Search results for " elements"

showing 10 items of 732 documents

TASCAを用いたCn, Nh, Fl化学実験のためのHg, Tl, PbのSiO2及びAu表面に対するオンライン化学吸着研究

2018

Online gas-solid adsorption studies with single atom quantities of Hg, Tl, and Pb on SiO$_{2}$ and Au surfaces were carried out using short-lived radioisotopes with half-lives in the range of 4-49 s. This is a model study to measure adsorption enthalpies of superheavy elements Cn, Nh, and Fl. The short-lived isotopes were produced and separated by the gas-filled recoil separator TASCA at GSI. The products were stopped in He gas, and flushed into gas chromatography columns made of Si detectors whose surfaces were covered by SiO$_{2}$ or Au. The short-lived Tl and Pb were successfully measured by the Si detectors with the SiO$_{2}$ surface at room temperature. On the other hand, the Hg did no…

Analytical chemistrychemistry.chemical_elementElectronic structure010402 general chemistry01 natural sciencesadsorption studiethermochromatographyHomologs of superheavy elementRELATIVISTIC PERIODIC DFTMetalGSIAdsorptionCHEMISTRY0103 physical sciencesisothermal chromatographyPhysical and Theoretical ChemistrySUPERHEAVY ELEMENTS010306 general physicsCoperniciumChemistryQUARTZ SURFACE0104 chemical sciencesgas phase chromatography of single atomHEAVIEST ELEMENTSFleroviumELECTRONIC-STRUCTUREvisual_artYield (chemistry)METALvisual_art.visual_art_mediumGas chromatographyRelativistic quantum chemistryphysical preseparationSYSTEMRadiochimica acta
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High‐nuclearity mixed‐valence magnetic clusters : A general solution of the double exchange problem

1996

We report here a general solution of the double‐exchange problem in the high‐nuclearity mixed valence systems containing arbitrary number P of the electrons delocalized over the network of N (P<N) localized spins. The developed approach is based on the successive (chainlike) spin‐coupling scheme and takes full advantage from the quantum angular momentum theory. In the framework of this approach the closed‐form analytical expressions are deduced for the matrix elements of the double exchange interaction, two‐electron transfer, and three‐center interaction that can be referred to as the potential exchange transfer. For the arbitrary nuclearity mixed‐valence systems the matrix elements of all …

Angular momentumValence (chemistry)SpinsChemistryExchange interactionExchange InteractionsGeneral Physics and AstronomyElectron TransferQuantum numberLocalized StatesUNESCO::FÍSICA::Química físicaDelocalized electronMolecular ClustersQuantum mechanicsMixed−Valence CompoundsPhysical and Theoretical ChemistryMatrix ElementsSpin−Lattice Relaxation:FÍSICA::Química física [UNESCO]Exchange Interactions ; Molecular Clusters ; Matrix Elements ; Electron Transfer ; Localized States ; Spin−Lattice Relaxation ; Mixed−Valence CompoundsQuantumBasis set
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Intralaboratory validation of four in vitro assays for the prediction of the skin sensitizing potential of chemicals

2011

Abstract Allergic contact dermatitis is induced by repeated skin contact with an allergen. Assessment of the skin sensitizing potential of chemicals, agrochemicals, and especially cosmetic ingredients is currently performed with the use of animals. Animal welfare and EU legislation demand animal-free alternatives reflected in a testing and marketing ban for cosmetic ingredients beginning in 2013. The underlying mechanisms of induction and elicitation of skin sensitization are complex and a chemical needs to comply several properties being skin sensitizing. To account for the multitude of events in the induction of skin sensitization an in vitro test system will consist of a battery of vario…

Animal Testing AlternativesResponse ElementsToxicologymedicine.disease_causeSensitivity and SpecificityAntioxidantsCell LineAllergenmedicineHumansAllergic contact dermatitisReporter geneIntralaboratoryLocal lymph node assaybusiness.industryIn vitro toxicologyReproducibility of ResultsDendritic CellsGeneral MedicineDendritic cellAllergensSkin Irritancy Testsmedicine.diseaseHaCaTDermatitis Allergic ContactImmunologyPeptidesbusinessToxicology in Vitro
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Glycogen synthase 2 is a novel target gene of peroxisome proliferator-activated receptors.

2007

International audience; Glycogen synthase 2 (Gys-2) is the ratelimiting enzyme in the storage of glycogen in liver and adipose tissue, yet little is known about regulation of Gys-2 transcription. The peroxisome proliferator-activated receptors (PPARs) are transcription factors involved in the regulation of lipid and glucose metabolism and might be hypothesized to govern glycogen synthesis as well. Here, we show that Gys-2 is a direct target gene of PPARalpha, PPARbeta/delta and PPARgamma. Expression of Gys-2 is significantly reduced in adipose tissue of PPARalpha-/-, PPARbeta/delta-/- and PPARgamma+/- mice. Furthermore, synthetic PPARbeta/delta, and gamma agonists markedly up-regulate Gys-2…

Animals; Chromatin/ultrastructure; DNA Primers; Gene Expression Regulation Enzymologic; Glycogen Synthase/genetics; Hepatocytes/enzymology; Hepatocytes/physiology; Mice; Mice Knockout; Peroxisome Proliferator-Activated Receptors/deficiency; Peroxisome Proliferator-Activated Receptors/genetics; Polymerase Chain Reaction; RNA/genetics; RNA/isolation & purification; Rats; Transcription GeneticTranscription GeneticPeroxisome proliferator-activated receptorMESH : HepatocytesPPREPolymerase Chain Reactionadipose-tissuePPARMESH: HepatocytesMice0302 clinical medicineMESH: Animals610 Medicine &amp; healthchemistry.chemical_classificationRegulation of gene expression0303 health sciencesGlycogenglycogen-synthaseChromatinGlycogen Synthase030220 oncology & carcinogenesisMESH : DNA PrimersmicroarrayMESH: DNA Primersmedicine.medical_specialtyHealth aging / healthy living [IGMD 5]fatty-acid oxidationliverGene Expression Regulation EnzymologicMESH: Chromatin03 medical and health sciencesskeletal-muscleGlycogen synthaseMolecular Biology[ SDV.BBM ] Life Sciences [q-bio]/Biochemistry Molecular BiologyHNF4αVLAGPharmacologybeta/deltaMESH: Polymerase Chain Reactionresponse elementsMESH : Peroxisome Proliferator-Activated ReceptorsEndocrinologychemistryMicrobial pathogenesis and host defense [UMCN 4.1]Response elementPeroxisome Proliferator-Activated ReceptorsAdipose tissueMESH: Peroxisome Proliferator-Activated Receptorsin-vivoMESH: Mice KnockoutTransactivationchemistry.chemical_compoundVoeding Metabolisme en GenomicaMESH : RNAMESH : Polymerase Chain ReactionMice KnockoutMESH : ChromatinMESH : RatsMESH: Gene Expression Regulation EnzymologicMetabolism and Genomicsadipose tissueMetabolisme en GenomicaMolecular MedicineNutrition Metabolism and GenomicsMESH : Glycogen SynthaseResearch ArticleMESH: Ratsglycogen synthase 2610 Medicine & healthBiologyMESH : Gene Expression Regulation EnzymologicCellular and Molecular NeuroscienceVoedingMESH: RNAInternal medicineMESH : MicemedicineAnimals[SDV.BBM]Life Sciences [q-bio]/Biochemistry Molecular BiologyTranscription factorMESH: Micealpha ppar-alpha030304 developmental biologyNutritionDNA PrimersMESH: Glycogen SynthaseMESH: Transcription GeneticMESH : Transcription GeneticCell BiologyRatsgene transcriptionbiology.proteinHepatocytesRNAMESH : Mice KnockoutgammaMESH : Animalsmetabolism
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Toxicological Impact of Rare Earth Elements (REEs) on the Reproduction and Development of Aquatic Organisms Using Sea Urchins as Biological Models

2022

The growing presence of lanthanides in the environment has drawn the attention of the scientific community on their safety and toxicity. The sources of lanthanides in the environment include diagnostic medicine, electronic devices, permanent magnets, etc. Their exponential use and the poor management of waste disposal raise serious concerns about the quality and safety of the ecosystems at a global level. This review focused on the impact of lanthanides in marine organisms on reproductive fitness, fertilization and embryonic development, using the sea urchin as a biological model system. Scientific evidence shows that exposure to lanthanides triggers a wide variety of toxic insults, includi…

Aquatic OrganismsCalcium uptakeReproductionOrganic ChemistryGadoliniumGeneral MedicineModels BiologicalCatalysisComputer Science ApplicationsInorganic Chemistrysea urchin embryo developmental biology reproductive toxicology rare earth elements lanthanides gadolinium gene expression echinopluteus calcium uptake.LarvaSea UrchinsAnimalsMetals Rare EarthGene expressionSettore BIO/06 - Anatomia Comparata E CitologiaPhysical and Theoretical ChemistrySea urchin embryonic developmentMolecular BiologyEcosystemSpectroscopyInternational Journal of Molecular Sciences
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The Studio: Reflections and Issues Arising

1999

An advanced Telematic Studio was built at the University of Jyvaskyla to combine the latest technologies for local and distributed work and/or meetings. The objectives were to combine leading edge technologies with ethnographic design principles derived from CSCW and HCI to support a broad range of activities. We informed the design by studies of similar facilities on other sites. The Studio is popular, and it is easy to give glowing accounts of its use. Nevertheless, over three years a significant number of problems have arisen with both technologies and uses. Some of these are local. Others may be generalisable to any ‘cooperative building’. For example: problems with videoconferencing; i…

Architectural engineeringWorkstationbusiness.industryComputer scienceDesign elements and principlescomputer.software_genreComputer securitylaw.inventionVideoconferencingWork (electrical)lawComputer-supported cooperative workEthnographySystems designTelematicsbusinesscomputerStudio
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Enhancer trap infidelity in Drosophila optomotor-blind

2013

Reporter gene activity in enhancer trap lines is often implicitly assumed to mirror quite faithfully the endogenous expression of the "trapped" gene, even though there are numerous examples of enhancer trap infidelity. optomotor-blind (omb) is a 160 kb gene in which 16 independent P-element enhancer trap insertions of three different types have been mapped in a range of more than 60 kb. We have determined the expression pattern of these elements in wing, eye-antennal and leg imaginal discs as well as in the pupal tergites. We noted that one pGawB insertion (omb (P4) ) selectively failed to report parts of the omb pattern even though the missing pattern elements were apparent in all other 15…

Arthropod AntennaeNerve Tissue ProteinsEyeGenes ReporterEnhancer trapAnimalsDrosophila ProteinsWings AnimalDrosophila (subgenus)EnhancerPromoter Regions GeneticGeneGeneticsReporter genebiologyPupaChromosome MappingPromoterExtremitiesbiology.organism_classificationImaginal discMutagenesis InsertionalEnhancer Elements GeneticImaginal DiscsInsect ScienceDrosophilaT-Box Domain ProteinsDrosophila ProteinResearch Paper
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Double-beta-decay nuclear matrix elements in the QRPA framework

2012

We review the recent work done by the Jyväskylä-La Plata collaboration on the calculation of nuclear matrix elements for various modes of double-beta decays. Whenever helpful, we connect our recent work to the historical background in order to highlight the progress achieved in the field of double-beta decay. At the same time, we introduce some new concepts and ideas to treat e.g. possible backgrounds in Gamow-Teller strength functions generated in (p,n) and (n,p) reactions. © 2012 IOP Publishing Ltd. Fil: Suhonen, J.. Universidad de Jyvaskyla; Finlandia Fil: Civitarese, Enrique Osvaldo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La P…

AstronomíaPhysicsMatrix elementsNuclear and High Energy PhysicsParticle physicsField (physics)Ciencias FísicasDouble beta decayBibliographyNuclear matrixDouble beta decayCIENCIAS NATURALES Y EXACTASJournal of Physics G: Nuclear and Particle Physics
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XMM-Newton detection of the 2.1 ms coherent pulsations from IGR J17379-3747

2018

We report on the detection of X-ray pulsations at 2.1 ms from the known X-ray burster IGR J17379-3747 using XMM-Newton. The coherent signal shows a clear Doppler modulation from which we estimate an orbital period of ~1.9 hours and a projected semi-major axis of ~8 lt-ms. Taking into account the lack of eclipses (inclination angle of &lt; 75 deg) and assuming a neutron star mass of 1.4 Msun, we estimated a minimum companion star of ~0.06 Msun. Considerations on the probability distribution of the binary inclination angle make less likely the hypothesis of a main-sequence companion star. On the other hand, the close correspondence with the orbital parameters of the accreting millisecond puls…

Astrophysics::High Energy Astrophysical PhenomenaBrown dwarfFOS: Physical sciencesgeneral; stars: neutron; X-rays: binaries; accretion accretion disks [binaries]AstrophysicsAstrophysics::Cosmology and Extragalactic AstrophysicsEphemeris01 natural sciencesstars: neutronSettore FIS/05 - Astronomia E AstrofisicaMillisecond pulsar0103 physical sciencesAstrophysics::Solar and Stellar AstrophysicsEmission spectrum010303 astronomy & astrophysicsAstrophysics::Galaxy AstrophysicsOrbital elementsPhysicsHigh Energy Astrophysical Phenomena (astro-ph.HE)accretion accretion disksAccretion (meteorology)010308 nuclear & particles physicsAstronomy and AstrophysicsOrbital periodX-rays: binarieNeutron starbinaries: generalSpace and Planetary ScienceAstrophysics::Earth and Planetary AstrophysicsAstrophysics - High Energy Astrophysical Phenomena
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Study on ambient concentrations of PM10, PM10-2.5, PM2.5 and gaseous pollutants. Trace elements and chemical speciation of atmospheric particulates

2010

Abstract This study provides the first comprehensive report on mass concentrations of particulate matter of various sizes, inorganic and organic gas concentrations monitored at three sampling sites in the city of Palermo (Sicily, Italy). It also provides information on the water-soluble species and trace elements. A total of 2054 PM10 (1333) and PM2.5 (721) daily measurements were collected from November 2006 to February 2008. The highest mass concentrations were observed at the urban stations, average values being about two times higher than those at the suburban (control) site. Time variations in PM10 and also PM10–2.5 were observed at the urban stations, the highest concentrations being …

Atmospheric ScienceAmmonium nitrateair pollution PM10 and PM2.5 secondary airborne particulate BTX trace elementsTrace elementAir pollutionParticulatesmedicine.disease_causeAerosolSettore GEO/08 - Geochimica E Vulcanologiachemistry.chemical_compoundNitratechemistryEnvironmental chemistrymedicineNitrogen dioxideSulfateGeneral Environmental Science
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