Search results for " assi"

showing 10 items of 676 documents

Photo-assisted formation of a chelating diphos ligand from PPh3 and a cyclometallated [P(C6H4)(C6H5)2]− ligand. Crystal structure of Pd{η2-o-[P(C6H5)…

2000

Abstract The cyclometallated palladium compound, Pd[η2-(C6H4)P(C6H5)2]Br[P(C6H5)3] (1), in the solid state by action of light, evolves to give Pd{η2-o-[P(C6H5)2]2(C6H4)}Br2 (2). This compound contains the diphosphine, o-[P(C6H5)2]2(C6H4), as chelated ligand that is formed by a couple reaction of the metallated ligand η2-[(C6H4)P(C6H5)2]− and the coordinated arylphosphine. A study by NMR spectroscopy confirms that the o-phenylene bridge in the diphosphine ligand in 2 comes from the metallated phosphine ligand in 1.

LigandPhoto assistedOrganic Chemistrychemistry.chemical_elementCrystal structureNuclear magnetic resonance spectroscopyBiochemistryPalladium compoundInorganic Chemistrychemistry.chemical_compoundCrystallographychemistryMaterials ChemistryChelationPhysical and Theoretical ChemistryPhosphinePalladiumJournal of Organometallic Chemistry
researchProduct

Principe de précaution et assistance médicale à la procréation : l'ICSI

2004

International audience

LimiteProcréation médicalement assistée[SHS.DROIT]Humanities and Social Sciences/Law[SHS.DROIT] Humanities and Social Sciences/LawProtection maternelle et infantileSANTE PUBLIQUEComputingMilieux_MISCELLANEOUSTechniques diverses
researchProduct

The minimal cost maximum matching of a graph (supplementary remarks)

1971

In addition to the preceding paper, it will be shown that (1) the matching problem is closely related to the linear assignment problem and how (2) this property can be taken advantage of for solving the matching problem.

Linear bottleneck assignment problemMathematical optimizationProperty (philosophy)Matching (graph theory)General Mathematics3-dimensional matchingGraph (abstract data type)Management Science and Operations ResearchAssignment problemSoftwareGeneralized assignment problemWeapon target assignment problemMathematicsUnternehmensforschung Operations Research - Recherche Opérationnelle
researchProduct

"Del qual tenim loch": Leonor de Sicilia y el origen de la lugartenencia femenina en la Corona de Aragón.

2017

Durante la Baja Edad Media algunas reinas consortes de la Corona de Aragón ejercieron la Lugartenencia real, un cargo gubernamental por el cual ocupaban la posición propia de su marido, convirtiéndose en su alter ego. En el presente artículo pretendemos esclarecer los detalles de la primera Lugartenencia ejercida por una reina en la Corona de Aragón, dilucidar los motivos de su elección y la importancia que tendría para los posteriores monarcas. During the Late Middle Ages some queens consort of the Crown of Aragon were designated as lieutenants. Lieutenancy was a governmental office in which the king delegated all his power during a period of absence. In the present article we intend to cl…

LugartenenciaReinamedia_common.quotation_subjectLieutenancyArtCorona de AragónQueenship:9 - Geografía e historia::94 - Historia por países [CDU]Crown of AragonMedical TerminologyReginalidadde Sicilia LeonorSicily Eleanor ofQueenHumanitiesMedical Assisting and Transcriptionmedia_common
researchProduct

Prevalence of pathogenic copy number variants among children conceived by donor oocyte.

2021

AbstractDevelopment of assisted reproductive technologies to address infertility has favored the birth of many children in the last years. The majority of children born with these treatments are healthy, but some concerns remain on the safety of these medical procedures. We have retrospectively analyzed both the fertilization method and the microarray results in all those children born between 2010 and 2019 with multiple congenital anomalies, developmental delay and/or autistic spectrum disorder (n = 486) referred for array study in our center. This analysis showed a significant excess of pathogenic copy number variants among those patients conceived after in vitro fertilization with donor …

Male0301 basic medicineInfertilityDNA Copy Number VariationsReproductive Techniques AssistedMicroarraymedicine.medical_treatmentScienceDiseasesPrenatal diagnosisFertilization in VitroReproductive technologyBioinformaticsPolymorphism Single NucleotideRisk AssessmentArticle03 medical and health sciences0302 clinical medicineHuman fertilizationGeneticsPrevalenceHumansMedicineGenetic Predisposition to DiseaseCopy-number variationChild030219 obstetrics & reproductive medicineMultidisciplinaryIn vitro fertilisationMolecular medicinebusiness.industryQROocytemedicine.diseasePatologia030104 developmental biologymedicine.anatomical_structureRisk factorsChromosomes Human Pair 2KaryotypingOocytesMedicineFemalebusinessGenètica
researchProduct

SARS-CoV-2 vaccination modelling for safe surgery to save lives: data from an international prospective cohort study

2021

Abstract Background Preoperative SARS-CoV-2 vaccination could support safer elective surgery. Vaccine numbers are limited so this study aimed to inform their prioritization by modelling. Methods The primary outcome was the number needed to vaccinate (NNV) to prevent one COVID-19-related death in 1 year. NNVs were based on postoperative SARS-CoV-2 rates and mortality in an international cohort study (surgical patients), and community SARS-CoV-2 incidence and case fatality data (general population). NNV estimates were stratified by age (18–49, 50–69, 70 or more years) and type of surgery. Best- and worst-case scenarios were used to describe uncertainty. Results NNVs were more favourable in su…

MaleCOVID-19 Vaccinesafe surgery; vaccination modelling; COVID-19Vascular damage Radboud Institute for Health Sciences [Radboudumc 16]MULTICENTERComorbidity030230 surgery0302 clinical medicinephase 3 clinical trial (topic)Case fatality rateProspective StudiesSARS-CoV-2 Vaccination Safe surgeryCOVID-19/epidemiologySARS-CoV-2 ; vaccination ; safe surgeryeducation.field_of_studycase fatality rateVaccinationVaccinationAdolescent; Adult; Aged; COVID-19; COVID-19 Vaccines; Comorbidity; Elective Surgical Procedures; Female; Humans; Male; Middle Aged; Postoperative Complications; Preoperative Period; Prospective Studies; SARS-CoV-2; Vaccination; Young Adulthealth care policyElective Surgical Procedures030220 oncology & carcinogenesisvaccination modellingPreoperative PeriodCOVID-19; SARS-CoV-2; cancer; vaccination; outcome; mortality; infection; modellingCohort studyprospective studyHumanmedicine.medical_specialtyArticle03 medical and health sciencesSARS-CoV-2 vaccinationSDG 3 - Good Health and Well-beingCOVID-19 Vaccines/pharmacologyHumansVaccination/methodsElective surgeryeducationAgedScience & TechnologyElective Surgical Procedureadult; aged; Article; cancer grading; cancer surgery; case fatality rate; computer assisted tomography; elective surgery; female; follow up; health care policy; human; incidence; infection rate; infection risk; major clinical study; male; middle aged; mortality; outcome assessment; phase 3 clinical trial (topic); preoperative care; prospective study; sensitivity analysis; seroprevalence; Severe acute respiratory syndrome coronavirus 2; vaccination; young adult; COVID-19; COVID-19 Vaccines; Comorbidity; Elective Surgical Procedures; Postoperative Complications; Preoperative Period; SARS-CoV-2; Vaccination; surgery.Cura preoperatòriamajor clinical studymortalityinfectionProspective StudieincidenceSurgeryHuman medicinePostoperative Complication610 Medizin und GesundheitAcademicSubjects/MED00910Settore MED/18 - CHIRURGIA GENERALESettore MED/29 - CHIRURGIA MAXILLOFACCIALEcomputer assisted tomographyESTUDOS PROSPECTIVOSsurgerysafe surgeryPostoperative Complicationssensitivity analysisSevere acute respiratory syndrome coronavirus 2preoperative careVacunacióProspective cohort studyseroprevalenceIncidence (epidemiology)covidElective Surgical Procedures/methodsMiddle Agedcancer gradingCOVID vaccinationoutcome/dk/atira/pure/sustainabledevelopmentgoals/good_health_and_well_beingSARS-CoV-2; vaccination; surgeryOriginal ArticleFemalecancer surgeryAcademicSubjects/MED00010Life Sciences & BiomedicineAdultCOVID-19 VaccinesAdolescentinternational prospective cohort studyPostoperative Complications/prevention & controlPopulationinfection rateSARS-CoV-2/immunologyNOmodellingYoung Adultmedicinefollow upcancerddc:610infection riskoutcome assessmentLS7_4business.industrySARS-CoV-2Number needed to vaccinatePreoperative careCOVID-193126 Surgery anesthesiology intensive care radiologySettore MED/18Reconstructive and regenerative medicine Radboud Institute for Health Sciences [Radboudumc 10]elective surgeryEmergency medicinebusiness[SDV.MHEP]Life Sciences [q-bio]/Human health and pathologyThe British Journal of Surgery
researchProduct

Modeling Right Ventricle Failure After Continuous Flow Left Ventricular Assist Device: A Biventricular Finite-Element and Lumped-Parameter Analysis

2017

The risk of right ventricle (RV) failure remains a major contraindication for continuous-flow left ventricular assist device (CF-LVAD) implantation in patients with heart failure. It is therefore critical to identify the patients who will benefit from early intervention to avoid adverse outcomes. We sought to advance the computational modeling description of the mechanisms underlying RV failure in LVAD-supported patients. RV failure was studied by computational modeling of hemodynamic and cardiac mechanics using lumped-parameter and biventricular finite element (FE) analysis. Findings were validated by comparison of bi-dimensional speckle-tracking echocardiographic strain assessment of the …

MaleCardiac CatheterizationCardiac outputVentricular Dysfunction Rightmedicine.medical_treatmentHemodynamicsSpeckle tracking echocardiography02 engineering and technology030204 cardiovascular system & hematologySeverity of Illness IndexRight ventricular failure Left ventricular assist device Speckle-tracking echocardiography Lumped-parameter Finite-element analysis.Ventricular Function LeftVentricular Dysfunction Left0302 clinical medicineRisk FactorsMedicineModels CardiovascularMiddle AgedTreatment Outcomemedicine.anatomical_structureEchocardiographyCardiologyFemaleCardiology and Cardiovascular MedicineAdultmedicine.medical_specialtyFinite Element Analysis0206 medical engineeringBiomedical EngineeringProsthesis DesignProsthesis Implantation03 medical and health sciencesInternal medicineSettore ING-IND/12 - Misure Meccaniche E TermicheHumansComputer SimulationInterventricular septumContraindicationRetrospective StudiesHeart Failurebusiness.industryHemodynamicsmedicine.disease020601 biomedical engineeringVentricleVentricular assist deviceHeart failureVentricular Function RightHeart-Assist DevicesbusinessCardiovascular Engineering and Technology
researchProduct

Health Assets, Vocation and Zest for Healthcare Work. A Salutogenic Approach to Active Coping among Certified Nursing Assistant Students

2020

People&rsquo

MaleCoping (psychology)Health Toxicology and MutagenesisPopulationnurselcsh:MedicineInterpersonal communicationArticleactive coping*certified nurse assistantcertified nurse assistant03 medical and health sciences0302 clinical medicineNursingNursing AssistantsAdaptation PsychologicalHealth careHumans030212 general & internal medicineOccupationsStudentsasset-based approachNursing Assistanteducation*active copingeducation.field_of_study030505 public healthZestbusiness.industry*health assets model*vocationlcsh:Rhealth assets modelPublic Health Environmental and Occupational Healthsalutogenic model of health*salutogenic model of healthHealth promotionSpainVocational educationvocationFemale*asset-based approach*nurse0305 other medical sciencePsychologybusinessStress PsychologicalInternational Journal of Environmental Research and Public Health
researchProduct

Physical activity when riding an electric assisted bicycle

2017

Background: The objectives of the present study were to compare time spent cycling, exercise intensity, and time spent in moderate- (MPA) and vigorous intensity physical activity (VPA) when cycling on an E-bike and a conventional bicycle on two “cycling-to-work” routes with differences in topography, defined as a hilly and a flat route. Methods: Eight adults (23–54 years, two women) cycled outdoors on a conventional bicycle and an E-bike, on a flat (8.2 km) and a hilly (7.1 km) route, resulting in 32 journeys. Duration, elevation, and oxygen consumption were recorded using a portable oxygen analyser with GPS. A maximal cardiorespiratory fitness test was performed on a cycle ergometer. Resti…

MaleElectrically assisted bicycleMedicine (miscellaneous)Poison controlTransportation0302 clinical medicineElectricitylcsh:RC620-627Nutrition and Dieteticslcsh:Public aspects of medicine05 social sciencesVO2 maxMiddle Agedlcsh:Nutritional diseases. Deficiency diseasesCardiorespiratory FitnessFemaleCyclingAdultmedicine.medical_specialtyIntensityeducationPhysical ExertionPhysical activityPhysical Therapy Sports Therapy and Rehabilitation03 medical and health sciencesYoung AdultAnimal scienceOxygen Consumption0502 economics and businessPedalecsmedicineShort PaperHumansExercise050210 logistics & transportationCommutingCardiorespiratory fitnesslcsh:RA1-1270Calorimetry Indirect030229 sport sciencesIntensity (physics)BicyclingOxygen uptakeBasal metabolic ratePhysical therapyExercise intensityExercise TestEnvironmental scienceBasal Metabolismhuman activities
researchProduct

17β-Hydroxysteroid dehydrogenase-3 deficiency: From pregnancy to adolescence

2009

OBJECTIVE: Aim of this study is to report on basal clinical phenotype and follow up after diagnosis, of patients with 17beta-hydroxysteroid-dehydrogenase type 3 (17beta-HSD3) deficiency in Italy. SETTING: Pediatric Endocrine Departments, University Hospitals. PATIENTS: The cases of 5 Italian subjects affected by 17beta-HSD3 deficiency are presented in this study. INTERVENTIONS: Laboratory and genetic assessment. Gonadectomy and female sex assignment (4 patients) or GnRH analog therapy to regress puberty and gender identity disorder (1 patient). RESULTS: Presentation lasted from pregnancy (pre-natal diagnosis of a 46,XY fetus with female external genitalia) to infancy (inguinal hernia contai…

MaleGender Identity DisorderPediatricsmedicine.medical_specialty17-Hydroxysteroid DehydrogenasesEndocrinology Diabetes and MetabolismSex assignmentPrenatal diagnosisGene mutationBiologyClitoromegalyAdolescence pregnancy 17beta-Hydroxysteroid dehydrogenase-3 deficiencySettore MED/38 - Pediatria Generale E SpecialisticaEndocrinologyPregnancyPrenatal DiagnosismedicineHumansDisorders of sex developmentDISORDERS OF SEX DEVELOPMENTTestosterone17-BETA-HYDROXYSTEROID DEHYDROGENASE TYPE 3 GENEGynecologyPregnancyPubertymedicine.diseaseFemaleMALE/FEMALE SEX REVERSALTESTOSTERONE/D4-ANDROSTENEDIONE RATIO17-BETA-HYDROXYSTEROID DEHYDROGENASE TYPE 3 DEFICIENCYmedicine.symptomJournal of Endocrinological Investigation
researchProduct