Search results for " diffraction"
showing 10 items of 896 documents
Large Fibres in Urinary Calculi—-Promoters of Stone Formation
1988
Large fibres (phi 10-20 microns, length up to 5,000 microns) are sometimes imbedded in urinary calculi. It may be that these fibres can catch sediment particles and promote stone growth. By scanning electron microscopy the morphology of the fibres was studied as well as the relationship of the fibres with crystalline stone components. The reported findings suggest that the fibres are possibly formed in the tubuli as the result of an hitherto unknown defect.
X-ray diffraction of a protein crystal anchored at the air/water interface
1995
We report the first successful in situ x-ray diffraction experiment with a 2D protein array at the lipid/water interface and demonstrate that the order can be controlled via lateral pressure or density. A protein (streptavidin) was bound to a monolayer of biotinylated lipid at the air/water interface, and diffraction of the protein layer could be measured to many orders. Compression of the monolayer changed the diffraction pattern drastically, indicating that the protein structure can be strongly influenced by external parameters like lateral pressure or density. From the width of the peaks, we find that aggregates consisting of as few as 100 monomers contribute to the diffraction. This ind…
Microstructural, chemical and textural records during growth of snowball garnet
2009
The growth history of two populations of snowball garnet from the Lukmanier Pass area (central Swiss Alps) was examined through a detailed analysis of three-dimensional geometry, chemical zoning and crystallographic orientation. The first population, collected in the hinge of a chevron-type fold, shows an apparent rotation of 360 degrees. The first 270 degrees are characterized by spiral-shaped inclusion trails, gradual and concentric Mn zoning and a single crystallographic orientation, whereas in the last 90 degrees, crenulated inclusion trails and secondary Mn maxima centred on distinct crystallographic garnet domains are observed. Microstructural, geochemical and textural data indicate a…
An X-ray powder diffraction study of lanthanum–strontium ferromanganites
2001
Abstract Various lanthanum–strontium ferromanganites (La 1− x Sr x )(Mn 1− y Fe y )O 3± δ (LSMF) with x =0.2, 0.5 and 0.7 and y =0.2, 0.5 and 0.8 were prepared by a glycine–nitrate combustion route and conditioned into two different oxygenation states which are likely to be encountered in cathode materials for solid oxide fuel cells (SOFC). Crystal symmetries for both the low and the fully oxygenated states were determined by X-ray diffractometry. Most perovskite compositions crystallized in either cubic or rhombohedral symmetry with the exception of La 0.5 Sr 0.5 Mn 0.2 Fe 0.8 O 3± δ , where a transition from rhombohedral to cubic occurred in going from the full to the low oxygenation stat…
Automated electron diffraction tomography – development and applications
2019
Electron diffraction tomography, a potential method for structure analysis of nanocrystals, and, in more detail, the strategies to use automated diffraction tomography (ADT) technique are described. Examples of ADT application are discussed according to the material class.
Stylolite interfaces and surrounding matrix material: Nature and role of heterogeneities in roughness and microstructural development
2010
Rough pressure solution interfaces, like stylolites, are one of the most evident features of localized slow deformation in rocks of the upper crust. There is a general consensus that the development of these rough structures is a result of localized, stress enhanced, dissolution of material along a fluid filled interface, but little is known on the initiation of this roughness. The aim of this article is to reveal the role of heterogeneities initially present in the host-rock on roughness initiation. This should give insights on whether stylolite roughness is generated by a stress-induced instability or by the presence of disorder in the material (i.e. quenched noise). We use a microstructu…
Melting behaviour of d-sucrose, d-glucose and d-fructose
2004
The melting behaviour of d-sucrose, d-glucose and d-fructose was studied. The melting peaks were determined with DSC and the start of decomposition was studied with TG at different rates of heating. In addition, melting points were determined with a melting point apparatus. The samples were identified as d-sucrose, alpha-d-glucopyranose and beta-d-fructopyranose by powder diffraction measurements. There were differences in melting between the different samples of the same sugar and the rate of heating had a remarkable effect on the melting behaviour. For example, T(o), DeltaH(f) and T(i) (initial temperature of decomposition) at a 1 degrees Cmin(-1) rate of heating were 184.5 degrees C, 126…
An Easy Stereoselective Access to β,γ-Aziridino α-Amino Ester Derivatives via Mannich Reaction of Benzophenone Imines of Glycine Esters with N-Sulfon…
2007
Mannich-type addition of benzophenone imine glycinates across newly synthesized N-(p-toluenesulfonyl) alpha-chloroaldimines afforded gamma-chloro-alpha,beta-diamino ester derivatives with moderate diastereoselectivity as separable mixtures of anti and syn diastereomers. The gamma-chloro-alpha,beta-diamino esters were efficiently cyclized under basic conditions to the corresponding beta,gamma-aziridino alpha-amino ester derivatives, representing a new class of conformationally constrained heterocyclic alpha,beta-diamino acid derivatives. The relative configuration of the aziridines was determined via X-ray diffraction analysis. Mechanisms and intermediate transition states to explain the ste…
The effect of Fe doping on superconductivity in ZrRuP
2011
Abstract This work reports the structure and superconducting properties of the superconductor ZrRuP doped with Fe; the ZrRu 1− x Fe x P solid solution was investigated by means of X-ray powder diffraction, SQUID magnetometry and Mosbauer spectroscopy. It is shown that the modification of the superconducting properties by doping with Fe is similar to the effect of chemical pressure and that the Fe doped compounds do not show any magnetic ordering.
Thermodynamic and Neutron-Diffraction Studies of H2 and D2 Multilayers Physisorbed on Graphite
1991
The evolution of physisorbed films from two-dimensional (2D) to bulk behavior is a topic of high current interest.1 In this context the behavior of the quantum systems H2, HD and D2 is of particular relevance because of the following reasons: 1. Due to the strong influence of the quantum zero-point energy the hydrogen isotopes are highly compressible. This leads to strongly compressed monolayers2,3 before further layer condensation occurs. This property makes these systems significant for the exploration of conditions of multilayer growth. It is generally believed,1,4–6 that the incompatibility between the adsorbate and bulk lattice structures gives rise to lateral strains between the overl…