Search results for " antarctica"
showing 5 items of 15 documents
Regions gelades: Àrtic i Antàrtica en el nou mileni
2012
Xerrada sobre l'àrtic i l'antàrtic en el nou mil · lenni donada en el congrés sobre lleis regionals i internacionals realitzat a València del 13 al 15 de setembre.
Candida antarctica Lipase A-Based Enantiorecognition of a Highly Strained 4-Dibenzocyclooctynol (DIBO) Used for PET Imaging
2020
The enantiomers of aromatic 4-dibenzocyclooctynol (DIBO), used for radiolabeling and subsequent conjugation of biomolecules to form radioligands for positron emission tomography (PET), were separated by kinetic resolution using lipase A from Candida antarctica (CAL-A). In optimized conditions, (R)-DIBO [(R)-1, ee 95%] and its acetylated (S)-ester [(S)-2, ee 96%] were isolated. In silico docking results explained the ability of CAL-A to differentiate the enantiomers of DIBO and to accommodate various acyl donors. Anhydrous MgCl2 was used for binding water from the reaction medium and, thus, for obtaining higher conversion by preventing hydrolysis of the product (S)-2 into the starting materi…
Biodiesel via in situ wet microalgae biotransformation: Zwitter-type ionic liquid supported extraction and transesterification
2017
The production of biodiesel derived from microalgae is among the most forthcoming technologies that provide an ecologic alternative to fossil fuels. Herein, a method was developed that enables the direct extraction and conversion of algal oil to biodiesel without prior isolation. The reaction occurs in aqueous media catalyzed by immobilized Candida antarctica lipase B (Novozyme 435). Zwitter-type ionic liquids were used as cocatalyst to improve the selectivity and reactivity of the enzyme. In a model reaction with sunflower oil, 64% biodiesel was obtained. Applying this method to a slurry of whole-cell Chlorella zof ingiensis in water resulted in 74.8% of lipid extraction, with 27.7% biotra…
High-resolution orthophoto map and digital surface models of the largest Argentine Islands (the Antarctic) from unmanned aerial vehicle photogrammetry
2020
This study presents the first high-resolution orthophoto maps and digital surface models (DSMs) of the largest Argentine Islands, West Antarctica. Aerial surveys with small unmanned aerial vehicle (UAV) were performed in Austral summer, 2018, taking 10,041 aerial photographs. Accuracy requirements were ensured using ground control points (GCPs). A resolution of 3.4 and 6.8 cm/px of orthomosaics and DSMs is reached on average, and the RMS reprojection error is 0.22 m on average. We report the morphometric parameters of surveyed islands and discuss issues related to accuracy and the usage of UAVs in polar conditions. This study demonstrates that small and low cost UAVs can be successfully use…
The Antarctic Treaty System
2022
In this publication, I talk about the Antarctic Treaty System