Search results for " electrosynthesis"

showing 10 items of 29 documents

Oxidative C-N fusion of pyridinyl-substituted porphyrins.

2018

International audience; The mild (electro) chemical oxidation of pyridin-2-ylthio-meso substituted Ni(II) porphyrins affords C-N fused cationic and dicationic pyridinium-based derivatives. These porphyrins are fully characterized and the molecular structure of one of them was confirmed by X-ray crystallography. A mechanism for the intramolecular oxidative C-N coupling is proposed based on theoretical calculations and cyclic voltammetry analyses.

Oxidative phosphorylation010402 general chemistry01 natural sciencesMedicinal chemistryCatalysischemistry.chemical_compound[CHIM.ANAL]Chemical Sciences/Analytical chemistryMaterials Chemistrypolycyclic compoundsMolecule[CHIM.COOR]Chemical Sciences/Coordination chemistrydimers fused porphyrin absorption-bands electrosynthesis displacement arrays anthracenes snar tapes pi-extended porphyrinsFusion010405 organic chemistryChemistry[CHIM.ORGA]Chemical Sciences/Organic chemistryMetals and AlloysCationic polymerizationGeneral Chemistry[CHIM.MATE]Chemical Sciences/Material chemistry0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsIntramolecular forceCeramics and CompositesPyridiniumCyclic voltammetryChemical communications (Cambridge, England)
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Electrodeposited nickel–zinc alloy nanostructured electrodes for alkaline electrolyzer

2022

Abstract Over the last decade, as a consequence of the global decarbonization process, the interest towards green hydrogen production has drastically increased. In particular a substantial research effort has focused on the efficient and affordable production of carbon-free hydrogen production processes. In this context, the development of more efficient electrolyzers with low-cost electrode/electrocatalyst materials can play a key role. This work, investigates the fabrication of electrodes of nickel-zinc alloys with nanowires morphology cathode for alkaline electrolyzers. Electrodes are obtained by the simple method of template electrosynthesis that is also inexpensive and easily scalable.…

Potassium hydroxideMaterials scienceRenewable Energy Sustainability and the EnvironmentAlkaline water electrolysisNanowireEnergy Engineering and Power TechnologyOverpotentialCondensed Matter PhysicsElectrosynthesisElectrocatalystElectrochemistrychemistry.chemical_compoundSettore ING-IND/23 - Chimica Fisica ApplicataFuel TechnologyAlkaline electrolyzer Hydrogen evolution reaction Nanostructured electrodes Nanowires Nickel–zinc alloy Template electrosynthesischemistryChemical engineeringSettore ING-IND/17 - Impianti Industriali MeccaniciHydrogen productionInternational Journal of Hydrogen Energy
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Fabbricazione e caratterizzazione di elettrodi di PbO2 nanostrutturati

2008

Settore ING-IND/23 - Chimica Fisica ApplicataAnodic Alumina Membranes Template Electrosynthesis Lead Dioxide Nanowires
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Growth and photo-electrochemical behaviour of Cu2O nanowires

2008

Settore ING-IND/23 - Chimica Fisica ApplicataAnodic alumina membranes Template electrosynthesis Nanowires Copper oxide Semiconductors
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Ultrafast lead-acid battery with nanostructured Pb and PbO2 electrodes

2018

Lead-acid batteries (LABs) are still extensively used in the field of energy storage, owing to a well-known and reliable technology. LABs can deliver high power and store energy for a very long time. In addition, they are reliable and easy to produce. The raw materials for their manufacture are practically unlimited, and about 95% of the materials can be recovered and reused. However, the lower specific energy storage (about 30-40 Wh kg-1), in comparison with other storage systems, limits their use in the most emerging and challenging applications, like electrical mobility, due to the high atomic weight of lead [1]. One of the principal limitations in the use of LABs in electric vehicles (E…

Settore ING-IND/23 - Chimica Fisica ApplicataLead acid batteries nanowire nanostructures template electrosynthesis
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Template Electrodeposition of CIS and CIGS Nanowires for Application in Solar Cells

2010

Settore ING-IND/23 - Chimica Fisica ApplicataNanostructures CIGS solar cells anodic alumina template electrosynthesis
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Fabrication and Characterization of Different Nanostructures

2007

Settore ING-IND/23 - Chimica Fisica ApplicataNanostructures Nanowires Nanotubes Electrodeposition Template Electrosynthesis Anodic Alumina Membranes
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Fabrication and characterization of nanostructured materials

2008

Settore ING-IND/23 - Chimica Fisica ApplicataNanostructures Template Electrosynthesis Anodic alumina membranes Nanowires Nanotubes
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Optimization of Electrodeposited Nickel-Zinc Alloys for Alkaline Electrolyzer with Nanostructured Electrodes

It is common opinion that hydrogen will become increasingly important over time. However, many research efforts still need to be made to develop efficient, low-cost and carbon-free hydrogen production. In this context, electrolysers will play a key role, but it is necessary to develop efficient and low-cost electrode/electrocatalyst materials. In this work, Nickel-Zinc alloy electrodes with nanowires morphology were investigated as cathode for alkaline electrolyzer. Electrodes were obtained by the simple method of template electrosynthesis that is also inexpensive and scalable. Nanostructured electrodes were analysed by morphological and chemical analyses. The nanowires composition is depen…

Settore ING-IND/23 - Chimica Fisica ApplicataSettore ING-IND/17 - Impianti Industriali MeccaniciAlkaline Electrolyzer Nanostructured Electrodes Nickel-Zinc Alloy Hydrogen Evolution Reaction Template Electrosynthesis
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Pd-Co-Based Electrodes for Hydrogen Production by Water Splitting in Acidic Media

2023

To realize the benefits of a hydrogen economy, hydrogen must be produced cleanly, efficiently and affordably from renewable resources and, preferentially, close to the end-users. The goal is a sustainable cycle of hydrogen production and use: in the first stage of the cycle, hydrogen is produced from renewable resources and then used to feed a fuel cell. This cycle produces no pollution and no greenhouse gases. In this context, the development of electrolyzers producing high-purity hydrogen with a high efficiency and low cost is of great importance. Electrode materials play a fundamental role in influencing electrolyzer performances; consequently, in recent years considerable efforts have b…

Settore ING-IND/23 - Chimica Fisica ApplicataSettore ING-IND/17 - Impianti Industriali MeccaniciGeneral Materials ScienceSettore ING-IND/32 - Convertitori Macchine E Azionamenti ElettriciPd–Co alloys acidic media electrolyzers green hydrogen nanowires template electrosynthesisgreen hydrogen; electrolyzers; Pd–Co alloys; nanowires; template electrosynthesis; acidic media
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