Search results for " complex"
showing 10 items of 3391 documents
Varieties Generated by Certain Models of Reversible Finite Automata
2006
Reversible finite automata with halting states (RFA) were first considered by Ambainis and Freivalds to facilitate the research of Kondacs-Watrous quantum finite automata. In this paper we consider some of the algebraic properties of RFA, namely the varieties these automata generate. Consequently, we obtain a characterization of the boolean closure of the classes of languages recognized by these models.
Synthesis, structure and photophysical properties of a highly luminescent terpyridine-diphenylacetylene hybrid fluorophore and its metal complexes
2014
A new fluorescent terpyridyl-diphenylacetylene hybrid fluorophore 4'-[4-{(4-methoxyphenyl)ethynyl}phenyl]-2,2':6',2''-terpyridine, L, was synthesized via Sonogashira cross-coupling of 4'-(4-bromophenyl)-2,2':6',2''-terpyridine and 4-ethynylanisole in the presence of Pd(PPh3)4/CuI as a catalyst. The solid state structure of L shows a trans arrangement of pyridine nitrogen atoms along the interannular bond in the terpyridine domain. Five transition metal complexes of L, {[FeL2](CF3SO3)2 (1), [ZnL2](ClO4)2 (2), [CdL2](ClO4)2 (3), [RuL2](PF6)2 (4), and PtMe3IL (5)}, have also been synthesized and characterized by spectroscopic methods and single crystal X-ray analysis. The X-ray crystal structu…
Synthesis, structure and photophysical properties of a highly luminescent terpyridine-diphenylacetylene hybrid fluorophore and its metal complexes
2015
A new fluorescent terpyridyl-diphenylacetylene hybrid fluorophore 4′-[4-{(4-methoxyphenyl)ethynyl}phenyl]-2,2′:6′,2′′-terpyridine, L, was synthesized via Sonogashira cross-coupling of 4′-(4-bromophenyl)-2,2′:6′,2′′-terpyridine and 4-ethynylanisole in the presence of Pd(PPh3)4/CuI as a catalyst. The solid state structure of L shows a trans arrangement of pyridine nitrogen atoms along the interannular bond in the terpyridine domain. Five transition metal complexes of L, {[FeL2](CF3SO3)2 (1), [ZnL2](ClO4)2 (2), [CdL2](ClO4)2 (3), [RuL2](PF6)2 (4), and PtMe3IL (5)}, have also been synthesized and characterized by spectroscopic methods and single crystal X-ray analysis. The X-ray crystal structu…
Adding Transitivity and Counting to the Fluted Fragment
2023
We study the impact of adding both counting quantifiers and a single transitive relation to the fluted fragment - a fragment of first-order logic originating in the work of W.V.O. Quine. The resulting formalism can be viewed as a multi-variable, non-guarded extension of certain systems of description logic featuring number restrictions and transitive roles, but lacking role-inverses. We establish the finite model property for our logic, and show that the satisfiability problem for its k-variable sub-fragment is in (k+1)-NExpTime. We also derive ExpSpace-hardness of the satisfiability problem for the two-variable, fluted fragment with one transitive relation (but without counting quantifiers…
Molecular phylogeny of the spider family Sparassidae with focus on the genus Eusparassus and notes on the RTA-clade and ‘Laterigradae’
2013
The phylogeny of the spider family Sparassidae is comprehensively investigated using four molecular markers (mitochondrial COI and 16S; nuclear H3 and 28S). Sparassidae was recovered as monophyletic and as most basal group within the RTA-clade. The higher-level clade Dionycha was not but monophyly of RTA-clade was supported. No affiliation of Sparassidae to other members of the 'Laterigradae' (Philodromidae, Selenopidae and Thomisidae) was observed, and the crab-like posture of this group assumed a result of convergent evolution. Only Philodromidae and Selenopidae were found members of a supported clade, but together with Salticidae and Corinnidae, while Thomisidae was nested within the hig…
Membrane Protein Complexes: Structure and Function
2018
This edited book contains a compilation of 14 advanced academic chapters dealing with the structure and function of membrane protein complexes. This rapidly advancing important field of study closely parallels those on soluble protein complexes, and viral protein and nucleoprotein complexes.Diverse topics are included in this book, ranging from membrane–bound enzymes to ion channels, proton pumps and photosystems. Data from X-ray crystallography, cryo-electron microscopy and other biophysical and biochemical techniques are presented throughout the book. There is extensive use of colour figures of protein structures. Throughout the book structure and function are closely correlated.The two e…
The Christian Funerary Areas
2017
Il contributo costituisce il primo studio unitario sulla catacomba e sulle aree funerarie cristiane sub-divo delle Regiones III, IV e V di Sabratha (Libia). After the earthquake of 365 A.D., the gradual process of Christianisation that involved the territories of North Africa left many signs in the Regio Tripolitania. Sabratha became a diocesan centre during the 4th and 5th centuries, and the Paleochristian catacomb, excavated after the Peace of the Church in year 313, is the first attestation of the new faith, togerther with the open-air funerary areas distributed between the episcopal complex of the Regio III, the Oceanus Thermae, the Theatre in the Regio IV and the Temple of Hercules.
Sobolev homeomorphic extensions onto John domains
2020
Given the planar unit disk as the source and a Jordan domain as the target, we study the problem of extending a given boundary homeomorphism as a Sobolev homeomorphism. For general targets, this Sobolev variant of the classical Jordan-Schoenflies theorem may admit no solution - it is possible to have a boundary homeomorphism which admits a continuous $W^{1,2}$-extension but not even a homeomorphic $W^{1,1}$-extension. We prove that if the target is assumed to be a John disk, then any boundary homeomorphism from the unit circle admits a Sobolev homeomorphic extension for all exponents $p<2$. John disks, being one sided quasidisks, are of fundamental importance in Geometric Function Theory.
Arsenite-induced aneuploidy following short and long-term exposure in mammalian cells
2009
We studied the long-term progression of chromosomal instability in V79 cells treated acutely with arsenite (10mM, 24 hr) followed by growth in arsenic-free medium for 120 cell generations. Indirect immunostaining using anti-ß-tubulin antibody showed severe alterations in spindle morphology after only 6 h treatment and cytogenetic investigations carried out at the end of treatment revealed that the percentage of cells with 21 chromosomes (modal number of the cell line) decreased, making way for aneuploid cells. The acquired instability remained and propagated within the cell population. Moreover, we treated V79-derived G12 cells with sub-lethal doses (0.1-1.0 μM) of arsenite for 10 days foll…
Communication between iron(II) building blocks in cooperative spin transition phenomena
2003
[EN] In the present article we discuss the cooperative nature of the spin crossover phenomenon in iron(II) complexes, providing a perspective of the state of the art in this area. The first aspect we discuss is the role of the intermolecular interactions, more precisely the ¿-interactions, in mononuclear complexes. We show that by playing with the nature of the ligands, aliphatic, aromatic, or extended aromatic, it is possible to create stronger cohesive forces and receive a more cooperative response from the compound. In the next step the singular family of bipyrimidine-bridged iron(II) dinuclear compounds is presented as the simplest example of polynuclear spin crossover complexes exhibit…