Search results for " elements"

Standardization and validation of a new method based on pre-concentration techniques

2010

Zirconium–hafnium and rare earth element signatures discriminating the effect of atmospheric fallout from hydrothermal input in volcanic lake water

2016

The geochemical behaviour of Rare Earth Elements, Zr and Hf was investigated in the thermal waters of Nevado del Ruiz volcano system. A wide range of pH, between 1.0 and 8.8, characterizes these fluids. The acidicwaters are sulphate dominatedwith different Cl/SO4 ratios. The important role of the pH and the ionic complexes for the distribution of REE, Zr a nd Hf in the aqueous phase was evidenced. The pH rules the precipitation of authigenic Fe and Al oxyhydroxides producing changes in REE, Zr, Hf amounts and strong anomalies of Cerium. The precipitation of alunite and jarosite removes LREE from the solution, changing the REE distribution in acidic waters. Y-Ho and Zr-Hf (twin pairs) have a…

Zr, Hf and REE fractionation between dissolved pool and sediments in river waters. Effect of changing ionic strength conditions in element partitioni…

Discrimination between effects induced by microbial activity and water-rock interactions under hydrothermal conditions according to REE behaviour

2013

AbstractRare earth elements (REE) were investigated in siliceous stromatolites forming in the Specchio di Venere Lake on Pantelleria Island. Chondrite-normalised patterns show significant La enrichments and Eu depletions suggesting that fluids involved in stromatolite growth experienced strong rock-water interactions under hydrothermal conditions. At the same time, enrichments in heavy REE (HREE) with respect to intermediate REE (MREE) suggest that hydrothermal fluids interacted with microbial mats during deposition of the stromatolites. The above-mentioned features suggest that rock-water interactions and bacterial activity were simultaneously recorded in the REE patterns of stromatolites,…

Geochemistry of Zr, Hf and REE in extreme water environments: hyperacid, hyper saline and lake waters in hydrothermal systems

This PhD thesis concerns the geochemistry of Zr, Hf and REE in extreme water environments characterized by a wide spectrum of chemical physical-parameters and compositions. The investigations were carried out in hypersaline waters covering a wide range of Eh values along Dead Sea Fault (Israel), in hyperacid waters circulating in Nevado del Ruiz volcano-hydrothermal system (Colombia) and in CO2-rich waters belonging to the Pantelleria volcano-hydrothermal system (Italy), including the alkaline lake “Specchio di Venere” formed within a calderic depression. The wide spectrum of chemical-physical conditions and various water chemical compositions interacting with different solid phases allowed…

The behaviour of REEs in Thailand's Mae Klong estuary: Suggestions from the Y/Ho ratios and lanthanide tetrad effects

2007

Abstract The concentrations of Rare Earth Elements and yttrium (REY) were measured in dissolved phase, in suspended particulate matter (SPM) and in sediments in seven sampling stations in the Mae Klong estuarine system (Inner Thailand Gulf) in order to study their behaviour and distribution pattern. The analysed samples generally show high Rare Earth Element (REE) content in the dissolved phase, with high Medium Rare Earth Elements (MREEs) and Y enrichments in the shale-normalized pattern (versus PAAS). These chemical features are interpreted in terms of direct influences of weathering processes of REE-rich minerals (e.g., phosphates), which abundantly out-crop in the Mae Klong watershed. T…

Evolution-guided evaluation of the inverted terminal repeats of the synthetic transposon Sleeping Beauty.

2018

Abstract Sleeping Beauty (SB) is a synthetic Tc1/mariner transposon that is widely used for genetic engineering in vertebrates, including humans. Its sequence was derived from a consensus of sequences found in fish species including the Atlantic salmon (Salmo salar). One of the functional components of SB, the transposase enzyme, has been subject to extensive mutagenesis yielding hyperactive protein variants for advanced applications. The second functional component, the transposon inverted terminal repeats (ITRs), has so far not been extensively modified, mainly due to a lack of natural sequence information. Importantly, as genome sequences become available, they can provide a rich source …

Increased thyroid cancer incidence in a basaltic volcanic area is associated with non-anthropogenic pollution and biocontamination

2016

The increased thyroid cancer incidence in volcanic areas suggests an environmental effect of volcanic-originated carcinogens. To address this problem, we evaluated environmental pollution and biocontamination in a volcanic area of Sicily with increased thyroid cancer incidence. Thyroid cancer epidemiology was obtained from the Sicilian Regional Registry for Thyroid Cancer. Twenty-seven trace elements were measured by quadrupole mass spectrometry in the drinking water and lichens (to characterize environmental pollution) and in the urine of residents (to identify biocontamination) in the Mt. Etna volcanic area and in adjacent control areas. Thyroid cancer incidence was 18.5 and 9.6/10(5) inh…

Early screening of new accumulating versus non-accumulating tree species for the phytomanagement of marginal lands

2019

International audience; The use of fast-growing trees producing a high quantity of biomass can bring significant practical and economic benefits to the reclamation of marginal lands. The present study aims to identify new shrub/tree species to offer a wider range of shrubs/trees useful for phytomanagement practices. We implemented three experimental sites in France of 1 ha each (Thann, Carrières-sous-Poissy and Leforest) contaminated by different potentially toxic elements (PTE) with a total of 38 different tree species. After two years of growth, the element concentrations in stem and leaf biomasses, tree survival rate and growth of plants were assessed. Although the three sites had elevat…

Variations in the concentrations of macro- and trace elements in two grasses and in the rhizosphere soil during a day

2019

The aim of the research was to study short-term variations in concentrations of 17 elements in two widely distributed natural plant species (couch grass and plantain) and in the rhizosphere soil of the plants. The plant and soil samples were collected in a field from a small site over a daytime. In the course of the day, the variations of the total amounts of C, N, and H in the rhizosphere soil were rather marked and different for the soils taken from roots of plantain and couch grass. The concentrations of some other elements in the rhizosphere soil of the plants varied in a similar way. The short-term variations of element concentrations in roots and leaves of the plants were also rather …