurements, it differs from true absorption when…