Search results for " controlled release"

showing 3 items of 13 documents

Single cigar-shaped nanopores functionalized with amphoteric amino acid chains: experimental and theoretical characterization.

2012

We present an experimental and theoretical characterization of single cigar-shaped nanopores with pH-responsive carboxylic acid and lysine chains functionalized on the pore surface. The nanopore characterization includes (i) optical images of the nanostructure obtained by FESEM; (ii) different chemical procedures for the nanopore preparation (etching time and functionalizations; pH and electrolyte concentration of the external solution) allowing externally tunable nanopore responses monitored by the current-voltage (I-V) curves; and (iii) transport simulations obtained with a multilayer nanopore model. We show that a single, approximately symmetric nanopore can be operated as a reconfigurab…

NanoporeRe-configurablePHAmino acid chainsEtching timeElectrical signalCarboxylic AcidsGeneral Physics and AstronomyFunctionalizationsElectrolytePore surfaceElectrochemistryFunctionalizedCarboxylic acidOptical imageNanoporesElectric conductivityI - V curveElectrochemistryGeneral Materials ScienceTheoretical modelRectifying behaviorsFundamental conceptsRectifying propertiesSurface propertyGeneral EngineeringHydrogen-Ion ConcentrationCigar-shaped nanoporeCharacterization (materials science)Data processingChemistryNanoporeAmino acidsIon channelTransport simulationIodineLogic functionsNanostructureMaterials scienceLogicSurface PropertiesCharacterizationNanotechnologyTunabilitiesArticleDrug controlled releaseElectrical resistivity and conductivityEtchingTransport processPH-responsiveCurrent voltage curveDiodeChemical proceduresCarboxylic acidsLysineElectric ConductivityModels TheoreticalGeometrical opticsNanostructuresAmphoteric amino acid chainsCurrent-voltage curvesExternal solutionsFISICA APLICADAElectrolyte concentrationACS nano
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Halloysite Nanotubes: Controlled Access and Release by Smart Gates

2017

© 2017 by the authors. Licensee MDPI, Basel, Switzerland. Hollow halloysite nanotubes have been used as nanocontainers for loading and for the triggered release of calcium hydroxide for paper preservation. A strategy for placing end-stoppers into the tubular nanocontainer is proposed and the sustained release from the cavity is reported. The incorporation of Ca(OH) 2 into the nanotube lumen, as demonstrated using transmission electron microscopy (TEM) imaging and Energy Dispersive X-ray (EDX) mapping, retards the carbonatation, delaying the reaction with CO 2 gas. This effect can be further controlled by placing the end-stoppers. The obtained material is tested for paper deacidification. We…

NanotubeMaterials scienceGeneral Chemical EngineeringCarbonation02 engineering and technologyengineering.material010402 general chemistry01 natural sciencesHalloysiteArticlelcsh:Chemistrychemistry.chemical_compoundControlled releaseGeneral Materials ScienceComposite materialCelluloseSettore CHIM/02 - Chimica FisicaNanocompositeNanocompositeCalcium hydroxideNanocontainerHalloysiteCellulose; Controlled release; Halloysite; Nanocomposite021001 nanoscience & nanotechnologyControlled release0104 chemical scienceslcsh:QD1-999chemistryCarbonatationengineeringhalloysite; nanocomposite; cellulose; controlled release0210 nano-technologyNanomaterials
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Green composites for fertilizer controlled release produced by compression molding and FDM

2023

Excessive fertilization causes ecological problems due to leaching issues. To solve this problem and promote agriculture sustainability an innovative green composite for controlled release fertilizers was produced by adding NPK fertilizer flour to a biodegradable polymer with or without Opuntia Ficus Indica (OFI) particles. Six formulations were produced and employed for the fabrication of devices both for compression molding (CM) and fused deposition modeling (FDM). Both fillers displayed a good dispersion in the composites, excellent adhesion with the polymeric matrix and effectively acted as reinforcement. The decrease of NPK release rate (up to 30 days) was achieved using whole composit…

Settore ING-IND/22 - Scienza E Tecnologia Dei MaterialiPolymer-matrix composites Biocomposite 3D Printing Compression moulding green composites NPK controlled release
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