Search results for " chloride"
showing 10 items of 880 documents
Rotational spectrum of silyl chloride: hyperfine structure and equilibrium geometry
2012
The Lamb-dip technique was employed to record the rotational spectra of two isotopic species of silyl chloride, namely (28)SiH3Cl and (29)SiH3Cl, in order to investigate their hyperfine structure. High-accuracy quantum-chemical computations were employed to predict the hyperfine parameters involved and to support the experimental investigation. Analysis of the experimental spectra led to an improvement in the accuracy of the known spectroscopic constants as well as allowed us to determine additional spectroscopic parameters for the first time. Furthermore, the equilibrium structure of silyl chloride was reinvestigated using both theoretical and experimental data. The best theoretical and se…
Glial Chloride Homeostasis Under Transient Ischemic Stress
2021
High water permeabilities permit rapid adjustments of glial volume upon changes in external and internal osmolarity, and pathologically altered intracellular chloride concentrations ([Cl–]int) and glial cell swelling are often assumed to represent early events in ischemia, infections, or traumatic brain injury. Experimental data for glial [Cl–]int are lacking for most brain regions, under normal as well as under pathological conditions. We measured [Cl–]int in hippocampal and neocortical astrocytes and in hippocampal radial glia-like (RGL) cells in acute murine brain slices using fluorescence lifetime imaging microscopy with the chloride-sensitive dye MQAE at room temperature. We observed s…
Modular Small Diameter Vascular Grafts with Bioactive Functionalities.
2015
We report the fabrication of a novel type of artificial small diameter blood vessels, termed biomimetic tissue-engineered blood vessels (bTEBV), with a modular composition. They are composed of a hydrogel scaffold consisting of two negatively charged natural polymers, alginate and a modified chitosan, N,O-carboxymethyl chitosan (N,O-CMC). Into this biologically inert scaffold two biofunctionally active biopolymers are embedded, inorganic polyphosphate (polyP) and silica, as well as gelatin which exposes the cell recognition signal, Arg-Gly-Asp (RGD). These materials can be hardened by exposure to Ca(2+) through formation of Ca(2+) bridges between the polyanions, alginate, N,O-CMC, and polyP…
Evaluation of the enhanced resistance of Ogataea (Hansenula) polymorpha to benzalkonium chloride as a resource for bioremediation technologies
2019
Abstract Benzalkonium chloride (BAC) is highly abundant in wastewaters due to its wide application in household and industrial products. The aim of this research was to compare the resistance of two genetically related strains, Ogataea polymorpha (wild type) and O. polymorpha cat8Δ (recombinant strain), to enhanced concentrations of BAC (≥ 100 mg/L) in terms of its appearance in wastewaters. Inhibition of the respiration activity of wt and cat8Δ by 100 mg/L and 300 mg/L BAC in a xylose-containing broth (4 g/L xylose) was dependent on the carbon source used for obtaining the yeast biomass through ethanol fermentation. The respiration activity of wt in a liquid broth was inhibited by BAC, whi…
The influence of backslopping on lactic acid bacteria diversity in tarhana fermentation
2020
Tarhana is produced at batch systems in which the microbiota has changed accordingly to the microbial load from ingredients. In order to stabilize the microbiota, the effects of backslopping carried out under different temperature regimes (25 and 30 °C), pH (3.70 and 4.00) and inoculation rates (5, 10 and 15%) on lactic acid bacteria (LAB) diversity were determined in tarhana dough. LAB and Total Aerobic Mesophilic Bacteria (TAMB) numbers increased in all tarhana dough samples subjected to backslopping. Temperature and pH significantly affected the microbiological diversity of tarhana whereas the different inoculation rates did not. Tarhana dough showed complex tarhana microbiota following …
Plume composition and volatile flux of Nyamulagira volcano, Democratic Republic of Congo, during birth and evolution of the lava lake, 2014-2015
2017
Very little is known about the volatile element makeup of the gaseous emissions of Nyamulagira volcano. This paper tries to fill this gap by reporting the first gas composition measurements of Nyamulagira’s volcanic plume since the onset of its lava lake activity at the end of 2014. Two field surveys were carried out on 1 November 2014, and 13–15 October 2015. We applied a broad toolbox of volcanic gas composition measurement techniques in order to geochemically characterize Nyamulagira’s plume. Nyamulagira is a significant emitter of SO2, and our measurements confirm this, as we recorded SO2 emissions of up to ~ 14 kt/d during the studied period. In contrast to neighbouring Nyiragongo volc…
Synthesis, characterization and conformational analysis of chloro-bis(glycylglycinate)germanium(IV) chloride
2011
Chloro-bis(glycylglycinate)germanium(IV) chloride, [Cl(glygly)2Ge]Cl, was synthesized and characterized in the solid state by elemental analysis, thermogravimetry and infrared spectroscopy. Solution studies were also performed by 1H-NMR and 13C-NMR in dimethylsulfoxide (DMSO-d6) and by electric conductivity. The structural determination of the complex and the interpretation of the spectroscopic results were performed by employing an integrated computational approach, based on a systematic conformational search analysis on the [Cl(glygly)2Ge]+ ion performed by the Systematic Conformational Search Algorithm (SCSA) code, working at the hybrid B3LYP/6-31G(d,p) level. The combination of experime…
Stability and disassembly properties of human naïve Hsp60 and bacterial GroEL chaperonins.
2015
Human Hsp60 chaperonin and its bacterial homolog GroEL, in association with the corresponding co-chaperonins Hsp10 and GroES, constitute important chaperone systems promoting the proper folding of several mitochondrial proteins. Hsp60 is also currently described as a ubiquitous molecule with multiple roles both in health conditions and in several diseases. Naïve Hsp60 bearing the mitochondrial import signal has been recently demonstrated to present different oligomeric organizations with respect to GroEL, suggesting new possible physiological functions. Here we present a combined investigation with circular dichroism and small-angle X-ray scattering of structure, self-organization, and sta…
CCDC 954904: Experimental Crystal Structure Determination
2013
Related Article: Huayan Yang , Yu Wang , Jing Lei , Lei Shi , Xiaohu Wu , Ville Mäkinen , Shuichao Lin , Zichao Tang , Jian He , Hannu Häkkinen , Lansun Zheng , and Nanfeng Zheng|2013|J.Am.Chem.Soc.|135|9568|doi:10.1021/ja402249s
CCDC 2060888: Experimental Crystal Structure Determination
2021
Related Article: Lucija Ptiček, Lucija Hok, Petra Grbčić, Filip Topić, Mario Cetina, Kari Rissanen, Sandra Kraljević Pavelić, Robert Vianello, Livio Racané|2021|Org.Biomol.Chem.|19|2784|doi:10.1039/D1OB00235J