Search results for " conductor"

Modified Donnan phenomena in polyaniline with poly(vinyl sulphonate) chains

1993

We develop a physical model, based on the modified Donnan phenomena ideas introduced previously by the authors, to describe the acid doping of the conducting polymer polyaniline. The theory is motivated by the experimental work of Asturias et al. [Ber. Bunsenges. Phys. Chem. 95, 1381 (1991)]. Good agreement between theory and experiment is found.

Impedance spectroscopy characterization of functionalized alumina membranes

2005

Abstract Anodic alumina membranes have been impregnated with a protonic conductor either by immersion or by vacuum permeation of a saturated aqueous solution of CsHSO4 for different times. Synthetized salt, obtained through the reaction of cesium carbonate with sulphuric acid (in excess), contained a small quantity of Cs2SO4. Unmodified membranes consist of amorphous Al2O3 with a regular distribution of pores (average diameter: 200 nm) and are stable up to 850 °C. Long impregnation times caused partial dissolution of alumina, with formation of Al(HSO4)3 on the front surfaces as well as into pore walls. From the frequency dispersion of the impedance, the “macroscopic conductivity” of membran…

Polydithienothiophenes: Two new conjugated materials with narrow band gap

1997

Abstract The electrochemical polymerisation of dithieno[3,4-b:3',2'-d]thiophene and dithieno[3,4-b:2',3'-d]thiophene leads to conjugated materials with narrow band gap in which the p- and n-doping processes are possible in organic electrolytes. The spectroelectrochemical study of these polymers is reported.

Electrical conductive coordination polymers

2011

Coordination polymers are currently one of the hottest topics in Inorganic and Supramolecular Chemistry. This critical review summarizes the current state-of-the-art on electrical conductive coordination polymers (CPs), also named metal-organic frameworks (MOFs). The data were collected following two sort criteria of the CPs structure: dimensionality and bridging ligands (151 references).

1988

Conductive Directly Fused Poly(Porphyrin) Coatings by Oxidative Chemical Vapour Deposition - From Single- to Triple-Fused

2019

A Model for Assessing the Magnitude and Distribution of Sheath Currents in Medium and High-Voltage Cable Lines

2020

In this article, the authors discuss a simulation model to study the effect of cross-bonding of metallic sheaths, and/or nonmagnetic armors, of single-core medium- and high-voltage cables in the same circuit. In single-core cables, the resistive losses due to the induced circulating currents in cable sheaths or armors cause an increase of the cable temperature, which therefore reduces its ampacity. This is a serious issue affecting the distribution and transmission lines. In addition, the risk of electric shock due to induced voltages may be present if a person is in contact with the armor/sheath at its unbounded end. For these reasons, special bonding techniques of metal sheaths are employ…

The Importance of Electronic Dimensionality in Multiorbital Radical Conductors

2019

The exceptional performance of oxobenzene-bridged bis-1,2,3-dithiazolyls 6 as single-component neutral radical conductors arises from the presence of a low-lying π-lowest unoccupied molecular orbital, which reduces the potential barrier to charge transport and increases the kinetic stabilization energy of the metallic state. As part of ongoing efforts to modify the solid-state structures and transport properties of these so-called multiorbital materials, we report the preparation and characterization of the acetoxy, methoxy, and thiomethyl derivatives 6 (R = OAc, OMe, SMe). The crystal structures are based on ribbonlike arrays of radicals laced together by S···N′ and S···O′ secondary bondin…

Structural analysis, phase stability and electrochemical characterization of Nb doped BaCe0.9Y0.1O3−x electrolyte for IT-SOFCs

2012

Abstract To improve the chemical stability of high temperature proton conductors based on barium cerate, electrolyte powders doped with different amounts of niobium were synthesized by the citrate–nitrate auto-combustion method. Pure single phases of BaCe 0.9− x Nb x Y 0.1 O 3− x (BCYN, 0.03 ≤  x  ≤ 0.12) were obtained by thermal treatment at 1000 °C. Sintering at 1450 °C for 10 h produced dense pellets. X-ray absorption spectroscopy allowed to define the dopant ion insertion site and the co-dopant valency. Treatments in pure CO 2 atmosphere at 700 °C for 3 h and subsequent XRD analysis were carried out to probe the chemical stability of the produced electrolytes. The influence of the prese…

Detector's quantum backaction effects on a mesoscopic conductor and fluctuation-dissipation relation

2017

International audience; When measuring quantum mechanical properties of charge transport in mesoscopic conductors, backaction effects occur. We consider a measurement setup with an elementary quantum circuit, composed of an inductance and a capacitor, as detector of the current flowing in a nearby quantum point contact. A quantum Langevin equation for the detector variable including backaction effects is derived. Differences with the quantum Langevin equation obtained in linear response are pointed out. In this last case, a relation between fluctuations and dissipation is obtained, provided that an effective temperature of the quantum point contact is defined.