Search results for " conductor"
showing 10 items of 169 documents
Multipactor Effect Characterization of Dielectric Materials for Space Applications
2018
[EN] The objective of this paper is to advance the state of the art in the characterization of the multipactor effect in dielectric materials. The materials studied are the most commonly used dielectrics in space applications, namely, Alumina, Rexolite, Rogers RT5870, Rohacell, Teflon, and Ultem 1000. In this paper, a new family of coaxial waveguide components, covering the L- and S-bands, with a wideband, low-pass response has been designed, and six different prototypes have been specifically optimized and manufactured. The six prototypes have then been used to simulate and measure the multipactor breakdown susceptibility charts for the six dielectric materials investigated. Finally, the s…
Mapping of local conductivity variations on fragile nanopillar arrays by scanning conductive torsion mode microscopy.
2010
A gentle method that combines torsion mode topography imaging with conductive scanning force microscopy is presented. By applying an electrical bias voltage between tip and sample surface, changes in the local sample conductivity can be mapped. The topography and local conductivity variations on fragile free-standing nanopillar arrays were investigated. These samples were fabricated by an anodized aluminum oxide template process using a thermally cross-linked triphenylamine-derivate semicondcutor. The nanoscale characterization method is shown to be nondestructive. Individual nanopillars were clearly resolved in topography and current images that were recorded simultaneously. Local current−…
Recent advances in polyoxometalate-containing molecular conductors
2005
The recent advances in crystalline conducting molecular materials based on polyoxometalates (POMs) and organic donors of the tetrathiafulvalene (TTF) family or perylene are discussed. We emphasise the wide diversity of POM structural types and the variety of packing architectures for the organic molecules that can be induced by these inorganic anions. Besides structural effects, we show that these hybrids can have interesting electric and/or magnetic properties. Thus, in the last years the common belief that this type of radical salts containing such big and highly charged anions could only exhibit poor conducting properties has been refuted by the production of new materials exhibiting hig…
Molecule-based ferromagnetic conductors: Strategy and design
2008
The design and study of hybrid crystalline solids in the search for multifunctional materials is one of the most appealing possibilities where molecule-based materials offer striking advantages: from the combination of molecular building blocks with the desired tailor-made chemical and physical properties. In this review we will cover all aspects of the so-called molecular ferromagnetic conductors, built from combination in a single compound of organic cationic radicals, able to give rise to conducting architectures, with polymeric anionic metal complexes, able to give rise to ferromagnetism. The relevant successes and drawbacks of this approach will be highlighted and discussed in detail.
Theoretical determination of the geometric and electronic structures of oligorylenes and poli(peri‐naphthalene)
1992
We present a theoretical investigation of the electronic structure of oligorylenes (from perylene to heptarylene, including also the naphthalene molecule) and their corresponding polymer poly(peri‐naphthalene) (PPN) using the nonempirical valence effective (VEH) method. The geometry of the unit cell used to generate the polymer is extrapolated from the PM3‐optimized molecular geometries of the longest oligorylenes. That geometry shows some bond alternation along the perimeter carbon chains and a bond length of ≊1.46 Å is calculated for the peri bonds connecting the naphthalene units. The VEH one‐electron energy level distributions calculated for oligorylenes are used to interpret the experi…
Electrode–Electrolyte Compatibility in Solid-Oxide Fuel Cells: Investigation of the LSM–LNC Interface with X-ray Microspectroscopy
2015
Ca:LaNbO4 (LNC) constitutes the last real breakthrough in high-temperature proton conductors, with better chemical and mechanical stability with respect to cerate and zirconate perovskites. However, the low amount of bivalent dopant that can be hosted in the LaNbO4 matrix poses a limit to the proton concentration in the electrolyte. Using synchrotron X-ray microspectroscopy, we investigated the compatibility of annealed LNC/LSM electrolyte/cathode bilayers for proton-conducting SOFCs. The element maps are complemented by microEXAFS and microXANES, giving information on the fate of different cations after diffusion. The X-ray microspectroscopy approach described here is applied for the first…
Stimulated 7^Li echo NMR spectroscopy of slow ionic motions in a solid electrolyte
2000
Abstract Lithium spin-alignment spectroscopy is presented as an NMR technique for studying slow translational motions in solid and solid-like ionic conductors. We employ phase cycling that allows to measure two-time translational correlation functions via the generation of a pure quadrupolar ordered state. Correlation functions of the crystalline electrolyte Li 3 Sc 2 (PO 4 ) 3 were recorded for times ranging from about 0.1 ms to more than 10 s, implying that translational diffusion coefficients smaller than 10 −20 m 2 /s become accessible.
Phase transitions in Ag-based solid electrolytes as detected by thermosonimetry
2001
Abstract Observations of the acoustic emission accompanying the solid–solid (polymorphic) phase changes in silver iodide and silver chalcogenides were performed. It has been found that the temperature dependencies of both the number of acoustic events and their counting rate, registered when heating the investigated materials, display distinct anomalies at the temperature corresponding to the polymorphic phase transition occurring in a given substance. The phase transition temperatures determined from the position of these anomalies agree well with the results of control DSC measurements, as well as with the literature data on the temperatures of the transition of investigated materials to …
Giant barocaloric effects over a wide temperature range in superionic conductor AgI
2017
Current interest in barocaloric effects has been stimulated by the discovery that these pressure-driven thermal changes can be giant near ferroic phase transitions in materials that display magnetic or electrical order. Here we demonstrate giant inverse barocaloric effects in the solid electrolyte AgI, near its superionic phase transition at ~420 K. Over a wide range of temperatures, hydrostatic pressure changes of 2.5 kbar yield large and reversible barocaloric effects, resulting in large values of refrigerant capacity. Moreover, the peak values of isothermal entropy change (60 J K−1 kg−1 or 0.34 J K−1 cm−3) and adiabatic temperature changes (18 K), which we identify for a starting tempera…
Spin-up instability of electromagnetically levitated spherical bodies
2000
Stability of a solid sphere in both uniform and linear alternating magnetic fields is considered with respect to virtual rotations. When the frequency of the alternating magnetic field exceeds a certain critical threshold depending on the configuration of the field, the sphere is found to spin up around a horizontal axis. The physical mechanism of this instability is the same as that of operation of a single-phase induction motor. Sufficiently small rotational disturbances can be completely suppressed by imposing an axial steady magnetic field of strength comparable to that of the alternating field. Nonlinear stability analysis shows that for sufficiently high frequencies, spin-up can be ca…