Search results for " effect"

showing 10 items of 7524 documents

Proximity Effect using a Nanocage Structure: Polyhedral Oligomeric Silsesquioxane-Imidazolium Tetrachloro- palladate Salt as a Precatalyst for the Su…

2016

A polyhedral oligomeric silsesquioxane-imidazolium tetrachloropalladate salt (POSS-Imi-PdCl4) was prepared by the reaction of a polyhedral oligomeric silsesquioxane-imidazolium chloride salt (POSS-Imi-Cl) with PdCl2 and used as a pre-catalyst for the Suzuki-Miyaura reaction in water at 100 °C at a low loading (0.08-0.16 mol %). Biphenyl compounds were isolated in high to excellent yields. A comparison of the POSS-based catalyst with the corresponding catalyst without the nanocage structure (i.e., 1-butyl-3-methylimidazolium tetrachloropalladate) highlighted the role of the POSS structure to reach higher yields in the Suzuki-Miyaura reaction. This result is ascribed to a proximity effect of …

chemistry.chemical_elementSalt (chemistry)supported catalyst010402 general chemistry01 natural sciencesCatalysisCatalysisInorganic Chemistrychemistry.chemical_compoundNanocagesX-ray photoelectron spectroscopyPolymer chemistryOrganic chemistrysupported catalystsPhysical and Theoretical Chemistrychemistry.chemical_classification010405 organic chemistryChemistryOrganic Chemistrypalladiumcage compoundSilsesquioxane0104 chemical sciencesBiphenyl compoundphase-transfer catalysiphase-transfer catalysisC-C couplingcage compoundsProximity effect (atomic physics)Palladium
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Interactive effects of boron and salinity on greenhouse tomato grown in closed soilless system.

2012

chlorophyll fluorescenceGreenhousechemistry.chemical_elementhydroponicsprotected horticultureHorticultureHydroponicsboron (B) toxicityleaf burnSalinityHorticultureAgronomyInteractive effectschemistryNaClEnvironmental scienceboron (B) toxicity chlorophyll fluorescence hydroponics leaf burn NaCl protected horticulture Solanum lycopersicum L.Solanum lycopersicum LBoronChlorophyll fluorescence
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On the trail of local welfare innovations in rural Finland

2019

Final Draft In Finland, the rural areas have been most affected by the developments threatening the survival of the welfare state as well as by conflicting efforts to save it. However, there are rural communities that have—as a response to the mainstream policy emphasizing economic efficiency and individual responsibility—developed innovative solutions to secure their welfare. Based on a case study focusing on two of such communities, these local welfare innovations are a result from a combination of external causes and local resources including the sense of community and a diverse enough community structure. The authors argue that in the context of welfare policy, the promotion of local we…

clubsPublic economicscommitteesmedia_common.quotation_subjectsosiaaliset innovaatiotmaaseutuyhteisötGeography Planning and DevelopmenthyvinvointipolitiikkaPublic policyprovision and effects of welfare programmessocial choiceManagement Monitoring Policy and LawDevelopmentgrowth development and changes [regional economic activity]government policyhyvinvointitalouskehitysohjelmatPolitical sciencewelfare economicsmaaseutuSocial choice theoryWelfareassociationsmedia_common
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Prevention of Dominant IgG Adsorption on Nanocarriers in IgG‐Enriched Blood Plasma by Clusterin Precoating

2019

Abstract Nanocarriers for medical applications must work reliably within organisms, independent of the individual differences in the blood proteome. Variation in the blood proteome, such as immunoglobulin levels, is a result of environmental, nutrition, and constitution conditions. This variation, however, should not influence the behavior of nanocarriers in biological media. The composition of the protein corona is investigated to understand the influence varying immunoglobulin levels in the blood plasma have on the interactions with nanocarriers. Specifically, the composition of the nanocarriers' coronas is analyzed after incubation in plasma with normal or elevated immunoglobulin G (IgG)…

clusterinGeneral Chemical Engineeringmedia_common.quotation_subjectGeneral Physics and AstronomyMedicine (miscellaneous)Protein Corona02 engineering and technology010402 general chemistry01 natural sciencesBiochemistry Genetics and Molecular Biology (miscellaneous)Immunoglobulin Gimmunoglobulin Gprotein coronaBlood plasmaGeneral Materials ScienceReceptorInternalizationlcsh:Sciencemedia_commonstealth effectbiologyFull PapernanocarriersChemistryGeneral EngineeringFull Papers021001 nanoscience & nanotechnology0104 chemical sciencesIgG bindingBiophysicsbiology.proteinlcsh:QNanocarriersAntibody0210 nano-technologyAdvanced Science
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Community Resilience to Cyclone Disasters in Coastal Bangladesh

2016

Bangladesh is one of the poorest and most disaster-prone countries in the world. To address both problems simultaneously, sustainable livelihoods (SL) could be better connected with disaster risk reduction (DRR). For this purpose, one initiative implemented in Bangladesh is called the Vulnerability to Resilience (V2R) programme which ran from 2013 to 2016. This programme was primarily initiated and funded by the British Red Cross in a consortium with the Swedish Red Cross and the German Red Cross. This article presents the first evaluation of the V2R programme with three objectives. The first objective was to measure whether the selected communities have achieved community resilience charac…

coastal communityEnvironmental sciencesBangladeshEnvironmental effects of industries and plantscyclonevulnerabilityTJ807-830GE1-350TD194-195resiliencedisaster risk reductionsustainable livelihoodsRenewable energy sourcesSustainability
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High-contrast sub-Doppler absorption spikes in a hot atomic vapor cell exposed to a dual-frequency laser field

2017

International audience; The saturated absorption technique is an elegant method widely used in atomic and molecular physics for high-resolution spectroscopy, laser frequency standards and metrology purposes. We have recently discovered that a saturated absorption scheme with a dual-frequency laser can lead to a significant sign reversal of the usual Doppler-free dip, yielding a deep enhanced-absorption spike. In this paper, we report detailed experimental investigations of this phenomenon, together with a full in-depth theoretical description. It is shown that several physical effects can support or oppose the formation of the high-contrast central spike in the absorption profile. The physi…

coherent population trappingGeneral Physics and Astronomy01 natural scienceslaw.invention010309 opticssymbols.namesakelawLaser cooling0103 physical sciencesvapor cellPhysics::Atomic Physics010306 general physicsAbsorption (electromagnetic radiation)Spectroscopyoptical pumpingPhysicsQuantum optics[PHYS.PHYS.PHYS-OPTICS]Physics [physics]/Physics [physics]/Optics [physics.optics]Doppler-free spectroscopydual-frequency laserLaserAtomic clockMetrologyHanle effectsymbolsAtomic physics[PHYS.ASTR]Physics [physics]/Astrophysics [astro-ph]Doppler effect
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A Non-Local Mode-I Cohesive Model for Ascending Thoracic Aorta Dissections (ATAD)

2018

This paper presents a non-local interface mechanical model to describe aortic dissection. In this regard, the mode-I debonding problem based on a cohesive zone modeling is endowed with non-local terms to include long-range interactions that are present in multi-layered biological tissue. Such non-local effects are related to the collagen fibers that transmit forces between non-adjacent elements. Numerical simulations are provided with different values of the non-local parameters in order to show the effect of the non-locality during the debonding processes.

cohesive zone modelSettore MED/09 - Medicina InternaMaterials scienceEnergy Engineering and Power Technologydebonding processIndustrial and Manufacturing Engineeringbiomechanicsnon-local effectsArtificial Intelligencemedicine.arterybiomechanics; cohesive zone model; debonding process; non-local effectsmedicineThoracic aortaInstrumentationdebonding proceAortic dissectionRenewable Energy Sustainability and the EnvironmentMode (statistics)BiomechanicsComputer Science Applications1707 Computer Vision and Pattern RecognitionMechanicsBiological tissuemedicine.diseaseNon localCohesive zone modelComputer Networks and Communicationnon-local effectbiomechanicSettore ICAR/08 - Scienza Delle Costruzioni
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ALIGNEMENT UNI ET TRIDIMENSIONNEL DE MOLÉCULES PAR IMPULSION LASER FEMTOSECONDE

2007

This thesis is devoted to the study of the alignment of linear and asymmetric top molecules generated by an intense laser pulse. In the case of short pulses with respect to molecular rotation, periodic alignment appears in field-free conditions after the extinction of the field. We study theoretically and experimentally the effects of intensity, temperature and polarization of the electric field on produced alignment. If the field is linearly polarized, the interaction leads to the alignment of the most polarizable axis of the molecule. If the field is elliptically polarized, the pulse can generate a simultaneous alignment of the three principal axes of inertia of an asymmetric top molecule…

cohérence rotationnelleMolecular alignmenteffet Kerr optique.[PHYS.PHYS.PHYS-ATOM-PH]Physics [physics]/Physics [physics]/Atomic Physics [physics.atom-ph][ PHYS.PHYS.PHYS-ATOM-PH ] Physics [physics]/Physics [physics]/Atomic Physics [physics.atom-ph]Alignement moléculairebiréfringenceimpulsion ultrabrèveoptical Kerr effect.Pump-probe techniquelinear and asymmetric top moleculesmolécules linéaires et asymétriquestechniques pompe-sondeultrashort laser pulse[PHYS.PHYS.PHYS-ATOM-PH] Physics [physics]/Physics [physics]/Atomic Physics [physics.atom-ph]rotational coherenceeffet Kerr optique
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"Having a drink in a bar": An immersive approach to explore the effects of context on drink choice

2013

UT: 000315557500004; International audience; This paper aims to evaluate the effect of context on food choices. Two studies are presented to test the potential of an immersive approach to help understanding contextual influences on drink choices. To generate contextual effects, two bar-like environments based on the idea of "having a drink in a bar" were created: one with wood furniture and one with blue furniture. In both immersive bars, clips with visual and music stimuli were projected on a wall to change the overall warmth of the ambience. In the first study, five different clips were projected. Participants in the immersive bars had to choose a drink within a large range of drinks for …

colour030309 nutrition & dieteticsContextual effectsBar (music)media_common.quotation_subject[ SDV.AEN ] Life Sciences [q-bio]/Food and NutritionApplied psychologyContext (language use)food choicecontextmultisensory perception03 medical and health sciences0404 agricultural biotechnologyPerceptionContextual variableacceptabilityFood choicemusicphysical-environmentauditory cuesComputingMilieux_MISCELLANEOUSmedia_common0303 health sciencesNutrition and Dieteticsflavorimmersive barsdurationCognition04 agricultural and veterinary sciences040401 food scienceTest (assessment)drink choicesresponsesPsychologysocial-interactionSocial psychology[SDV.AEN]Life Sciences [q-bio]/Food and NutritionFood Science
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Hunting for new physics signals in the LHC era

2021

Actualment, el ME de física de partícules és capaç d’explicar satisfactòriament tres de les quatre interaccions fonamentals de la matèria: fortes, febles i electromagnètiques. Tot i això, hi han molts aspectes que aquesta fantàstica teoria no és capaç d’explicar i, sens dubte, ha d’haver alguna cosa més enllà d’aquesta teoria. En aquesta tesi es pretén descobrir si hi ha algun indici a les dades actuals dels acceleradors que suggerisca l’existència de nova física (NF). Pretenem, per tant, determinar fins a quin punt alguns dels models de NF que han sigut proposats a la literatura poden ser plausibles tenint en compte les dades actuals. D’aquesta forma, serem capaços de trobar restriccions s…

colour-octet scalars:FÍSICA::Física de altas energías::Física teórica altas energías [UNESCO]phenomenologystandard model effective field theorytop-quarkUNESCO::FÍSICA::Física de altas energías::Física teórica altas energías
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