Search results for " crack"

Catalytic cracking of n-alkane naphtha: The impact of olefin addition and active sites differentiation

2015

An extended dual kinetic model allows to fit the n-heptane cracking results working in a wide range of reaction conditions. The duality of the model is provided by the contribution of monomolecular and bimolecular cracking mechanisms. It takes into account the role played by the olefins formed on the global cracking or added within the feed. Furthermore by means of this model and the kinetic parameters obtained when cracking n-heptane on ZSM-5, it has been observed that, while some characterization techniques show a homogeneous zeolite surface from the point of view of the active sites, rigorous kinetic experiments point to the possibility that the reactant sees a heterogeneous surface with…

Localized hydrogen cracking in the austenitic phase of a duplex stainless steel

1996

The aim of this study is to investigate the role of hydrogen on the mechanical behavior of an austenitic phase, in the particular situation of duplex stainless steels. In these duplex alloys, in presence of hydrogen, the ferritic phase is embrittled by hydrogen and the resistance to cracking is mainly related to the behavior of the austenitic phase. Thus, a discussion of the role of hydrogen at the crack tip of a duplex alloy (as function of the microstructure) has been proposed by T. Perng and C.J. Altester after experiments conducted in gaseous environment. A similar experimental approach has been followed in this study; slow strain rate tests (SSRT) have been performed on duplex stainles…

Automation of Optimized Gabor Filter Parameter Selection for Road Cracks Detection

2016

International audience; Automated systems for road crack detection are extremely important in road maintenance for vehicle safety and traveler's comfort. Emerging cracks in roads need to be detected and accordingly repaired as early as possible to avoid further damage thus reducing rehabilitation cost. In this paper, a robust method for Gabor filter parameters optimization for automatic road crack detection is discussed. Gabor filter has been used in previous literature for similar applications. However, there is a need for automatic selection of optimized Gabor filter parameters due to variation in texture of roads and cracks. The problem of change of background, which in fact is road text…

Application of the 3-D boundary element method to delaminated composite structures

2013

A three-dimensional boundary element model for anisotropic solids is presented to study the fracture mechanics behavior of delaminated composite structures. The multi-domain technique is implemented to model the layered configurations and the cracks occurring at bi-material interface. The Modified Crack Closure Integral technique is implemented to characterize the fracture mechanics behavior of delaminations in terms of the total energy release rate and mode mix phase angles. Validating analyses, performed on different delaminated configurations, have shown the effectiveness of the proposed approach. Moreover, some original results are presented to investigate the effects of the stacking se…

The mechanically-based approach to 3D non-local linear elasticity theory: Long-range central interactions

2010

Abstract This paper presents the generalization to a three-dimensional (3D) case of a mechanically-based approach to non-local elasticity theory, recently proposed by the authors in a one-dimensional (1D) case. The proposed model assumes that the equilibrium of a volume element is attained by contact forces between adjacent elements and by long-range forces exerted by non-adjacent elements. Specifically, the long-range forces are modelled as central body forces depending on the relative displacement between the centroids of the volume elements, measured along the line connecting the centroids. Further, the long-range forces are assumed to be proportional to a proper, material-dependent, dis…

3D boundary element analysis of delamination crack using the Modified Crack Closure Integral

2012

Structural Health Monitoring of delaminated composite structures by the Boundary Element method

2012

Structural Health Monitoring (SHM) for composite materials is becoming a primary task due to their extended use in safety critical applications. Different methods, based on the use of piezoelectric transducers, strain memory alloys as well as of fibre optics, has been successfully proposed to detect and monitor damage in composite structural components with particular attention focused on delamination cracks. In the present paper a Structural Health Monitoring model based on the use of piezoelectric sensors, already proposed by the authors for isotropic damaged components, is extended to delaminated composite structures. The dynamic behavior of the host damaged structure and the bonded piez…

Buckling and post-buckling analysis of cracked composite plates via a single-domain Ritz approach

2018

Thin and moderately thick composite multi-layered plates are widely employed in many engineering applications, especially in naval and aerospace structures. These structural components can experience in service the presence of cracks, generated for example by corrosion, fatigue or accidental external causes. Cracks can affect the load carrying capability, buckling and post-buckling behaviour of plates; therefore, their effects need to be investigated and taken into account for fail safe or damage tolerant design. Additionally, attention should be devoted to the interaction of cracks with buckling and post-buckling behaviour, as the energy release rate in post-buckling regimes can be adverse…

A kinetic study of the cracking, isomerization, and disproportionation of n-heptane on a chromium-exchanged Y zeolite

1982

The kinetic rate constants for the cracking, isomerization, and disproportionation of n-heptane over a CrHNaY (32% chromium exchanged) zeolite catalyst at 400, 450, and 470 °C have been calculated. The interaction of n-heptane with a model Lewis acid such as BF3 and progress along the reaction coordinate have been studied by means of molecular orbital calculations. From the kinetic results, i.e., activation energies and frequency factors, and the theoretical calculations, it can be concluded that the controlling step in these reactions is not the formation of the carbonium ion, but the subsequent transformation of this carbonium ion. In addition, the theoretical calculations show that the a…

Current views on the mechanism of catalytic cracking

2000

Abstract The cracking mechanisms of hydrocarbons have been reviewed and the kinetic and thermodynamic implications of the different steps, i.e. initiation, chain propagation, and termination, have been discussed. Although the cracking mechanism of olefins and alkylaromatics is well established, the initiation step for the cracking of paraffins is still under debate. The role of Bronsted-type active sites and also the possible influence of extra-framework Al species in the case of zeolite catalysts, especially when commercial feeds and industrial conditions are employed, are presented. The product distribution is determined by the number of propagation events occurring per initiation step, a…