Search results for " composition"

2017

Abstract. Size-resolved and vertical profile measurements of single particle chemical composition (sampling altitude range 50–3000 m) were conducted in July 2014 in the Canadian high Arctic during an aircraft-based measurement campaign (NETCARE 2014). We deployed the single particle laser ablation aerosol mass spectrometer ALABAMA (vacuum aerodynamic diameter range approximately 200–1000 nm) to identify different particle types and their mixing states. On the basis of the single particle analysis, we found that a significant fraction (23 %) of all analyzed particles (in total: 7412) contained trimethylamine (TMA). Two main pieces of evidence suggest that these TMA-containing particles origi…

Intense magmatic degassing through the lake of Copahue volcano, 2013–2014

2015

Here we report on the first assessment of volatile fluxes from the hyperacid crater lake hosted within the summit crater of Copahue, a very active volcano on the Argentina-Chile border. Our observations were performed using a variety of in situ and remote sensing techniques during field campaigns in March 2013, when the crater hosted an active fumarole field, and in March 2014, when an acidic volcanic lake covered the fumarole field. In the latter campaign, we found that 566 to 1373 t d -1 of SO 2 were being emitted from the lake in a plume that appeared largely invisible. This, combined with our derived bulk plume composition, was converted into flux of other volcanic species (H 2 O ~ 1098…

Aviation Contrail Cirrus and Radiative Forcing Over Europe During 6 Months of COVID‐19

2021

Abstract The COVID‐19 pandemic led to a 72% reduction of air traffic over Europe in March–August 2020 compared to 2019. Modeled contrail cover declined similarly, and computed mean instantaneous radiative contrail forcing dropped regionally by up to 0.7 W m−2. Here, model predictions of cirrus optical thickness and the top‐of‐atmosphere outgoing longwave and reflected shortwave irradiances are tested by comparison to Meteosat‐SEVIRI‐derived data. The agreement between observations and modeled data is slightly better when modeled contrail cirrus contributions are included. The spatial distributions and diurnal cycles of the differences in these data between 2019 and 2020 are partially caused…

Clouds and aerosols in Puerto Rico - a new evaluation

2007

The influence of aerosols, both natural and anthropogenic, remains a major area of uncertainty when predicting the properties and behaviour of clouds and their influence on climate. In an attempt to better understand warm cloud formation in a tropical marine environment, a period of intensive measurements took place in December 2004 in Puerto Rico, using some of the latest developments in online instrumentation such as aerosol mass spectrometers, cloud condensation nuclei counters and a hygroscopicity tandem differential mobility analyser. Simultaneous online measurements of aerosol size distributions, composition, hygroscopicity and optical properties were made near the lighthouse of Cape …

Single-particle characterization of ice-nucleating particles and ice particle residuals sampled by three different techniques

2015

Abstract. In the present work, three different techniques to separate ice-nucleating particles (INPs) as well as ice particle residuals (IPRs) from non-ice-active particles are compared. The Ice Selective Inlet (ISI) and the Ice Counterflow Virtual Impactor (Ice-CVI) sample ice particles from mixed-phase clouds and allow after evaporation in the instrument for the analysis of the residuals. The Fast Ice Nucleus Chamber (FINCH) coupled with the Ice Nuclei Pumped Counterflow Virtual Impactor (IN-PCVI) provides ice-activating conditions to aerosol particles and extracts the activated particles for analysis. The instruments were run during a joint field campaign which took place in January and …

Sensitivity of tropospheric chemical composition to halogen-radical chemistry using a fully coupled size-resolved multiphase chemistry–global climate…

2014

Observations and model calculations indicate that highly non-linear multiphase atmospheric processes involving inorganic Cl and Br significantly impact tropospheric chemistry and composition, aerosol evolution, and radiative transfer. The sensitivity of global atmospheric chemistry to the production of marine aerosol and the associated activation and cycling of inorganic Cl and Br was investigated using a size-resolved multiphase coupled chemistry–global climate model (National Center for Atmospheric Research's Community Atmosphere Model (CAM) v3.6.33). Simulated results revealed strong meridional and vertical gradients in Cl and Br species. They also point to possible physicochemical mecha…

A Theoretical Study of the Wet Removal of Atmospheric Pollutants. Part V: The Uptake, Redistribution, and Deposition of (NM4)4SO4by a Convective Clou…

1995

Abstract The effects of an ice phase on the wet deposition of aerosol particles was studied by means of the authors’ 2D cloud dynamics model with spectral microphysics applied to the Cooperative Convective Precipitation Experiment in Miles City, Montana, on 19 July 1981. The cloud macrostructure as well as the cloud microstructure simulated by the model was found to agree well with observations. Although no on-site observations were available with respect to the chemical composition of the cloud and rain water, the values predicted by the model compared well with typical nearby measurements. The following conclusions can be derived from the model computations: (1) In confirmation of the aut…

Urban organic aerosol composition in eastern China differs from north to south:Molecular insight from a liquid chromatography-mass spectrometry (Orbi…

2021

Air pollution by particulate matter in China affects human health, the ecosystem and the climate. However, the chemical composition of particulate aerosol, especially of the organic fraction, is still not well understood. In this study, particulate aerosol samples with a diameter of ≤2.5 µm (PM2.5) were collected in January 2014 in three cities located in northeast, east and southeast China, namely Changchun, Shanghai and Guangzhou. Organic aerosol (OA) in the PM2.5 samples was analyzed by an ultrahigh-performance liquid chromatograph (UHPLC) coupled to a high-resolution Orbitrap mass spectrometer in both negative mode (ESI-) and positive mode electrospray ionization (ESI+). After non-targe…

Evidence for montmorillonite or its compositional equivalent in Columbia Hills, Mars

2007

During its exploration of the Columbia Hills, the Mars Exploration Rover ‘‘Spirit’’ encountered several similar samples that are distinctly different from Martian meteorites and known Gusev crater soils, rocks, and sediments. Occurring in a variety of contexts and locations, these ‘‘Independence class’’ samples are rough-textured, iron-poor (equivalent FeO 4 wt%), have high Al/Si ratios, and often contain unexpectedly high concentrations of one or more minor or trace elements (including Cr, Ni, Cu, Sr, and Y). Apart from accessory minerals, the major component common to these samples has a compositional profile of major and minor elements whic…

Leachate analyses of volcanic ashes from Stromboli volcano: A proxy for the volcanic gas plume composition?

2011

[1] Many volcanoes show a change in chemical composition of the gas phase prior to periods of eruptive activity. Fine-grained tephra erupted from active vents and transported through volcanic plumes can adsorb, and therefore rapidly scavenge, volatile elements such as sulfur, halogens, and metal species in the form of soluble salts adhering to ash surfaces. Analysis of such water-soluble surface materials is a suitable supplement for remote monitoring of volcanic gases at inaccessible volcanoes. In this work, ash samples of the 2004 to 2009 eruptive activity of Stromboli volcano were sampled, leached, and analyzed for major and trace elements. Data analysis and interpretation was focused on…