Search results for " Yield"
showing 10 items of 550 documents
Electro-catalytic and photo-catalytic reformation of CO 2 –reactions and efficiencies processes (Review)
2019
Energy harvesting with lowest environmental impact is one of key elements for cleaner future. Photocatalytic as well as electrocatalytic CO2 reformation processes are considered as prominent methods. Thus, extensive research of CO2 reformation is being done to find the right materials that holds crucial qualities. For photocatalysis that includes pronounced separation of light-generated opposite sign charge carriers, sensitivity to visible light, high quantum yield. In electrocatalysis high CO2 adsorption, chemical stability, multielectron reaction catalysts are necessary. Additionally, materials participating in the reaction process must be provided with charge carriers at proper reduction…
Magnitude and distribution of stresses in composite resin and sound dentine interface with mechanical retentions
2014
Background: Adhesive systems are constantly subjected to mechanical and chemical stresses that negatively impact the integrity and durability of the dentine-adhesive interface. Despite the lack of evidence to support or reject the clinical indication for mechanical retention, the potential further contribution of these preparations to the behavior of the composite resin-sound dentine bond has been rarely addressed. The authors evaluated by finite element analysis the effect of mechanical retention on the magnitude and distribution of stresses in a composite resin-sound dentin bonding interface when subjected to tensile and shear forces. Material and Methods: A three-dimensional model was cr…
Two-photon absorption dye based on 2,5-bis(phenylacrylonitrile)thiophene with aggregration enhanced fluorescence
2016
This paper reports the synthesis and characterization of a 2,5-bis(phenylacrylonitrile) thiophene based two-photon dye, designed to show enhancement in fluorescence quantum yield in nanoaggregated form. Strong solvatochromism has been observed and explained by the favoritism of locally excited (LE) or internal charge transfer (ICT) state depending on the solvent polarity. Aqueous dispersions of nanoparticles have been prepared and investigated regarding their optical properties which were correlated to the LE and ICT state and the molecular structure of the aggregates. (C) 2016 Optical Society of America
High Optical Performance of Cyan‐Emissive CsPbBr3 Perovskite Quantum Dots Embedded in Molecular Organogels
2021
This is the pre-peer reviewed version of the following article: High Optical Performance of Cyan‐Emissive CsPbBr3 Perovskite Quantum Dots Embedded in Molecular Organogels, which has been published in final form at https://doi.org/10.1002/adom.202001786. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions." Perovskite quantum dots (PQDs) have fascinating optoelectronic properties, such as high photoluminescence quantum yield (PLQY) for a broad range of materials, and the possibility to obtain different bandgaps with the same material or halide combinations. Nevertheless, blue‐emissive materials generally present…
β-C3N4 Nanocrystals: Carbon Dots with Extraordinary Morphological, Structural, and Optical Homogeneity
2018
Carbon nanodots are known for their appealing optical properties, especially their intense fluorescence tunable in the visible range. However, they are often affected by considerable issues of optical and structural heterogeneity, which limit their optical performance and limit the practical possibility of applying these nanoparticles in several fields. Here we developed a synthesis method capable of producing a unique variety of carbon nanodots displaying an extremely high visible absorption strength (ε > 3 × 106 M(dot)−1 cm−1) and a high fluorescence quantum yield (73%). The high homogeneity of these dots reflects in many domains: morphological (narrow size distribution), structural (q…
Energy level determination in bulk heterojunction systems using photoemission yield spectroscopy: case of P3HT:PCBM
2018
Financial support provided by Scientific Research Project for Students and Young Researchers Nr. SJZ2015/20 realized at the Institute of Solid State Physics, University of Latvia, is greatly acknowledged. This work has been supported by the Latvian State Research Program on Multifunctional Materials IMIS2. Jennifer Mann from Physical Electronics is greatly acknowledged for providing UPS data.
Elastoplastic analysis by active macro-zones with linear kinematic hardening and von Mises materials.
2014
In this paper a strategy to perform elastoplastic analysis with linear kinematic hardening for von Mises materials under plane strain conditions is shown. The proposed approach works with the Symmetric Galerkin Boundary Element Method applied to multidomain problems using a mixed variables approach, to obtain a more stringent solution. The elastoplastic analysis is carried out as the response to the loads and the plastic strains, the latter evaluated through the self-equilibrium stress matrix. This matrix is used both, in the predictor phase, for trial stress evaluation and, in the corrector phase, for solving a nonlinear global system which provides the elastoplastic solution of the active…
Sets versus trial sequences, Hausdorff versus von Mises: “Pure” mathematics prevails in the foundations of probability around 1920
2010
Abstract The paper discusses the tension which occurred between the notions of set (with measure) and (trial-) sequence (or—to a certain degree—between nondenumerable and denumerable sets) when used in the foundations of probability theory around 1920. The main mathematical point was the logical need for measures in order to describe general nondiscrete distributions, which had been tentatively introduced before (1919) based on von Mises’s notion of the “Kollektiv.” In the background there was a tension between the standpoints of pure mathematics and “real world probability” (in the words of J.L. Doob) at the time. The discussion and publication in English translation (in Appendix ) of two …
Experimental study of the pyrolysis of waste bitumen for oil production
2020
Abstract This work focuses on bitumen slow pyrolysis. Mass and energy yields of oil, solid and gas were obtained from pyrolysis experiments using a semi-batch reactor in a nitrogen atmosphere, under three non-isothermal conditions (maximum temperature: 450 °C, 500 °C and 550 °C). The effect of temperature on the product yields was discussed. The gas compositions were analysed using gas chromatography (GC) and the heating value of oil and solid residue was also measured. Using a thermo-gravimetric analyser, kinetic parameters were evaluated through Ozawa-Flynn-Wall (OFW) method. Results showed that oil yield is maximum at 500 °C (50%). Moreover, gas yield increased with increasing pyrolysis …
A Simple Analytical Model for Remote Assessment of the Dynamics of Biomass Accumulation
2011
Efficient means for assessment of the dynamics and the state of the stocks of renewable assets such as wood biomass are important for sustainable supplies satisfying current needs. So far attention has been paid mainly to the economic aspects of forest management while ecological problems are rising with the expected transfer from fossil to renewable resources supplies of which from forest being essential for traditional consumers of wood and for emerging biorefineries. Production of biomass is more reliant on assets other than money the land (territory) available and suitable for the purpose being the first in the number. Studies of the ecological impacts (the “footprint”) of sustainable u…