Search results for " X-ray emission"

showing 3 items of 43 documents

Artificial cartilage bio-matrix formed of hyaluronic acid and Mg2+-polyphosphate.

2016

Here we show that inorganic polyphosphate (polyP), a polyanionic metabolic regulator consisting of multiple phosphate residues linked by energy-rich phosphoanhydride bonds, is present in the synovial fluid. In a biomimetic approach, to enhance cartilage synthesis and regeneration, we prepared amorphous polyP microparticles with Mg2+ as counterions. The particles were characterised by X-ray diffraction (XRD), energy-dispersive X-ray (EDX) and Fourier transformed infrared spectroscopic (FTIR) analyses. Similar particles were obtained after addition of Mg2+ ions to a solution containing hyaluronic acid, as a major component of the synovial fluid, and soluble Na-polyP. The viscous paste-like ma…

magnesium polyphosphatelcsh:Diseases of the musculoskeletal systemlcsh:Surgeryregenerative medicine02 engineering and technologyCartilage metabolism01 natural sciencesChondrocyteExtracellular matrixchemistry.chemical_compoundCollagen Type IIIChondrocytesX-Ray DiffractionPolyphosphatesHyaluronic acidSpectroscopy Fourier Transform InfraredSynovial FluidmedicineCell AdhesionSynovial fluidHumansMagnesiumRNA MessengerHyaluronic Acidmicroparticles010405 organic chemistryCartilagePolyphosphateSpectrometry X-Ray EmissionSOX9 Transcription Factorlcsh:RD1-811021001 nanoscience & nanotechnology0104 chemical sciencesExtracellular MatrixUp-Regulationosteoarthritismedicine.anatomical_structureCartilageCollagen Type IIIchemistrytissue engineeringBiophysicsMicroscopy Electron Scanninglcsh:RC925-9350210 nano-technologyBiomedical engineering
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Transition-edge sensors for particle-induced X-ray emission spectrometry

2018

A transition-edge sensor array has been applied to particle-induced X-ray emission. We have characterized the detector for quantitative analysis and obtained minimum detection limit over two orders of magnitude better compared to a silicon drift detector. We have also studied chemical effects in analysis of Ti, TiO2 and TiN using proton and heavy ion beams. A chemical shift for TiO2 was observed in proton measurements, and relative multiple ionization X-ray satellite line intensities changed between metallic Ti and other compounds with heavy ions. Detection of low energy X-rays down to 0.5 keV was achieved by installing a polycapillary lens in front of the transition-edge sensor array in ex…

particle-induced X-ray emissionhigh energy resolutiontransition-edge sensorchemical speciation
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Study of the thermochromic phase transition in CuMo1−xWxO4 solid solutions at the W L3-edge by resonant X-ray emission spectroscopy

2021

This is the peer reviewed version of the following article: I. Pudza, A. Kalinko, A. Cintins, A. Kuzmin, Acta Mater. 205 (2021) 116581, which has been published in final form at https://www.sciencedirect.com/science/article/abs/pii/S1359645420310181 This article may be used for non-commercial purposes in accordance with Elsevier Terrms and Conditions for Self-Archiving.

resonant X-ray emission spectroscopy (RXES)crystal-field splitting:NATURAL SCIENCES:Physics [Research Subject Categories]CuMo1−xWxO4high-energy resolution fluorescence detected X-ray absorption near-edge structure (HERFD-XANES)
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