Search results for " correlation"
showing 10 items of 1380 documents
Functional and biomechanical changes in keratoconic corneas after implantation of intracorneal ring segments 5 and 6mm in diameter
2012
Purpose To determinate biomechanical and functional changes in human keratoconic corneas after triangular section ring implantation in two designs. Methods Retrospective study of biomechanical properties of 46 patients (60 eyes) with keratoconus undergoing surgery Keraring® intracorneal ring segments divided into two groups according to 5 or 6 mm of diameter. Surgical technique to made the channel was with IntraLase femtosecond laser. UCVA and BSCVA were measured and biomechanical factors provided by the device ORA before surgery and postoperatively one month, 3 months and 6 months. Results After surgery, we obtained a significant increase (p 0.05). At baseline- 6 months, the improvement in…
Modifying the body distribution of HPMA-based copolymers by molecular weight and aggregate formation.
2011
There is a recognized need to create well-defined polymer probes for in vivo and clinical positron emission tomography (PET) imaging to guide the development of new generation polymer therapeutics. Using the RAFT polymerization technique in combination with the reactive ester approach, here we have synthesized well-defined and narrowly distributed N-(2-hydroxypropyl)methacrylamide homopolymers (pHPMA) (P1* and P2*) and random HPMA copolymers consisting of hydrophilic HPMA and hydrophobic lauryl methacrylate comonomers (P3* and P4*). The polymers had molecular weights below (P1* and P3*) and above the renal threshold (P2* and P4*). Whereas the homopolymers dissolve in isotonic solution as in…
A computational study of some electric and magnetic properties of gaseous BF3 and BCl3
2005
We present the results of an extended computational study of the electric and magnetic properties connected to Cotton-Mouton birefringences, on the trifluoro- and trichloroborides in the gas phase. The electric dipole polarizabilities, magnetizabilities, quadrupole moments, and higher-order hypersusceptibilities—expressed as quadratic and cubic frequency-dependent response functions—are computed within Hartree-Fock, density-functional, and coupled-cluster response theories employing singly and doubly augmented correlation-consistent basis sets and London orbitals in the magnetic property calculations. The results, which illustrate the capability of time-dependent density-functional theory f…
Performance Analysis of STBC-OFDM Systems in Temporally or Spatially Correlated Fading Channels
2010
This paper analyzes the performance of space-time block coded orthogonal frequency division multiplexing (OFDM) systems. In our analysis, we abandon the usually made assumption of quasi-static channel conditions. Instead of this, we consider the more general and realistic case that the channel envelope changes during two consecutive transmission time slots. In addition, we take the spatial correlation between sub-channels into account. We first present a general formal expression for the bit error probability (BEP), from which we find analytical solutions for the BEP not only for temporally fading channels but also for spatially correlated channels. The knowledge of the obtained analytical …
The Influence of Spatial Correlation and Severity of Fading on the Statistical Properties of the Capacity of OSTBC Nakagami-m MIMO Channels
2009
This paper deals with the analysis of statistical prop- erties of the capacity of spatially uncorrelated orthogonal space- time block coded (OSTBC) Nakagami-m multiple-input multiple- output (MIMO) channels. We have derived exact closed-form expressions for the probability density function (PDF), cumula- tive distribution function (CDF), level-crossing rate (LCR), and average duration of fades (ADF) of the channel capacity. We have also investigated the statistical properties of the approximated capacity of spatially correlated OSTBC Nakagami-m MIMO channels. The results are studied for different values of the fading parameter m, corresponding to different fading conditions. It is observed …
Optimal Sampling Period and Required Number of Samples for OSTBC-MIMO Rayleigh Fading Channel Capacity Simulators
2014
The purpose of this paper is to contribute to the performance assessment of channel capacity simulators. Here, we consider the instantaneous capacity (also referred to as the mutual information) in orthogonal space-time block code (OSTBC) transceiver systems over multiple-input multiple-output (MIMO) Rayleigh fading channels. To ensure that the level-crossing rate (LCR) of the instantaneous capacity can efficiently and accurately be simulated, we derive closed-form approximate solutions to the optimal sampling period and the required number of samples to be generated. Several numerical examples will be presented to illustrate the usefulness of our procedure. It will also be shown that the d…
An ab initio study of the tautomeric equilibria of the N-oxides of hydroxypyridines in the vapour phase
1993
Abstract An ab initio self-consistent field molecular orbital study of the N-oxides of hydroxypyridines has been carried out. The optimized structures have been obtained at the 6-31G ∗ level, and the energy values have been computed at the 6-31G ∗ and MP2-6-31G ∗ //6-31G ∗ levels. The tautomerization energies for the three couples of systems in the vapour phase have been evaluated.
A theoretical determination of the dissociation energy of the nitric oxide dimer
1994
Multi-reference CI methods have been applied to determine the dissociation energy and structure of thecis-N2O2 molecule. The convergence of the theoretical result has been checked with respect to a systematic expansion of the one-electron basis set and the multi-reference CI wave function. The best calculated value, 13.8 kJ/mol, is in agreement with the experimental value, 12.2 kJ/mol. It has been obtained with an extended ANO-type basis set [6s5p3d2f], including the effect of the basis set superposition error (BSSE) in the geometry optimization, and additional effects, such as the electron correlation of core electrons and relativistic corrections, using the average coupled pair functional…
Analysis of the CIPSI/DCCI approach to characterize the HF AND F2 single bond
1990
Abstract The aim of the present work is to account for the main differential correlation contributions occurring during the bond breaking process of HF and F2 molecules in an accurate and inexpensive way. Starting from the dissociation-consistent configuration interaction (DCCI) scheme by Goddard and co-workers the corresponding contributions are evaluated within the framework reported by Malrieu and co-workers, namely configuration interaction by perturbation with multiconfigurational zeroth-order wavefunction selected by iterative process (CIPSI). In addition, the DCCI scheme has been improved by introducing the dispersion effects associated with the valence MOs adjacent to the bond. The …
Diagnostic efficacy of panoramic mandibular index to identify postmenopausal women with low bone mineral densities
2011
Objectives: The aim of the study was to compare and assess the accuracy of panoramic mandibular index (PMI) and antegonial index (AI) in the panoramic radiographs of postmenopausal women with normal and low skeletal bone mineral densities( BMD) diagnosed by using dual energy x-ray absorptiometry ( DXA). Study Design: In panoramic radiographs obtained from 40 post menopausal women( 20 normal and 20 osteoporo tic) aged between 50-75 who’s BMD has already been assessed by a DXA, the mean was calculated for PMI and AI index values measured in the right and left mandibles. The PMI and AI index values were evaluated using the student’s t test. The correlation between the observers for indices was…