Search results for " electricity"

Computational evidence in favor of a two-state, two-mode model of the retinal chromophore photoisomerization

2000

In this paper we use ab initio multiconfigurational second-order perturbation theory to establish the intrinsic photoisomerization path model of retinal chromophores. This is accomplished by computing the ground state ( S 0 ) and the first two singlet excited-state ( S 1 , S 2 ) energies along the rigorously determined photoisomerization coordinate of the rhodopsin chromophore model 4- cis -γ-methylnona-2,4,6,8-tetraeniminium cation and the bacteriorhodopsin chromophore model all- trans -hepta-2,4,6-trieniminium cation in isolated conditions. The computed S 2 and S 1 energy profiles do not show any avoided crossing feature along the S 1 reaction path and maintain an energy gap >20 kcal⋅…

EU transition in power sector: How RES affects the design and operations of transmission power systems

2019

In the past, much of Europe's electricity grid network has been designed in consideration of the locations of conventional generation plants. However, a large share of today's renewables production – notably variable wind and solar – does not correspond to this grid architecture. Interconnectors, in addition to internal infrastructure, are key to creating new electricity corridors to connect areas of surplus to areas of scarcity. In this context, in 2014 the European Council, in recognizing that a fundamental role of transmission infrastructure is to enable the integration of areas of high renewable energy potential with main consumption areas, endorsed the proposal by the European Commissi…

Efecto Raman resonante con campos magnéticos intensos en heteroestructuras semiconductoras

1994

Production altitude and time delays of the terrestrial gamma flashes: Revisiting the Burst and Transient Source Experiment spectra

2008

[1] On the basis of the RHESSI results it has been suggested that terrestrial gamma flashes (TGFs) are produced at very low altitudes. On the other hand some of the Burst and Transient Source Experiment (BATSE) spectra show unabsorbed fluxes of X rays in the 25–50 keV energy range, indicating a higher production altitude. To investigate this, we have developed a Monte Carlo code for X-ray propagation through the atmosphere. The most important features seen in the modeled spectra are (1) a low-energy cutoff which moves to lower energies as TGFs are produced at higher altitudes, (2) a high-energy cutoff which moves to lower energies as TGFs are observed at larger zenith angles, and (3) time d…

Microscopic approach to the kinetics of pattern formation of charged molecules on surfaces.

2010

A microscopic formalism based on computing many-particle densities is applied to the analysis of the diffusion-controlled kinetics of pattern formation in oppositely charged molecules on surfaces or adsorbed at interfaces with competing long-range Coulomb and short-range Lennard-Jones interactions. Particular attention is paid to the proper molecular treatment of energetic interactions driving pattern formation in inhomogeneous systems. The reverse Monte Carlo method is used to visualize the spatial molecular distribution based on the calculated radial distribution functions (joint correlation functions). We show the formation of charge domains for certain combinations of temperature and dy…

Torsional effects on the molecular polarizabilities of the benzothiazole (A)-benzobisthiazole (B) oligomer A-B13-A

1996

Abstract We outline a method for the calculation of multipole moments and molecular dipole-dipole ( ), dipole-quadrupole ( ), and quadrupole-quadrupole ( ) polarizabilities, which we have successfully applied to benzothiazole (A)-benzobisthiazole (B) oligomer A-B13-A. Three model rotational isomers have been characterized: (1) the fully planar (000) rotational isomer; (2) a conformation with each unit rotated 10° in the alternate direction (+−+), and (3) a rotational isomer with each unit rotated 10° in the same direction (+++). The dipole moment, μ , is smaller for isomers 000 and +−+ than for isomer +++. The calculation of , , and has been performed by use of the interacting induced dipol…

Uptake of polymeric nanoparticles in a human induced pluripotent stem cell-based blood-brain barrier model: Impact of size, material, and protein cor…

2021

The blood–brain barrier (BBB) maintains the homeostasis of the central nervous system, which is one of the reasons for the treatments of brain disorders being challenging in nature. Nanoparticles (NPs) have been seen as potential drug delivery systems to the brain overcoming the tight barrier of endothelial cells. Using a BBB model system based on human induced pluripotent stem cells (iPSCs), the impact of polymeric nanoparticles has been studied in relation to nanoparticle size, material, and protein corona. PLGA [poly(lactic-co-glycolic acid)] and PLLA [poly(d,l-lactide)] nanoparticles stabilized with Tween® 80 were synthesized (50 and 100 nm). iPSCs were differentiated into human brain m…

Polystyrene Sulfonate–Porphyrin Assemblies: Influence of Polyelectrolyte and Porphyrin Structure

2011

In this study, electrostatic self-assembly of different polystyrene sulfonates and a set of tetravalent cationic porphyrins is investigated. It is shown that association of linear polystyrene sulfonates of different molar masses yields finite size nanoscale assemblies that are stable in aqueous solution. Aggregates are compared to the ones of cylindrical brushes, revealing that both form assemblies in the 100 nm range with the charge ratio (molar ratio of porphyrin charges to polyelectrolyte charges) being determining, while the morphology of the resulting network-like assemblies is different for both polyelectrolyte architectures. For the smallest 8k polystyrene sulfonate, in addition, sto…

Ev charging station at university campus

2017

This paper faces the technical and economic challenges related to the design of a green recharge area for electric vehicles at the Campus of Palermo, Italy, with the aim of reduce both costs and pollution connected to the charging process. Based on the behaviour of the student population, the electrical load is identified and two possible solutions are evaluated to manage the peak load: an orientation of the panels increasing the power at defined time and the use of a storage system. The main strength and weakness points of two systems are investigated by taking into account the Levelized Cost of Energy (LCOE), which reaches 75.3 €/MWh for the orientation of panel and 103 €/MWh for stor…

Solar pavements: A critical review

2021

Abstract Resilient, smart and sustainable: these are the keywords for the next generation of road infrastructures. As a renewable and environment-friendly energy harvesting pavement, the concept of a solar pavement has become one of the most researched new highway transportation infrastructures with a goal to transform the road system from the energy consumer to the energy provider, and eliminate or alleviate pollution from the source of energy. At present, the commercial technology through photovoltaic is limited by space installation requirements, which restricts its popularization and application. On the other hand, applying photovoltaic power generation technology to the pavement can pr…