Search results for " Thermodynamics"
showing 10 items of 288 documents
Fluid dynamics with saturated minijet initial conditions in ultrarelativistic heavy-ion collisions
2014
Using next-to-leading order perturbative QCD and a conjecture of saturation to suppress the production of low-energy partons, we calculate the initial energy densities and formation times for the dissipative fluid dynamical evolution of the quark-gluon plasma produced in ultrarelativistic heavy-ion collisions. We identify the framework uncertainties and demonstrate the predictive power of the approach by a good global agreement with the measured centrality dependence of charged particle multiplicities, transverse momentum spectra and elliptic flow simultaneously for the Pb+Pb collisions at the LHC and Au+Au at RHIC. In particular, the shear viscosity in the different phases of QCD matter is…
Three Duality Symmetries between Photons and Cosmic String Loops, and Macro and Micro Black Holes
2015
We present a review of two thermal duality symmetries between two different kinds of systems: photons and cosmic string loops, and macro black holes and micro black holes, respectively. It also follows a third joint duality symmetry amongst them through thermal equilibrium and stability between macro black holes and photon gas, and micro black holes and string loop gas, respectively. The possible cosmological consequences of these symmetries are discussed.
Chemical heterogeneities in the mantle: The equilibrium thermodynamic approach
2016
Abstract This study attempts to answer a simple and yet fundamental question in relation to our understanding of the chemical evolution of deep Earth and planetary interiors. Given two initially separate assemblages (lithologies) in chemical equilibrium can we predict the chemical and mineralogical compositions of the two assemblages when they are put together to form a new equilibrated system? Perhaps a common perception is that given sufficient time, the two assemblages will homogenize chemically and mineralogically, however from a chemical thermodynamic point of view, this is not the case. Certain petrological differences in terms of bulk composition, mineralogy and mineral abundance rem…
Two-state protein-like folding of a homopolymer chain
2010
Many small proteins fold via a first-order "all-or-none" transition directly from an expanded coil to a compact native state. Here we study an analogous direct freezing transition from an expanded coil to a compact crystallite for a simple flexible homopolymer. Wang-Landau sampling is used to construct the 1D density of states for square-well chains of length 128. Analysis within both the micro-canonical and canonical ensembles shows that, for a chain with sufficiently short-range interactions, the usual polymer collapse transition is preempted by a direct freezing or "folding" transition. A 2D free-energy landscape, built via subsequent multi-canonical sampling, reveals a dominant folding …
Simulations clarify when supercooled water freezes into glassy structures
2014
Although liquid water is a ubiquitous substance and its properties are crucial for all living species, the precise understanding of these properties is still a matter of active scientific research. One rather mysterious aspect concerns the conditions when undercooled water freezes not into ice crystals but into glass-like structures. Based on a rather novel type of computer simulation approach, in PNAS, Limmer and Chandler (1) propose a nonequilibrium phase diagram that attempts to clarify the conditions (temperature, pressure, cooling protocol) under which one should observe transitions from undercooled water to different forms of amorphous ice.
Phononic heat transport in the transient regime: An analytic solution
2016
We investigate the time-resolved quantum transport properties of phonons in arbitrary harmonic systems connected to phonon baths at different temperatures. We obtain a closed analytic expression of the time-dependent one-particle reduced density matrix by explicitly solving the equations of motion for the nonequilibrium Green's function. This is achieved through a well-controlled approximation of the frequency-dependent bath self-energy. Our result allows for exploring transient oscillations and relaxation times of local heat currents, and correctly reduces to an earlier known result in the steady-state limit. We apply the formalism to atomic chains, and benchmark the validity of the approx…
Kirkwood–Buff integrals of finite systems
2018
The Kirkwood–Buff (KB) theory provides an important connection between microscopic density fluctuations in liquids and macroscopic properties. Recently, Krüger et al. derived equations for KB integrals for finite subvolumes embedded in a reservoir. Using molecular simulation of finite systems, KB integrals can be computed either from density fluctuations inside such subvolumes, or from integrals of radial distribution functions (RDFs). Here, based on the second approach, we establish a framework to compute KB integrals for subvolumes with arbitrary convex shapes. This requires a geometric function w(x) which depends on the shape of the subvolume, and the relative position inside the subvolu…
RADIATION OF THE INNER HORIZON OF THE REISSNER–NORDSTRÖM BLACK HOLE
2005
Despite of over thirty years of research of the black hole thermodynamics our understanding of the possible role played by the inner horizons of Reissner-Nordstr\"om and Kerr-Newman black holes in black hole thermodynamics is still somewhat incomplete: There are derivations which imply that the temperature of the inner horizon is negative and it is not quite clear what this means. Motivated by this problem we perform a detailed analysis of the radiation emitted by the inner horizon of the Reissner-Nordstr\"om black hole. As a result we find that in a maximally extended Reissner-Nordstr\"om spacetime virtual particle-antiparticle pairs are created at the inner horizon of the Reissner-Nordstr…
AdS$_2$/CFT$_1$ correspondence and near-extremal black hole entropy
1999
We provide a realization of the AdS$_2$/CFT$_1$ correspondence in terms of asymptotic symmetries of the AdS$_2\times$S$^1$ and AdS$_2\times$S$^2$ geometries arising in near-extremal BTZ and Reissner-Nordstr\"om black holes. Cardy's formula exactly accounts for the deviation of the Bekenstein-Hawking entropy from extremality. We also argue that this result can be extended to more general black holes near extremality.
Thermal duality and thermodynamics of micro black holes
2015
Starting from a generalized black hole entropy with logarithmic area corrections, in this paper we obtain (for positive value of the coefficient of the correction term) a generalized equation of state for black holes with two dual branches. In one of them (the usual one for macro black holes) T ≃ 1/M, with T temperature and M mass. In the other one, for micro black holes, instead, T ≃ M. We compare the equilibrium and stability between macro black holes and electromagnetic radiation in a finite box with reflecting walls, with the dual situation corresponding to micro black holes and cosmic string loops, also in a finite box. In this model, the dual phenomenon of evaporation of unstable mac…