Search results for " diffusion"

Anomalous diffusion: Summary

2007

Testing Mode-Coupling Theory for a Supercooled Binary Lennard-Jones Mixture II: Intermediate Scattering Function and Dynamic Susceptibility

1995

We have performed a molecular dynamics computer simulation of a supercooled binary Lennard-Jones system in order to compare the dynamical behavior of this system with the predictions of the idealized version of mode-coupling theory (MCT). By scaling the time $t$ by the temperature dependent $\alpha$-relaxation time $\tau(T)$, we find that in the $\alpha$-relaxation regime $F(q,t)$ and $F_s(q,t)$, the coherent and incoherent intermediate scattering functions, for different temperatures each follows a $q$-dependent master curve as a function of scaled time. We show that during the early part of the $\alpha$-relaxation, which is equivalent to the late part of the $\beta$-relaxation, these mast…

Theory of Kondo suppression of spin polarization in nonlocal spin valves

2016

We theoretically analyze contributions from the Kondo effect to the spin polarization and spin diffusion length in all-metal nonlocal spin valves. Interdiffusion of ferromagnetic atoms into the normal metal layer creates a region in which Kondo physics plays a significant role, giving discrepancies between experiment and existing theory. We start from a simple model and construct a modified spin drift-diffusion equation which clearly demonstrates how the Kondo physics not only suppresses the electrical conductivity but even more strongly reduces the spin diffusion length. We also present an explicit expression for the suppression of spin polarization due to Kondo physics in an illustrative …

Dynamics of the rotational degrees of freedom in a supercooled liquid of diatomic molecules

1997

Using molecular dynamics computer simulations, we investigate the dynamics of the rotational degrees of freedom in a supercooled system composed of rigid, diatomic molecules. The interaction between the molecules is given by the sum of interaction-site potentials of the Lennard-Jones type. In agreement with mode-coupling theory (MCT), we find that the relaxation times of the orientational time correlation functions C_1^(s), C_2^(s) and C_1 show at low temperatures a power-law with the same critical temperature T_c, and which is also identical to the critical temperature for the translational degrees of freedom. In contrast to MCT we find, however, that for these correlators the time-tempera…

Microscopic theory for the glass transition in a system without static correlations

2002

We study the orientational dynamics of infinitely thin hard rods of length L, with the centers-of-mass fixed on a simple cubic lattice with lattice constant a.We approximate the influence of the surrounding rods onto dynamics of a pair of rods by introducing an effective rotational diffusion constant D(l),l=L/a. We get D(l) ~ [1-v(l)], where v(l) is given through an integral of a time-dependent torque-torque correlator of an isolated pair of rods. A glass transition occurs at l_c, if v(l_c)=1. We present a variational and a numerically exact evaluation of v(l).Close to l_c the diffusion constant decreases as D(l) ~ (l_c-l)^\gamma, with \gamma=1. Our approach predicts a glass transition in t…

Stochastic Models of Higher Order Dielectric Responses

2018

The nonlinear response for systems exhibiting Markovian stochastic dynamics is calculated using time-dependent perturbation theory for the Green’s function, the conditional probability to find the system in a given configuration at a certain time given it was in another configuration at an earlier time. In general, the Green’s function obeys a so-called master-equation for the balance of the gain and loss of probability in the various configurations of the system. Using various models for the reorientational motion of molecules it is found that the scaled modulus of the third-order response, \(X_3\), shows a hump-like behavior for random rotational motion in some cases and it exhibits “triv…

Vortex diffusion and vortex-line hysteresis in radial quantum turbulence

2014

Abstract We study the influence of vortex diffusion on the evolution of inhomogeneous quantized vortex tangles. A simple hydrodynamical model to describe inhomogeneous counterflow superfluid turbulence is used. As an illustration, we obtain solutions for these effects in radial counterflow of helium II between two concentric cylinders at different temperatures. The vortex diffusion from the inner hotter cylinder to the outer colder cylinder increases the vortex length density everywhere as compared with the non-diffusive situation. The possibility of hysteresis in the vortex line density under cyclical variations of the heat flow is explored.

SPECIAL HPERBOLIC TYPE APPROXIMATION FOR SOLVING OF 3-D TWO LAYER STATIONARY DIFFUSION PROBLEM

2019

In this paper we examine the conservative averaging method (CAM) along the vertical z-coordinate for solving the 3-D boundary-value 2 layers diffusion problem. The special parabolic and hyperbolic type approximation (splines), that interpolate the middle integral values of piece-wise smooth function, is investigated. With the help of these splines the problems of mathematical physics in 3-D with respect to one coordinate are reduced to problems for system of equations in 2-D in every layer. This procedure allows reduce also the 2-D problem to a 1-D problem and the solution of the approximated problem can be obtained analytically. As the practical application of the created mathematical mode…

Diffusion Process in Quasi-One-Dimensional Structures as Elements of Novel Nanodevices

2012

The effective diffusion coefficient in two-phase one-dimensional model with the periodical distribution of inclusions in the effective medium approximation is calculated and generalization about a quasi-one-dimensional case is formed.

Influence of rotational diffusion on the electric field induced effect on the fluorescence spectrum of diluted solutions I. Theory and numerical simu…

1997

Abstract The theory for the calculation of excited state dipole moments from electrooptical emission measurements, developed by Baumann and Deckers (Ber. Bunsenges. Phys. Chem. 81 (1977) 786) presupposes a Boltzmann distribution for the emitting molecules. Using the anisotropic rotational diffusion model and taking into account all important electric field induced effects, we derive equations that describe quantitatively the electric field effect on the fluorescence of an ensemble of solute rigid molecules which are not yet equilibrated with respect to their orientation when emitting. Numerical simulations are performed to compare the general case and the limiting case of a prevailing Boltz…