Search results for " Spectroscopy"
showing 10 items of 6851 documents
Raman spectroscopy of glycolic acid complexes with N2
2019
High overtone excitation induced conformational isomerization of glycolic acid – nitrogen complex in an argon matrix was investigated by Raman spectroscopy. The interaction between glycolic acid and nitrogen change the green light (532 nm) induced isomerization processes compared to non-complexed glycolic acid. The 180° rotation around of the Csingle bondC bond and stabilization of carboxyl Odouble bondCsingle bondOsingle bondH dihedral angle to trans position were the main conformational changes observed in the complex of the lowest energy conformer and nitrogen. Interestingly, only one stable light-induced conformational product was observed, which isomerises back to the lowest energy con…
Spins and magnetic moments of 58;60;62;64Mn ground states and isomers
2015
The odd-odd 54;56;58;60;62;64Mn isotopes (Z = 25) were studied using bunched-beam collinear laser spectroscopy at ISOLDE, CERN. From the measured hyperfine spectra the spins and magnetic moments of Mn isotopes up to N = 39 were extracted. The previous tentative ground state spin assignments of 58;60;62;64Mn are now firmly determined to be I = 1 along with an I = 4 assignment for the isomeric states in 58;60;62Mn. The I = 1 magnetic moments show a decreasing trend with increasing neutron number while the I = 4 moments remain quite constant between N = 33 and N = 37. The results are compared to large-scale shell-model calculations using the GXPF1A and LNPS effective interactions. The excellen…
Discovery of the new isotopes ²⁴⁰Es and ²³⁶Bk and in-beam spectroscopic studies of ²⁴⁴Cf
2017
The hitherto unknown neutron-deficient nuclei 240Es and 236Bk were synthesised using the fusion-evaporation reaction 209Bi(34S,3n)240Es. The ritu gas-filled recoil separator and the great spectrometer were used in this decay spectroscopic study. The measured electron-capture delayed fission (ECDF) branches in both of the new isotopes complement the experimental data available in the heavier odd-odd Es and Bk isotopes. Furthermore, the ECDF branches show a continuation in the exponential increase of the ECDF probabilities as a function of QEC − Bsf when approaching the proton dripline. In addition, an in-beam γ-ray spectroscopic study of the neutron-deficient isotope 244Cf was made using the fus…
Decay spectroscopy of the very neutron-deficient lead and thallium isotopes 178,179Pb and ¹⁷⁹Tl
2018
This thesis reports on the production of the very neutron-deficient isotopes 178,179Pb and 179Tl, using heavy-ion fusion-evaporation reactions. The gas-filled separator RITU and the GREAT spectrometer at its focal plane position were used for the decay spectroscopy study. The α decay of 178Pb and its α-decay chain were studied through α-α correlations. The α-particle energy and half-life were measured for 178Pb as, Eα= 7610(30) keV and t1/2 = 0.21−+0.21 0.08 ms, respectively. The half-life is consistent with recent theoretical calculations using the Coulomb and Proximity Potential Model (CPPM). The hindrance factor for 178Pb was deduced and corresponds to an unhindered Δl = 0 transition. Th…
Detailed spectroscopy of the neutron-deficient bismuth isotopes ¹⁹³,¹⁹⁵Bi
2015
Two experiments aiming to study the shape coexistence and competing structures in 193Bi and 195Bi isotopes have been performed at the Accelerator laboratory of the University of Jyv askyl a, Finland (JYFL). Many new states have been found, hugely extending the previously known level schemes for both isotopes. The i13=2 bands were extended up to I = 45/2+ in both the 193;195Bi isotopes. In case of 193Bi, the I = 31/2+ member of the i13=2 band was found to de-excite also to a long-lived isomeric state. This link determines the energy of the isomeric state to be 2350(1) keV and suggests a spin and parity of 29/2+. The half-life of the isomeric state was measured to be 85(3) s. A level structur…
Local Structure Studies of Ti for SrTi16O3 and SrTi18O3 by Advanced X-ray Absorption Spectroscopy Data Analysis
2015
Strontium titanate is a model quantum paraelectric in which in the region of dominating quantum statistics the ferroelectric instability is inhibited due to nearly complete compensation of the harmonic contribution into ferroelectric soft mode frequency by the zero-point motion contribution. The enhancement of atomic masses by the substitution of 18O for 16O decreases the zero-point atomic motion and low-T ferroelectricity in SrTi18O3 is realized. In this study we report on the local structure of Ti in SrTi16O3 and SrTi18O3 by Ti K-edge extended x-ray absorption fine structure measurements in temperature range 6 – 300 K.
Electronic spectroscopy of I2-Xe complexes in solid Krypton
2012
In the present work, we have studied ion-pair states of matrix-isolated I2 with vacuum-UV absorption and UV-vis-NIR emission, where the matrix environment is systematically changed by mixing Kr with Xe, from pure Kr to a more polarizable Xe host. Particular emphasis is put on low doping levels of Xe that yield a binary complex I2–Xe, as verified by coherent anti-Stokes Raman scattering (CARS) measurements. Associated with interaction of I2 with Xe we can observe strong new absorption in vacuum-UV, redshifted 2400 cm−1 from the X → D transition of I2. Observed redshift can be explained by symmetry breaking of ion-pair states within the I2–Xe complex. Systematic Xe doping of Kr matrices shows…
FTIR matrix isolation and theoretical studies of glycolic acid dimers
2018
Glycolic acid (GA) dimers were studied in low temperature argon matrices by means of FTIR spectroscopy. Experimentally, the dimers were produced when monomeric glycolic acid molecules were thermally mobilized upon annealing of argon matrices at 25–35 K. The experimental spectra observed upon annealing indicate the presence of three different dimer structures. Computationally, MP2 and DFT calculations were used to study the potential dimer species in order to scrutinize the possible dimer structures, their energetics and their spectral features. Altogether 27 local minima were found for dimer structures for the three lowest conformers of glycolic acid considered based on previous studies on …
Experimental and computational studies of unconventional main group compounds : stable radicals and reactive intermediates
2017
Ever since their discovery, radicals have intrigued the minds of experimental and theoretical chemists alike. While the vast majority of radicals are transient species, a large number of stable and persistent radicals are also known. This has enabled the use of radicals in different applications. For example, radicals are highly useful in chemical synthesis due to their selectivity and functional group tolerance. Detailed knowledge of the electronic structure of synthetic intermediates, both radical and non-radical, enables chemists to improve existing synthesis routes and to design completely new ones. This thesis is divided into two parts. The first part begins with an introduction to the…
Anion Responsive Molecular Switch Based on a Doubly‐Strapped Calix[4]pyrrole
2022
A calix[4]pyrrole receptor bearing two proximally meso - meso linking isophthaloyl straps displays open and closed states depending on the calix[4]pyrrole conformation. In the crystal structures and in non-polar solvent, the calix[4]pyrrole adopts open 1,3-alternate conformation with straps on the sides. Anion binding triggers a closed state of the receptor providing two types of interactions with an aromatic benzoate guest: hydrogen bonds from the pyrrolic groups and π ··· π interactions from the phenyl groups of the straps. Slow exchange dynamics was observed on the NMR timescale indicating that benzoate, acetate and chloride anions, which bind with relatively low affinity get kinetically…