Search results for " Tunnel"
showing 10 items of 477 documents
Excess Electrons at Oxide Surfaces
2015
Excess electrons profoundly affect the properties of oxide surfaces. The present review deals with excess charges on rutile and anatase. These much studied titania polymorphs open with strong prospects regarding (photo)catalysis and dye-sensitized solar cells. In the complex landscape of the mechanisms of electron trapping and electron transfer toward adsorbates, excess electrons open with flexible model systems which are the focus of an extensive research effort.
Lateral Fusion of Chemical Vapor Deposited N = 5 Armchair Graphene Nanoribbons
2017
Bottom-up synthesis of low-bandgap graphene nanoribbons with various widths is of great importance for their applications in electronic and optoelectronic devices. Here we demonstrate a synthesis of N = 5 armchair graphene nanoribbons (5-AGNRs) and their lateral fusion into wider AGNRs, by a chemical vapor deposition method. The efficient formation of 10- and 15- AGNRs is revealed by a combination of different spectroscopic methods, including Raman and UV−visnear-infrared spectroscopy as well as by scanning tunneling microscopy. The degree of fusion and thus the optical and electronic properties of the resulting GNRs can be controlled by the annealing temperature, providing GNR films with o…
Comparison between probe stagnation point heat flux measurements and correlation formulas in SCIROCCO plasma wind tunnel tests
2012
A large part of the SCIROCCO Arc Heater Performance Map has been investigated. The heat flux measurements at the stagnation point of t he facility Calibratio Probe have been used to find an experimental fit. Such a formula ha s been compared with the predictions of the De Filippis-Serpico equation and the well known Fay-Riddell formula. Finally the experimental fit has been also compared with the Sa gner-Verant formula obtained at the ONERA F4 hypersonic plasma wind tunnel.
Dynamics of spin state conversion processes in the solid state
1989
High spin (HS) ⇌ low spin (LS) conversions in transition metal complexes are nonradiative transitions between spin states. In this contribution, we present a study of the temperature and pressure dependence of the HS ⇌ LS intersystem crossing dynamics. For some iron(II) spin-crossover complexes, the rate constants were determined by line shape analysis of57Fe Mossbauer spectra. Their temperature dependence is described by an Arrhenius equation, their pressure dependence is interpreted within absolute rate theory. HS → LS conversion rates at low temperatures were determined from the relaxation of light-induced formation of HS states, monitored by optical spectroscopy. Deviations from a simpl…
Intersystem crossing in Fe(II) coordination compounds
1994
Fe(II) spin-crossover systems can be quantitatively converted from the low-spin (LS) to the high-spin (HS) state well below the thermal transition temperature by irradiating either into the metal-ligand charge transfer or d-d absorption bands, and even in low-spin systems a transient population of the HS state can be achieved. This fact can be made use of to determine HS → LS relaxation rate constants for a wide variety of Fe(II) spin-crossover and low-spin systems. The HS → LS relaxation shows strong deviations from an Arrhenius behaviour, with nearly temperature-independent tunnelling below ∼70 K and a thermally activated process above ∼100 K. The range of more than 12 orders of magnitude…
A Contradiction between Pulsed and Steady-State Studies in the Recombination Kinetics of Close Frenkel Defects in KBr and KCl Crystals
1994
Theoretical study of the kinetics of the correlated annealing of pairs of close (geminate) F-H centers in KCl and KBr crystals controlled by their diffusion and elastic attraction shows that the multi-step (kink) decay in defect concentrations observed more than once in thermostimulated experiments takes place only for very close F-H center pairs which are no further than fourth nearest neighbors. On the other hand, it is demonstrated (both theoretically and experimentally) that such F-H center pairs should be destroyed by the tunneling recombination already at time ≤10 -4 s, i.e. much before beginning of the thermostimulated experiments. Possible explanations of this contradiction are sugg…
A Wind Tunnel and Theoretical Study of the Melting Behavior of Atmospheric Ice Particles. IV: Experiment and Theory for Snow Flakes
1990
Abstract An experiment in the Mainz vertical Cloud Tunnel is described in which natural and laboratory-made aggregates of snow crystals (snow flakes) were melted under free fall conditions in the vertical air stream of the tunnel, which was allowed to warm up at the rates experienced by falling snow flakes in the atmosphere. The variation of the fall mode, the fall velocity, and the percentage of ice melted, as a function of percentage of distance travelled for 99% melting was recorded by cinematography. The laboratory results were confirmed by the results of a theoretical heat transfer model which we developed for the melting of a snow flake. In this model a snow flake was idealized by an …
Design, construction and commissioning of the Braunschweig Icing Wind Tunnel
2018
Beyond its physical importance in both fundamental and climate research, atmospheric icing is considered as a severe operational condition in many engineering applications like aviation, electrical power transmission and wind-energy production. To reproduce such icing conditions in a laboratory environment, icing wind tunnels are frequently used. In this paper, a comprehensive overview on the design, construction and commissioning of the Braunschweig Icing Wind Tunnel is given. The tunnel features a test section of 0.5 m × 0.5 m with peak velocities of up to 40 m s−1. The static air temperature ranges from −25 to +30 °C. Supercooled droplet icing with liquid water contents up to 3 g m−3 c…
A Laboratory Dust Generator Applying Vibration to Soil Sample: Mineralogical Study and Compositional Analyses
2020
International audience; A laboratory study was carried out using a vibrating system (SyGAVib) to produce aerosols from four soils collected in the central Tunisian region around Sfax. The aim of this device is to mimic dust emission by natural wind erosion. Using compositional analysis, the dust produced was compared to (i) dust generated in a wind tunnel by the same soils, (ii) fine sieved and (iii) original bulk soils, and (iv) naturally occurring aerosol samples collected in the same area. The relative quartz content strongly decreases from bulk to fine soils, and again from fine soils to both wind tunnel and vibration‐generated aerosols. Compositional data analysis (CoDA) clearly shows …
Particle surface area dependence of mineral dust in immersion freezing mode: investigations with freely suspended drops in an acoustic levitator and …
2014
Abstract. The heterogeneous freezing temperatures of supercooled drops were measured using an acoustic levitator. This technique allows one to freely suspend single drops in the air without any wall contact. Heterogeneous nucleation by two types of illite (illite IMt1 and illite NX) and a montmorillonite sample was investigated in the immersion mode. Drops of 1 mm in radius were monitored by a video camera while cooled down to −28 °C to simulate freezing within the tropospheric temperature range. The surface temperature of the drops was contact-free, determined with an infrared thermometer; the onset of freezing was indicated by a sudden increase of the drop surface temperature. For compari…