Search results for " Transformation"
showing 10 items of 1043 documents
Physical Cross Links in Amorphous PET, Influence of Cooling Rate and Ageing
2003
A Continuous Cooling Transformation (CCT) procedure can be used to distinguish the initial “state” of the amorphous PET samples produced upon solidification from the melt at different cooling rates. The material frozen at this stage behaves as a rubber when brought above the Tg due to the onset of physical cross links. The rubber is not a stable network, however, since physical cross links may eventually dissolve. Their size distribution, and possibly their number, depend on cooling rate and ageing. Some may be even stable above the glass transition and act as nuclei for further crystallization from the glass. Upon increasing cooling rate, size distribution becomes smaller and stability of …
Polyamorphic transformation induced by electron irradiation ina-SiO2glass
2009
We report a study by electron paramagnetic resonance of amorphous silicon dioxide $(a{\text{-SiO}}_{2})$ irradiated by 2.5 MeV electrons in the dose range from $1.2\ifmmode\times\else\texttimes\fi{}{10}^{3}$ to $5\ifmmode\times\else\texttimes\fi{}{10}^{6}\text{ }\text{kGy}$. By measuring the change in the splitting of the primary $^{29}\text{S}\text{i}$ hyperfine doublet of the ${E}_{\ensuremath{\gamma}}^{\ensuremath{'}}$ centers we evidenced an irradiation induced local (around the defects) densification of $a{\text{-SiO}}_{2}$. Our data show that the local degree of densification of the materials is significantly higher than that obtained by mean density measurements, suggesting that the …
Influence of plasticizers and cryogenic grinding on the high-cooling-rate solidification behavior of PBT/PET blends
2015
Two structurally different plasticizers (cyclic and linear) and the effect of cryogenic grinding on the solidification behavior at high cooling rates by a continuous cooling transformation approach of poly(butylene terephthalate)/poly(ethylene terephthalate), PBT/PET, blends are described. The solidification curve (density versus cooling rate) is confirmed as an effective tool to compare the differences in crystallization behavior under conditions mimicking processing. In comparison to the bulky cyclic plasticizer, the linear oligomeric one was found to have a more pronounced influence on the crystallization behavior. A 60/40 by weight PBT/PET blend shows a drop-off of density at ∼50 K/s. I…
Phase evolution in hot forging of dual phase titanium alloys: Experiments and numerical analysis
2014
Abstract Modern aeronautical and aerospace industries must face the demanding challenge of reducing operational consumption and production costs coming from materials and labor. Current trend of engineering is oriented to meet both requirements increasing the use of materials characterized by high specific resistance as titanium alloys. Hot forging can be used to reduce the production costs of titanium components: forging in closed dies of billets or semi-finished forms, at different temperatures above or below the β-transus temperature, allows the production of complex shapes with limited amount of edge trim removal and machining rework after forging. Unfortunately, as far as Ti–6Al–4V tit…
Friction Stir Processing of NiTi Shape Memory Alloy: Microstructural Characterization
2010
Shape Memory Alloys (SMA) are metal materials that, after being strained, come back to their original shape at a designated temperature. Welding NiTi alloys is not simple because when the material is melted, due to the high reactivity of the alloy elements, the typical shape memory properties may disappear. The solid state welding process, such as friction stir welding, is thus attractive for SMA joining and it exhibits potentials for achieving welded joints affected by microstructural changes that preserve the shape memory properties. The present study investigates the feasibility of friction stir welding process to join NiTi shape memory alloys; in order to analyse the welding process, it…
Energy Conversion: Solid Oxide Fuel Cells: First-Principles Modeling of Elementary Processes
2013
Fuel cells are electrochemical devices that directly transform the chemical free energy of combustion (e.g., H2 + O2 and CHx + O2) into electrical energy. The avoidance of a thermal detour guarantees high theoretical efficiency. As far as the temperature regimes are concerned, we distinguish between high temperature ceramic fuel cells, intermediate-temperature fuel cells, and low temperature (i.e., only slightly above room temperature) fuel cells. The high temperature fuel cells are usually based on oxide components (ternary transition metal oxides as cathodes, Ni or Cu cermets as anodes, and acceptor-doped zirconia or ceria as electrolytes). The high temperature necessary for ion conductio…
Investigation of eutectic transformation of Zn−Al alloy by DTA
1995
The paper discusses the investigation of crystallization of metals and alloys by differential thermal analysis (DTA). It was assumed that this method allows determination of the mechanism and kinetics of volumetric crystallization underiso conditions (e.g. anisothermal) on the basis of the parameters of the equation expressing an integral form of the DTA curve. From DTA, a course of eutectic transformation was determined for a technical Zn−Al alloy containing 4wt% Al. Investigations were carried out under continuous cooling at various rates and the kinetics parameters were determined with the KEKAM equation:-ln(1-x)=kln
Radiation effects on stress evolution and dimensional stability of large fusion energy structures
2021
Abstract We assess the effects of neutron irradiation on the deformation and stress evolution of large-scale fusion energy structures. This is accomplished through non-linear finite element structural analysis of the coupled thermal and mechanical fields at the Beginning-Of-Life (BOL), at 45 dpa, and at 90 dpa. Radiation effects include volumetric swelling and the influence of radiation on the mechanical properties. The system studied here is a large section of a full inboard module of an integrated structure comprising the First Wall and Blanket (FW/B) of a Dual Cooled Lithium-Lead (DCLL) energy conversion unit in the Fusion Nuclear Science Facility (FNSF). The structural material is the f…
Structural and Magnetic Properties of Epitaxial Ni<sub>2</sub>MnGa Thin Films
2009
We report on the preparation and investigation of epitaxial thin films of the magnetic shape memory alloy Ni2MnGa. For samples close to the stoichiometric composition we find that the phase transformation temperature is affected by the crystallographic orientation. Changes in the crystal structure due to the transformation are observed using temperature-dependent X-ray diffraction. Films with higher manganese content are in the martensitic state at room temperature. Those samples on Al2O3(11-20) reveal the 7-layered orthorhombic structure that allows strains up to 10 %. To avoid blocking of magnetostrictive effects by the substrate, free-standing films are prepared using water-soluble NaCl(…
Optimizing Energy Transduction of Fluctuating Signals with Nanofluidic Diodes and Load Capacitors
2018
[EN] The design and experimental implementation of hybrid circuits is considered allowing charge transfer and energy conversion between nanofluidic diodes in aqueous ionic solutions and conventional electronic elements such as capacitors. The fundamental concepts involved are reviewed for the case of fluctuating zero-average external potentials acting on single pore and multipore membranes. This problem is relevant to electrochemical energy conversion and storage, the stimulus-response characteristics of nanosensors and actuators, and the estimation of the accumulative effects caused by external signals on biological ion channels. Half-wave and full-wave voltage doublers and quadruplers can…