Search results for " Stone"
showing 10 items of 160 documents
New biocides based on imidazolinium-functionalised hybrid mesoporous silica nanoparticles
2022
Here, we report the development of a new biocide based on hybrid mesoporous silica nanoparticles (MSN). The MSN was synthesized by condensation method in emulsion followed by grafting with two different silylated ionic liquid moieties, namely butyl imidazolinium bromide and imidazolinium propansulfonate betaine. Features of nanoparticles were characterized by Thermogravimetry, Infrared and ss-NMR Spectroscopy, and Transmission Electron Microscopy. The antibacterial properties were tested against a Gram-positive bacterial strain previously isolated from artefacts of interest in the field of Cultural Heritage. Interestingly, the hybrid material presents an antibacterial activity higher than i…
Environmental impact on historical monuments: The black crusts of the Venice lagoon
2020
Black crusts are typical decay forms on calcareous rocks in polluted urban environments. Their origin is due to “sulphation” reaction of calcium carbonate substrates (CaCO3), as a consequence of pH value decrease caused by SO2 in the polluted atmosphere. They can be therefore defined as a passive air pollution sampler. For the purpose of this work, samples from the historic center of Venice were analyzed. The city of Venice suffers in particular maritime and industrial pollution (Marghera industrial zone). By means of minero-petrographic and geochemical analyses, it was possible to obtain information on the mineralogy of the crust and its interaction with the underlying substrates, other th…
Degradation of stone materials in the archaeological context of the Greek-Roman Theatre in Taormina (Sicily, Italy)
2010
In the present work results on the degradation phenomena of stone materials in the Ancient Theatre of Taormina, one of the most important Greek–Roman monuments of Sicily, are reported. Artificial stone materials in different conservation conditions were investigated. Samples of salt efflorescences from brick walls and degraded setting mortars were taken from the open gallery in “summa cavea”. The chemical, physical and structural characterization was performed by means of X-Ray Photoelectron Spectroscopy (XPS), X-Ray Diffraction (XRD) and X-Ray Fluorescence (XRF), both in situ and ex situ. Results showed that the deterioration of stone materials is due to the aggressive action of the enviro…
Architetture di pietra e mestieri da perpetuare
2018
It is a short text written at the request of the Pro-loco of Sinagra , a small town in the province of Messina, dedicated to the traditional processing of the local stone.
Isotopic composition of cattle pancreatic stones: biological and geochemical implications.
1977
Latitudinal variations of the O18/O16-ratios of carbonate and phosphate of cattle pancreatic stones parallel a similar pattern of oxygen isotope values in rain water. C13/C12-ratios were virtually identical for the 7 cases studied. Isotopic measurements of mammalian hard tissues may be used for studying short-term climatic variations through Quaternary.
Interobserver and intraobserver variability in the radiological assessment of sialolithiasis using cone beam computed tomography
2021
Background Data regarding the inter- and intraobserver variability in the radiological assessment of sialolithiasis using cone beam computed tomography are missing in the current literature. This study assessed the inter- and intraobserver variability in the radiological assessment of sialolithiasis using cone beam computed tomography (CBCT). Material and Methods In 107 patients, 130 salivary glands (65 parotid and 65 submandibular) with clinical signs of obstruction were assessed by four independent observers; 2 residents OMFS and 2 experienced OMFS. The observers analyzed the CBCT images and determined the absence or presence of one or more salivary stones in the affected gland. This proc…
Alterazione e degrado dei materiali lapidei naturali
2008
The poor outcome of numerous restorations on artefacts of historical and artistic interest, after a few years, has shown how indispensable an accurate preliminary assessment of the conservation problems of the artefact is for the purposes of the reliability of the intervention. The correct diagnosis of the causes upstream of the phenomena of alteration and degradation, whether physiological or pathological, becomes the fundamental prerequisite for choosing any conservative or restorative intervention. From this point of view, in order to provide the reader with a useful tool for investigation and recognition in the field, the text illustrates the phenomena of alteration and degradation that…
Building materials and decay assessment of the Gerace Cathedral (Reggio Calabria, Southern Italy)
2023
A multi-analytical approach was employed for the first time to study the stone materials, wall paintings and related degradation forms in the Cathedral of Gerace (Reggio Calabria, southern Italy). With an area of around 1898 square meters, the Gerace Cathedral is the largest in Calabria: its construction dates back to the Norman era (between 1085 and 1120), and currently displays distinct features of Greek and Latin architectural orders. Despite having undergone numerous restorations, the church perfectly preserves its original buildings materials. Following an extensive site inspection campaign, supported by the experts dealing with building restoration, several areas were selected for ana…
Comparative analysis of direct and indirect costs of two minimally invasive techniques for the treatment of renal/ureteral calculi smaller than 2 cm
2020
[EN] Objective: To perform a comparative analysis of indirect and direct costs of two minimally invasive techniques (extracorporeal shock wave lithotripsy (ESWL) vs. ureteroscopy with holmium laser (URS/RIRS)) for the treatment of renal/ureteral calculi smaller than 2 cm. Material and methods: Prospective, comparative, non-randomized study of 84 patients treated for kidney stones smaller than 2 cm between January and December 2016. Of these, 38 (45.67%) were treated with ESWL (18 renal lithiasis and 20 ureteral lithiasis) and 46 (54.32%) with URS/RIRS (22 renal lithiasis and 24 ureteral lithiasis). A total of 19 (41.3%) patients in the URS/RIRS group and 15 (39.5%) patients in the ESWL grou…
Biliopancreatic Endoscopy in Altered Anatomy
2021
Background and Objectives: Anatomical post-surgical alterations of the upper gastrointestinal (GI) tract have always been challenging for performing diagnostic and therapeutic endoscopy, especially when biliopancreatic diseases are involved. Esophagectomy, gastrectomy with various reconstructions and pancreaticoduodenectomy are among the most common surgeries causing upper GI tract alterations. Technological improvements and new methods have increased the endoscopic success rate in these patients, and the literature has been rapidly increasing over the past few years. The aim of this systematic review is to identify evidence on the available biliopancreatic endoscopic techniques performed i…