Search results for " coupling"
showing 10 items of 724 documents
A Regio- and Diastereoselective Anodic Aryl-Aryl Coupling in the Biomimetic Total Synthesis of (-)-Thebaine.
2018
The biosynthesis of thebaine is based on the regioselective, intramolecular, oxidative coupling of (R)-reticuline. For decades, chemists have sought to mimic this coupling by using stoichiometric oxidants. However, all approaches to date have suffered from low yields or the formation of undesired regioisomers. Electrochemistry would represent a sustainable alternative in this respect but all attempts to accomplish an electrochemical synthesis of thebaine have failed so far. Herein, a regio- and diastereoselective anodic coupling of 3',4',5'-trioxygenated laudanosine derivatives is presented, which finally enables electrochemical access to (-)-thebaine.
The Nuclear Mean Field and Many-Nucleon Configurations
2007
After the two preceding chapters, throughout impregnated with messy-looking, though necessary mathematics, we are finally entering the realm of basic concepts of nuclear structure physics. While the preceding chapters may have been a shock to the reader not familiar with the fine details of angular momentum coupling, the present chapter should offer a soothing soft landing to the basic philosophy behind the nuclear shell model, namely the nuclear mean field.
Fullerene-ionic-liquid conjugates: a new class of hybrid materials with unprecedented properties.
2015
A modular approach has been followed for the synthesis of a series of fullerene-ionic-liquid (IL) hybrids in which the number of IL moieties (two or twelve), anion, and cation have been varied. The combination of C60 and IL give rise to new unique properties in the conjugates such as solubility in water, which was higher than 800 mg mL(-1) in several cases. In addition, one of the C60 -IL hybrids has been employed for the immobilization of palladium nanoparticles through ion exchange followed by reduction with sodium borohydride. Surprisingly, during the reduction several carbon nanostructures were formed that comprised nano-onions and nanocages with few-layer graphene sidewalls, which have…
Through-space spin-spin coupling in acetylenic systems. Ab initio and DFT calculations
2003
Abstract: We have investigated, by means of ab initio and DFT calculations, the magnitude of through-space spin-spin couplings ( J CH and J HH ) in CH/π bonded van der Waals dimers involving acetylene, and in a structurally related covalent compound (4-ethynylphenanthrene). Within regions where the interaction is stabilizing J HH couplings are very small (< 0.1 Hz) for all complexes. In the acetylene-methane complex J CH is also very small, whereas in the acetylene-benzene complex and the acetylene dimer it shows a relatively large dependence on the tilt angle from the T-shaped arrangement, for which the smallest values are calculated, to a parallel slipped arrangement where J CH is ca. 0.5…
Status of EU DEMO heat transport and power conversion systems
2018
Abstract DEMO in Europe is considered to be the nearest-term reactor design to follow ITER and capable of demonstrating production of electricity, operating with a closed fuel-cycle and to be a facilitating machine between ITER and a commercial reactor. The aim of this paper is to show the design progress of the complex system’s “chain” devoted to the extraction of the plasma generated pulsed thermal power and its conversion into electricity delivered to the grid, including the Primary Heat Transport System (PHTS), the Power Conversion System (PCS) and the Intermediate Heat Transport System (IHTS) – provided by an Energy Storage System (ESS) – in between PHTS and PCS, which is introduced fo…
Measurement of the W boson polarization in top quark decays with the ATLAS detector
2012
This paper presents measurements of the polarization of W bosons in top quark decays, derived from t¯t events with missing transverse momentum, one charged lepton and at least four jets, or two charged leptons and at least two jets. Data from pp collisions at a centre-of-mass energy of 7 TeV were collected with the ATLAS experiment at the LHC and correspond to an integrated luminosity of 1.04 fb−1. The measured fractions of longitudinally, left- and right-handed polarization are F0 = 0.67 ± 0.07, FL = 0.32 ± 0.04 and FR = 0.01 ± 0.05, in agreement with the Standard Model predictions. As the polarization of the W bosons in top quark decays is sensitive to the Wtb vertex Lorentz structure and…
Precision electroweak measurements on the Z resonance
2005
We report on the final electroweak measurements performed with data taken at the Z resonance by the experiments operating at the electron-positron colliders SLC and LEP. The data consist of 17 million Z decays accumulated by the ALEPH, DELPHI, L3 and OPAL experiments at LEP, and 600 thousand Z decays by the SLD experiment using a polarised beam at SLC. The measurements include cross-sections, forward-backward asymmetries and polarised asymmetries. The mass and width of the Z boson, $\MZ$ and $\GZ$, and its couplings to fermions, for example the $\rho$ parameter and the effective electroweak mixing angle, are precisely measured. The number of light neutrino species is determined to be 2.9840…
Electroweak measurements in electron-positron collisions at W-boson-pair energies at LEP
2013
The ALEPH, DELPHI, L3, OPAL collaborations and LEP Electroweak Working Group.-- arXiv:1302.3415
Comparison of two different approaches for harmonic distortion sources assessment
2021
The paper focuses the attention on the comparison of two approaches for power quality assessment in the electric grid. Both approaches are suitable for investigating the harmonic pollution source and discovering if the harmonic source comes from the customer or the utility grid. The two approaches have the same purpose but they are deeply different. The first approach is based on the knowledge of the customer and utility equivalent impedance while the second is based on single point measurement at point of common coupling PCC. In this paper, the advantages and drawbacks of the two approaches are investigated also supported by a case study.
Dynamic response of multiply connected primary-secondary systems
1990
The nodal equations of motion of the composite system are given in «total» and «relative» coordinates. In the framework of the component-mode synthesis method a coordinate transformation, here defined as an admissible one, is used to reduce the nodal equations of motion. This coordinate transformation is theoretically and numerically compared with the coordinate transformation usually used in the literature, which generally gives larger errors with respect to the former when a reduced number of nodes is considered